The statement of the theorem is as follows.1
In both parts of the theorem, the expression e i t A {\displaystyle e^{itA}} is defined by means of the functional calculus, which uses the spectral theorem for unbounded self-adjoint operators.
The operator A {\displaystyle A} is called the infinitesimal generator of ( U t ) t ∈ R . {\displaystyle (U_{t})_{t\in \mathbb {R} }.} Furthermore, A {\displaystyle A} will be a bounded operator if and only if the operator-valued mapping t ↦ U t {\displaystyle t\mapsto U_{t}} is norm-continuous.
The infinitesimal generator A {\displaystyle A} of a strongly continuous unitary group ( U t ) t ∈ R {\displaystyle (U_{t})_{t\in \mathbb {R} }} may be computed as
with the domain of A {\displaystyle A} consisting of those vectors ψ {\displaystyle \psi } for which the limit exists in the norm topology. That is to say, A {\displaystyle A} is equal to − i {\displaystyle -i} times the derivative of U t {\displaystyle U_{t}} with respect to t {\displaystyle t} at t = 0 {\displaystyle t=0} . Part of the statement of the theorem is that this derivative exists—i.e., that A {\displaystyle A} is a densely defined self-adjoint operator. The result is not obvious even in the finite-dimensional case, since U t {\displaystyle U_{t}} is only assumed (ahead of time) to be continuous, and not differentiable.
The family of translation operators
is a one-parameter unitary group of unitary operators; the infinitesimal generator of this family is an extension of the differential operator
defined on the space of continuously differentiable complex-valued functions with compact support on R . {\displaystyle \mathbb {R} .} Thus
In other words, motion on the line is generated by the momentum operator.
Stone's theorem has numerous applications in quantum mechanics. For instance, given an isolated quantum mechanical system, with Hilbert space of states H, time evolution is a strongly continuous one-parameter unitary group on H {\displaystyle {\mathcal {H}}} . The infinitesimal generator of this group is the system Hamiltonian.
Further information: Stone–von Neumann theorem and Heisenberg group
Stone's Theorem can be recast using the language of the Fourier transform. The real line R {\displaystyle \mathbb {R} } is a locally compact abelian group. Non-degenerate *-representations of the group C*-algebra C ∗ ( R ) {\displaystyle C^{*}(\mathbb {R} )} are in one-to-one correspondence with strongly continuous unitary representations of R , {\displaystyle \mathbb {R} ,} i.e., strongly continuous one-parameter unitary groups. On the other hand, the Fourier transform is a *-isomorphism from C ∗ ( R ) {\displaystyle C^{*}(\mathbb {R} )} to C 0 ( R ) , {\displaystyle C_{0}(\mathbb {R} ),} the C ∗ {\displaystyle C^{*}} -algebra of continuous complex-valued functions on the real line that vanish at infinity. Hence, there is a one-to-one correspondence between strongly continuous one-parameter unitary groups and *-representations of C 0 ( R ) . {\displaystyle C_{0}(\mathbb {R} ).} As every *-representation of C 0 ( R ) {\displaystyle C_{0}(\mathbb {R} )} corresponds uniquely to a self-adjoint operator, Stone's Theorem holds.
Therefore, the procedure for obtaining the infinitesimal generator of a strongly continuous one-parameter unitary group is as follows:
The precise definition of C ∗ ( R ) {\displaystyle C^{*}(\mathbb {R} )} is as follows. Consider the *-algebra C c ( R ) , {\displaystyle C_{c}(\mathbb {R} ),} the continuous complex-valued functions on R {\displaystyle \mathbb {R} } with compact support, where the multiplication is given by convolution. The completion of this *-algebra with respect to the L 1 {\displaystyle L^{1}} -norm is a Banach *-algebra, denoted by ( L 1 ( R ) , ⋆ ) . {\displaystyle (L^{1}(\mathbb {R} ),\star ).} Then C ∗ ( R ) {\displaystyle C^{*}(\mathbb {R} )} is defined to be the enveloping C ∗ {\displaystyle C^{*}} -algebra of ( L 1 ( R ) , ⋆ ) {\displaystyle (L^{1}(\mathbb {R} ),\star )} , i.e., its completion with respect to the largest possible C ∗ {\displaystyle C^{*}} -norm. It is a non-trivial fact that, via the Fourier transform, C ∗ ( R ) {\displaystyle C^{*}(\mathbb {R} )} is isomorphic to C 0 ( R ) . {\displaystyle C_{0}(\mathbb {R} ).} A result in this direction is the Riemann-Lebesgue Lemma, which says that the Fourier transform maps L 1 ( R ) {\displaystyle L^{1}(\mathbb {R} )} to C 0 ( R ) . {\displaystyle C_{0}(\mathbb {R} ).}
The Stone–von Neumann theorem generalizes Stone's theorem to a pair of self-adjoint operators, ( P , Q ) {\displaystyle (P,Q)} , satisfying the canonical commutation relation, and shows that these are all unitarily equivalent to the position operator and momentum operator on L 2 ( R ) . {\displaystyle L^{2}(\mathbb {R} ).}
The Hille–Yosida theorem generalizes Stone's theorem to strongly continuous one-parameter semigroups of contractions on Banach spaces.
Hall 2013 Theorem 10.15 - Hall, B.C. (2013), Quantum Theory for Mathematicians, Graduate Texts in Mathematics, vol. 267, Springer, Bibcode:2013qtm..book.....H, ISBN 978-1461471158 https://ui.adsabs.harvard.edu/abs/2013qtm..book.....H ↩