Both first and second generation Grubbs catalysts were commercially available from Materia, a startup company that Grubbs co-founded with Mike Giardello in Pasadena, California, in 1998. Materia has been able to obtain exclusive rights to manufacture many of the known olefin catalysts. Under Giardello, Materia was able to sell their catalysts through Sigma-Aldrich's chemicals catalogue. Sigma-Aldrich became their exclusive worldwide provider. In 2008, Materia partnered with Cargill to form Elevance Renewable Sciences to produce specialty chemicals from renewable oils, including biofuels. In 2017, Materia sold its catalyst business to Umicore. In 2021, Materia was acquired by ExxonMobil.
By controlling the catalyst used, it became possible to synthesize polymers with specialized structures and functional capabilities, including cyclic olefins, alternating copolymers, and multiblock copolymers. Using catalysts allows chemists to speed up chemical transformations and to lower the cost of what were previously complicated multi-step industrial processes.
While at Columbia University, Grubbs also met his future wife, Helen O'Kane, a special-education teacher, with whom he had three children: Barney (born 1972), Brendan H. (born 1974) and Kathleen (Katy) (born 1977).
"American Institute of Chemists Gold Medal". Science History Institute. March 22, 2018. https://www.sciencehistory.org/american-institute-of-chemists-gold-medal
"Press Release, 5 October 2005". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 12, 2016. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/press.html
"Lanxess rubber employs Materia catalysts". Chemical & Engineering News. 84 (34): 23. August 21, 2006. Retrieved January 9, 2018. https://cen.acs.org/articles/84/i34/Lanxess-rubber-employs-Materia-catalysts.html?type=paidArticleContent
"Jackson Purchase Nobel Laureate". Jackson Purchase Historical Society. Retrieved April 12, 2016. http://jacksonpurchasehistory.org/2010/12/13/jackson-purchase-nobel-laureate/
"Robert H. Grubbs – Biographical". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 12, 2016. In some places, my birthplace is listed as Calvert City and in others Possum Trot. I was actually born between the two, so either one really is correct. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/grubbs-bio.html
"Jackson Purchase Nobel Laureate". Jackson Purchase Historical Society. Retrieved April 12, 2016. http://jacksonpurchasehistory.org/2010/12/13/jackson-purchase-nobel-laureate/
History and Families, McCracken County, Kentucky, 1824–1989. Turner Publishing Company. December 22, 1989. ISBN 9780938021360. Retrieved December 22, 2021 – via Google Books. 9780938021360
"Jackson Purchase Nobel Laureate". Jackson Purchase Historical Society. Retrieved April 12, 2016. http://jacksonpurchasehistory.org/2010/12/13/jackson-purchase-nobel-laureate/
"Robert H. Grubbs – Biographical". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 12, 2016. In some places, my birthplace is listed as Calvert City and in others Possum Trot. I was actually born between the two, so either one really is correct. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/grubbs-bio.html
"Nobel laureate Robert Grubbs dies at 79". cen.acs.org. Retrieved December 22, 2021. https://cen.acs.org/people/obituaries/Nobel-laureate-Robert-Grubbs-dies/99/web/2021/12
Janine Young, Sikes (October 6, 2005). "A Gator wins Nobel in chemistry". The Gainesville Sun. Archived from the original on April 21, 2016. Retrieved April 14, 2016. https://web.archive.org/web/20160421170934/http://www.gainesville.com/article/20051006/LOCAL/51006006
"Robert H. Grubbs – Biographical". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 12, 2016. In some places, my birthplace is listed as Calvert City and in others Possum Trot. I was actually born between the two, so either one really is correct. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/grubbs-bio.html
Janine Young, Sikes (October 6, 2005). "A Gator wins Nobel in chemistry". The Gainesville Sun. Archived from the original on April 21, 2016. Retrieved April 14, 2016. https://web.archive.org/web/20160421170934/http://www.gainesville.com/article/20051006/LOCAL/51006006
Doerfler, Andrew (December 20, 2021). "UF Mourns the Passing of Robert H. Grubbs, Nobel-Winning Alumnus". News – College of Liberal Arts & Sciences. Retrieved December 22, 2021. https://news.clas.ufl.edu/uf-clas-mourns-the-passing-of-robert-h-grubbs-nobel-winning-alumnus/
Grubbs, Robert Howard (1968). I. Cyclebutadiene Derivatives II. Studies of Cyclooctatetraene Iron Tricarbonyl Complexes (PhD thesis). Columbia University. ProQuest 302317287. (subscription required) /wiki/ProQuest
"Robert H. Grubbs – Biographical". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 12, 2016. In some places, my birthplace is listed as Calvert City and in others Possum Trot. I was actually born between the two, so either one really is correct. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/grubbs-bio.html
"Robert H. Grubbs – Biographical". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 12, 2016. In some places, my birthplace is listed as Calvert City and in others Possum Trot. I was actually born between the two, so either one really is correct. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/grubbs-bio.html
"Robert H. Grubbs – Biographical". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 12, 2016. In some places, my birthplace is listed as Calvert City and in others Possum Trot. I was actually born between the two, so either one really is correct. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/grubbs-bio.html
"Robert H. Grubbs PhD " Leadership Board". Department of Chemistry, University of Florida. Retrieved April 14, 2016. https://www.chem.ufl.edu/about-all/directory/people/name/robert-grubbs/
"Nobel Laureates". Alfred P. Sloan Foundation. Retrieved April 15, 2016. https://sloan.org/fellowships/nobel-laureates
"Chemistry Nobel Prize for two Humboldtians". The Alexander von Humboldt Foundation. October 5, 2005. Archived from the original on November 14, 2018. https://web.archive.org/web/20181114224227/https://www.humboldt-foundation.de/web/33300.html
"Robert H. Grubbs American chemist". Encyclopædia Britannica. April 26, 2024. http://www.britannica.com/biography/Robert-H-Grubbs
"2002 Robert H. Grubbs, Caltech". Southern California Section of the American Chemical Society. July 20, 2012. Retrieved April 12, 2016. http://scalacs.org/?page_id=1089
Robert H. Grubbs publications indexed by Google Scholar
https://scholar.google.com/citations?user=Lukr7eoAAAAJ
Robert H. Grubbs publications indexed by the Scopus bibliographic database. (subscription required) https://www.scopus.com/authid/detail.url?authorId=36047111100
Notman, Nina (January 28, 2015). "Grubbs catalyst". Chemistry World. Retrieved April 15, 2016. http://www.rsc.org/chemistryworld/2015/01/grubbs-catalyst-olefin-metathesis-podcast
"Industry's Secret Ingredient". Caltech News. Archived from the original on September 10, 2015. Retrieved April 17, 2014. https://web.archive.org/web/20150910110435/https://innovation.caltech.edu/content/industrys-secret-ingredient
"Leading Innovation in Catalysis". Materia. Retrieved April 15, 2016. http://www.materia-inc.com/technology/olefin-metathesis
"The History of Materia". Materia. Retrieved April 15, 2016. http://www.materia-inc.com/corporate/about/history
"Industry's Secret Ingredient". Caltech News. Archived from the original on September 10, 2015. Retrieved April 17, 2014. https://web.archive.org/web/20150910110435/https://innovation.caltech.edu/content/industrys-secret-ingredient
"Materia and Sigma-Aldrich Announce Exclusive Distribution Deal for Grubbs' Metathesis Catalysts". Business Wire. August 18, 2003. Retrieved April 15, 2016. http://www.businesswire.com/news/home/20030818005374/en/Materia-Sigma-Aldrich-Announce-Exclusive-Distribution-Deal-Grubbs
Tullo, Alexander H. (March 31, 2008). "Cargill, Materia Launch New Firm Elevance will make specialty chemicals from vegetable oils". Chemical & Engineering News. 86 (13): 6. doi:10.1021/cen-v086n013.p006. http://cen.acs.org/articles/86/i13/Cargill-Materia-Launch-New-Firm.html
Kotrba, Ron (March 23, 2010). "Newton plant to become biorefinery showcase". Biodiesel Magazine. Retrieved April 15, 2016. http://www.biodieselmagazine.com/articles/4091/newton-plant-to-become-biorefinery-showcase
"Materia, Inc. Sells Catalyst Business to Umicore". Materia. December 20, 2017. Retrieved June 10, 2021. http://www.materia-inc.com/media/news/materia-inc.-sells-catalyst-business-to-umicore
"ExxonMobil acquires Materia, Inc., a high-performance structural polymers company". ExxonMobil. Retrieved December 18, 2021. https://corporate.exxonmobil.com:443/News/Newsroom/News-releases/2021/1207_ExxonMobil-Acquires-Materia-Inc-a-High-Performance-Structural-Polymers-Company
"Reliance Innovation Council (2007–2017) – Raghunath Mashelkar – Mukesh Ambani – Jean-Marie Lehn – Robert Grubbs – George Whitesides – Gary Hamel – William Haseltine". Reliance Industries Limited. Archived from the original on December 16, 2021. Retrieved December 20, 2021. https://web.archive.org/web/20211216034937/https://www.ril.com/Innovation-R-D/Innovation.aspx
"Nobel Laureates". USA Science & Engineering Festival. Archived from the original on April 21, 2010. Retrieved April 12, 2016. https://web.archive.org/web/20100421005310/http://www.usasciencefestival.org/about/advisors/
Janine Young, Sikes (October 6, 2005). "A Gator wins Nobel in chemistry". The Gainesville Sun. Archived from the original on April 21, 2016. Retrieved April 14, 2016. https://web.archive.org/web/20160421170934/http://www.gainesville.com/article/20051006/LOCAL/51006006
Miree-Luke, Lisa (October 8, 2015). "Axalta's Distinguished Lecture Series at the University of Pennsylvania Features Presentation on Methathesis Polymerization". Business Wire. Retrieved April 14, 2016. http://www.businesswire.com/news/home/20151008005945/en/Axalta%E2%80%99s-Distinguished-Lecture-Series-University-Pennsylvania-Features
Pearson, Rodney (April 3, 2001). "South Pasadena chemist wins national award for designing new catalysts". EurekaAlert. Archived from the original on April 15, 2016. Retrieved April 14, 2016. https://web.archive.org/web/20160415013720/http://www.eurekalert.org/pub_releases/2001-04/ACS-SPcw-0304101.php
Janine Young, Sikes (October 6, 2005). "A Gator wins Nobel in chemistry". The Gainesville Sun. Archived from the original on April 21, 2016. Retrieved April 14, 2016. https://web.archive.org/web/20160421170934/http://www.gainesville.com/article/20051006/LOCAL/51006006
Singh, Okram Mukherjee (2006). "Metathesis catalysts: Historical perspective, recent developments and practical applications" (PDF). Journal of Scientific & Industrial Research. 65 (December): 957–965. Retrieved April 12, 2016. http://nopr.niscair.res.in/bitstream/123456789/4987/1/JSIR%2065%2812%29%20957-965.pdf
Grubbs, Robert H. (2006). "Olefin-Metathesis Catalysts for the Preparation of Molecules and Materials (Nobel Lecture)". Angewandte Chemie International Edition. 45 (23): 3760–3765. doi:10.1002/anie.200600680. PMID 16724297. /wiki/Doi_(identifier)
Chatterjee, Arnab K.; Choi, Tae-Lim; Sanders, Daniel P.; Grubbs, Robert H. (September 2003). "A General Model for Selectivity in Olefin Cross Metathesis" (PDF). Journal of the American Chemical Society. 125 (37): 11360–11370. Bibcode:2003JAChS.12511360C. doi:10.1021/ja0214882. PMID 16220959. Retrieved April 14, 2016. http://medchem.rutgers.edu/mc504/pdfs/CM.pdf
Nguyen, SonBinh T.; Johnson, Lynda K.; Grubbs, Robert H.; Ziller, Joseph W. (May 1992). "Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media" (PDF). Journal of the American Chemical Society. 114 (10): 3974–3975. Bibcode:1992JAChS.114.3974N. doi:10.1021/ja00036a053. https://authors.library.caltech.edu/88217/2/ja00036a053_si_001.pdf
Schrock, R. R.; Feldman, J.; Cannizzo, L. F.; Grubbs, R. H. (September 1987). "Ring-opening polymerization of norbornene by a living tungsten alkylidene complex". Macromolecules. 20 (5): 1169–1172. Bibcode:1987MaMol..20.1169S. doi:10.1021/ma00171a053. /wiki/Bibcode_(identifier)
Novak, Bruce M.; Grubbs, Robert H. (1988). "The ring opening metathesis polymerization of 7-oxabicyclo[2.2.1]hept-5-ene derivatives: a new acyclic polymeric ionophore". Journal of the American Chemical Society. 110 (3): 960–961. Bibcode:1988JAChS.110..960N. doi:10.1021/ja00211a043. /wiki/Journal_of_the_American_Chemical_Society
Nguyen, SonBinh T.; Johnson, Lynda K.; Grubbs, Robert H.; Ziller, Joseph W. (May 1992). "Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media" (PDF). Journal of the American Chemical Society. 114 (10): 3974–3975. Bibcode:1992JAChS.114.3974N. doi:10.1021/ja00036a053. https://authors.library.caltech.edu/88217/2/ja00036a053_si_001.pdf
Nguyen, Sonbinh T.; Grubbs, Robert H.; Ziller, Joseph W. (1993). "Syntheses and activities of new single-component, ruthenium-based olefin metathesis catalysts". Journal of the American Chemical Society. 115 (21): 9858–9859. Bibcode:1993JAChS.115.9858N. doi:10.1021/ja00074a086. /wiki/Journal_of_the_American_Chemical_Society
Notman, Nina (January 28, 2015). "Grubbs catalyst". Chemistry World. Retrieved April 15, 2016. http://www.rsc.org/chemistryworld/2015/01/grubbs-catalyst-olefin-metathesis-podcast
Schwab, Peter; France, Marcia B.; Ziller, Joseph W.; Grubbs, Robert H. (1995). "A Series of Well-Defined Metathesis Catalysts–Synthesis of [RuCl2(CHR')(PR3)2] and Its Reactions". Angew. Chem. Int. Ed. Engl. 34 (18): 2039–2041. doi:10.1002/anie.199520391. /wiki/Angew._Chem._Int._Ed._Engl.
Schwab, Peter; Grubbs, Robert H.; Ziller, Joseph W. (1996). "Synthesis and Applications of RuCl2(=CHR')(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity". Journal of the American Chemical Society. 118 (1): 100–110. Bibcode:1996JAChS.118..100S. doi:10.1021/ja952676d. /wiki/Journal_of_the_American_Chemical_Society
Astruc, Didier (2005). "The metathesis reactions: from a historical perspective to recent developments" (PDF). New Journal of Chemistry. 29 (1): 42. doi:10.1039/b412198h. Archived from the original (PDF) on June 16, 2016. Retrieved April 12, 2016. https://web.archive.org/web/20160616011525/http://astruc.didier.free.fr/doc%20astruc/Metathese-NJC-2005-29-Astruc-p42-56.pdf
Wilson, Gerald O.; Porter, Keith A.; Weissman, Haim; White, Scott R.; Sottos, Nancy R.; Moore, Jeffrey S. (August 14, 2009). "Stability of Second Generation Grubbs' Alkylidenes to Primary Amines: Formation of Novel Ruthenium-Amine Complexes". Advanced Synthesis & Catalysis. 351 (11–12): 1817–1825. doi:10.1002/adsc.200900134. /wiki/Doi_(identifier)
"American Institute of Chemists Gold Medal". Science History Institute. March 22, 2018. https://www.sciencehistory.org/american-institute-of-chemists-gold-medal
Singh, Okram Mukherjee (2006). "Metathesis catalysts: Historical perspective, recent developments and practical applications" (PDF). Journal of Scientific & Industrial Research. 65 (December): 957–965. Retrieved April 12, 2016. http://nopr.niscair.res.in/bitstream/123456789/4987/1/JSIR%2065%2812%29%20957-965.pdf
Astruc, Didier (2005). "The metathesis reactions: from a historical perspective to recent developments" (PDF). New Journal of Chemistry. 29 (1): 42. doi:10.1039/b412198h. Archived from the original (PDF) on June 16, 2016. Retrieved April 12, 2016. https://web.archive.org/web/20160616011525/http://astruc.didier.free.fr/doc%20astruc/Metathese-NJC-2005-29-Astruc-p42-56.pdf
Miree-Luke, Lisa (October 8, 2015). "Axalta's Distinguished Lecture Series at the University of Pennsylvania Features Presentation on Methathesis Polymerization". Business Wire. Retrieved April 14, 2016. http://www.businesswire.com/news/home/20151008005945/en/Axalta%E2%80%99s-Distinguished-Lecture-Series-University-Pennsylvania-Features
"Industry's Secret Ingredient". Caltech News. Archived from the original on September 10, 2015. Retrieved April 17, 2014. https://web.archive.org/web/20150910110435/https://innovation.caltech.edu/content/industrys-secret-ingredient
"Robert H. Grubbs – Biographical". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 12, 2016. In some places, my birthplace is listed as Calvert City and in others Possum Trot. I was actually born between the two, so either one really is correct. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/grubbs-bio.html
"Columbia News ::: Alumnus Robert Grubbs Wins Nobel Prize in Chemistry". www.columbia.edu. Archived from the original on March 1, 2017. Retrieved July 21, 2016. https://web.archive.org/web/20170301132207/http://www.columbia.edu/cu/news/05/10/robertGrubbs_nobel.html
McClain, Dylan Loeb (December 24, 2021). "Robert H. Grubbs, 79, Dies; Chemistry Breakthrough Led to a Nobel". The New York Times. Retrieved December 24, 2021. https://www.nytimes.com/2021/12/24/science/robert-h-grubbs-dead.html
"Caltech Mourns the Loss of Nobel Laureate Robert H. Grubbs". Caltech. December 19, 2021. Retrieved December 19, 2021. https://www.caltech.edu/about/news/caltech-mourns-the-loss-of-nobel-laureate-robert-h-grubbs
McClain, Dylan Loeb (December 24, 2021). "Robert H. Grubbs, 79, Dies; Chemistry Breakthrough Led to a Nobel". The New York Times. Retrieved December 24, 2021. https://www.nytimes.com/2021/12/24/science/robert-h-grubbs-dead.html
McClain, Dylan Loeb (December 24, 2021). "Robert H. Grubbs, 79, Dies; Chemistry Breakthrough Led to a Nobel". The New York Times. Retrieved December 24, 2021. https://www.nytimes.com/2021/12/24/science/robert-h-grubbs-dead.html
"Press Release, 5 October 2005". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 12, 2016. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/press.html
"Robert H. Grubbs – Facts". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 15, 2016. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/grubbs-facts.html
"National Academy of Sciences Members". Caltech. Retrieved April 15, 2016. https://www.caltech.edu/about/news/robert-h-grubbs-wins-national-award-american-chemical-society-54744
"Robert H. Grubbs". American Academy of Arts & Sciences. November 18, 2021. Retrieved December 20, 2021. https://www.amacad.org/person/robert-h-grubbs
"Robert H. Grubbs". The Franklin Institute. January 10, 2014. Retrieved April 14, 2016. https://www.fi.edu/laureates/robert-h-grubbs
"Herman F. Mark Award 2000". Division of Polymer Chemistry, Inc. of the American Chemical Society. Archived from the original on March 15, 2016. Retrieved April 14, 2016. https://web.archive.org/web/20160315151551/http://www.polyacs.org/271.html
Pearson, Rodney (April 3, 2001). "South Pasadena chemist wins national award for designing new catalysts". EurekaAlert. Archived from the original on April 15, 2016. Retrieved April 14, 2016. https://web.archive.org/web/20160415013720/http://www.eurekalert.org/pub_releases/2001-04/ACS-SPcw-0304101.php
"2002 Robert H. Grubbs, Caltech". Southern California Section of the American Chemical Society. July 20, 2012. Retrieved April 12, 2016. http://scalacs.org/?page_id=1089
"Pasadena chemist wins national award for cata". EurekAlert!. Retrieved December 20, 2021. https://www.eurekalert.org/news-releases/625149
"Arthur C. Cope Award". ACS Chemistry for Life. American Chemical Society. Retrieved April 12, 2016. http://www.acs.org/content/acs/en/funding-and-awards/awards/national/bytopic/arthur-c-cope-award.html
"Tetrahedron Prize for Creativity". Elsevier B.V. Retrieved April 12, 2016. https://www.elsevier.com/awards/global/tetrahedron-prize-for-creativity
"Press Release, 5 October 2005". The Nobel Prize in Chemistry 2005. NobelPrize.org. Retrieved April 12, 2016. https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2005/press.html
"Members Grubbs". rsc.org. Royal Society of Chemistry. Retrieved April 15, 2016. https://royalsociety.org/people/robert-grubbs-13392/
"Robert H. Grubbs 31st Paul Karrer Lecture 2005". University of Zurich. Archived from the original on April 23, 2016. Retrieved April 12, 2016. https://web.archive.org/web/20160423154812/http://www.chem.uzh.ch/en/events/KarrerLecture/ListOfRecipients/RobertGrubbs.html
"Golden Plate Awardees of the American Academy of Achievement". www.achievement.org. American Academy of Achievement. https://achievement.org/our-history/golden-plate-awards/#science-exploration
"2009 ACS Fellows". American Chemical Society. Archived from the original on February 24, 2019. Retrieved April 15, 2016. https://web.archive.org/web/20190224231509/https://www.acs.org/content/acs/en/funding-and-awards/fellows/list-of-2009-acs-fellows.html
"American Institute of Chemists Gold Medal". Science History Institute. March 22, 2018. https://www.sciencehistory.org/american-institute-of-chemists-gold-medal
"2015 Inductees: Robert Howard Grubbs". Florida Inventors Hall of Fame. September 28, 2015. Retrieved April 14, 2016. http://www.floridainvents.org/robert-grubbs/
"Current NAI Fellows". National Academy of Inventors. Retrieved April 15, 2016. http://www.academyofinventors.org/search-fellows.asp?qFellows=G&Qa=%&qSort=FASC
"Professor Robert Howard Grubbs". National Academy of Engineering. Retrieved April 12, 2016. http://www.nae.edu/130206.aspx
"New Academicians and Foreign Members of the Chinese Academy of Sciences". Angewandte Chemie International Edition. 55 (8): 2633–2634. February 2016. doi:10.1002/anie.201511637. /wiki/Doi_(identifier)
"12 Famous Scientists Elected 2015 CAS Foreign Members". CASAD. Retrieved April 12, 2016. http://english.casad.cas.cn/bb/201601/t20160118_158870.html
Wang, Linda (February 13, 2017). "Robert Grubbs wins Remsen Award". Chemical & Engineering News. 59 (7). American Chemical Society. Retrieved December 20, 2021. https://cen.acs.org/articles/95/i7/Robert-Grubbs-wins-Remsen-Award.html
Anon (2017). "Professor Robert Grubbs ForMemRS". royalsociety.org. London: Royal Society. https://royalsociety.org/people/robert-grubbs-13392/