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Tetraperchloratoaluminate
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<h2 id="formation">Formation</h2> <p>Nitronium tetraperchloratoaluminate is made from exact amounts of <a href="/facts/Nitronium_perchlorate/0rbP8S2I">nitronium perchlorate</a> and anhydrous <a href="/facts/Aluminium_chloride/xrhvSxDr">aluminium chloride</a> combined in liquid <a href="/facts/Sulfur_dioxide/jDK1fIDs">sulfur dioxide</a>.<a class="footnote-ref" id="fnref:3" href="#fn:3"><sup>3</sup></a> </p><p>Ammonium tetraperchloratoaluminate can be formed by three moles of <a href="/facts/Nitronium_perchlorate/0rbP8S2I">nitronium perchlorate</a>, one mole of anhydrous <a href="/facts/Aluminium_chloride/xrhvSxDr">aluminium chloride</a>, and one mole of <a href="/facts/Ammonium_perchlorate/BDMsvjxu">ammonium perchlorate</a> combined in liquid sulfur dioxide.<a class="footnote-ref" id="fnref:4" href="#fn:4"><sup>4</sup></a> </p> <h2 id="properties">Properties</h2> <p>The tetraperchloratoaluminates are yellowish crystalline solids. They are stable up to 50 °C.<a class="footnote-ref" id="fnref:5" href="#fn:5"><sup>5</sup></a> </p><p>Above this temperature they decompose to <a href="/facts/Hexaperchloratoaluminate/IIHH5hIN">hexaperchloratoaluminates</a> which are more temperature stable.<a class="footnote-ref" id="fnref:6" href="#fn:6"><sup>6</sup></a> </p> <h2 id="references">References</h2> <ol> <li id="fn:1"><p>Guibert, C. R.; H. F. Klodowski; M. D. Marshall; A. D. McElroy (1 June 1966). "Complex Light Metal Perchlorates - Tetraperchloratoaluminates". Studies of Complex Perchlorates. Callery Chemical Company. pp. 14–27. Archived from the original on April 28, 2014. Retrieved 1 February 2014. <a href="https://web.archive.org/web/20140428034315/http://www.dtic.mil/cgi-bin/GetTRDoc?AD=AD0634105" target="_blank">https://web.archive.org/web/20140428034315/http://www.dtic.mil/cgi-bin/GetTRDoc?AD=AD0634105</a> <a href="#fnref:1" class="footnote-back-ref">↩</a></p></li> <li id="fn:2"><p>Titova, K. V.; E. I. Kolmakova (1977). "Tetraalkylammonium haloperchloratoaluminates". Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26 (2): 229–231. doi:10.1007/BF00921820. ISSN 0568-5230. <a href="/wiki/Doi_(identifier)" target="_blank">/wiki/Doi_(identifier)</a> <a href="#fnref:2" class="footnote-back-ref">↩</a></p></li> <li id="fn:3"><p>Guibert, C. R.; H. F. Klodowski; M. D. Marshall; A. D. McElroy (1 June 1966). "Complex Light Metal Perchlorates - Tetraperchloratoaluminates". Studies of Complex Perchlorates. Callery Chemical Company. pp. 14–27. Archived from the original on April 28, 2014. Retrieved 1 February 2014. <a href="https://web.archive.org/web/20140428034315/http://www.dtic.mil/cgi-bin/GetTRDoc?AD=AD0634105" target="_blank">https://web.archive.org/web/20140428034315/http://www.dtic.mil/cgi-bin/GetTRDoc?AD=AD0634105</a> <a href="#fnref:3" class="footnote-back-ref">↩</a></p></li> <li id="fn:4"><p>Guibert, C. R.; H. F. Klodowski; M. D. Marshall; A. D. McElroy (1 June 1966). "Complex Light Metal Perchlorates - Tetraperchloratoaluminates". Studies of Complex Perchlorates. Callery Chemical Company. pp. 14–27. Archived from the original on April 28, 2014. Retrieved 1 February 2014. <a href="https://web.archive.org/web/20140428034315/http://www.dtic.mil/cgi-bin/GetTRDoc?AD=AD0634105" target="_blank">https://web.archive.org/web/20140428034315/http://www.dtic.mil/cgi-bin/GetTRDoc?AD=AD0634105</a> <a href="#fnref:4" class="footnote-back-ref">↩</a></p></li> <li id="fn:5"><p>Guibert, C. R.; H. F. Klodowski; M. D. Marshall; A. D. McElroy (1 June 1966). "Complex Light Metal Perchlorates - Tetraperchloratoaluminates". Studies of Complex Perchlorates. Callery Chemical Company. pp. 14–27. Archived from the original on April 28, 2014. Retrieved 1 February 2014. <a href="https://web.archive.org/web/20140428034315/http://www.dtic.mil/cgi-bin/GetTRDoc?AD=AD0634105" target="_blank">https://web.archive.org/web/20140428034315/http://www.dtic.mil/cgi-bin/GetTRDoc?AD=AD0634105</a> <a href="#fnref:5" class="footnote-back-ref">↩</a></p></li> <li id="fn:6"><p>Guibert, C. R.; H. F. Klodowski; M. D. Marshall; A. D. McElroy (1 June 1966). "Complex Perchlorates - Hexaperchloratoaluminates". Studies of Complex Perchlorates. Callery Chemical Company. pp. 28–44. Archived from the original on April 28, 2014. Retrieved 1 February 2014. <a href="https://web.archive.org/web/20140428034315/http://www.dtic.mil/cgi-bin/GetTRDoc?AD=AD0634105" target="_blank">https://web.archive.org/web/20140428034315/http://www.dtic.mil/cgi-bin/GetTRDoc?AD=AD0634105</a> <a href="#fnref:6" class="footnote-back-ref">↩</a></p></li> </ol>