Bromine dioxide is formed when an electric current is passed through a mixture of bromine and oxygen gases at low temperature and pressure.4
Bromine dioxide can also be formed by the treatment of bromine gas with ozone in trichlorofluoromethane at −50 °C.5
When mixed with a base, bromine dioxide gives the bromide and bromate anions:6
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Perry, Dale L.; Phillips, Sidney L. (1995), Handbook of Inorganic Compounds, CRC Press, p. 74, ISBN 0-8493-8671-3, retrieved 17 March 2009 0-8493-8671-3 ↩
Müller, Holger S. P.; Miller, Charles E.; Cohen, Edward A. (1997). "The rotational spectrum and molecular properties of bromine dioxide, OBrO". The Journal of Chemical Physics. 107 (20): 8292. Bibcode:1997JChPh.107.8292M. doi:10.1063/1.475030. ISSN 0021-9606. /wiki/Bibcode_(identifier) ↩
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