Amadori rearrangement

<h2 id="food-chemistry">Food chemistry</h2>
<p>The reaction is associated with the amino-carbonyl reactions (also called glycation reaction, or <a href="/facts/Maillard_reaction/7vtYtpGk">Maillard reaction</a>)<a class="footnote-ref" id="fnref:3" href="#fn:3"><sup>3</sup></a> in which the reagents are naturally occurring sugars and <a href="/facts/Amino_acid/WDxYwBny">amino acids</a>. One study demonstrated  the possibility of Amadori rearrangement during interaction between oxidized dextran and gelatine.<a class="footnote-ref" id="fnref:4" href="#fn:4"><sup>4</sup></a>
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<h2 id="history">History</h2>
<p>The Amadori rearrangement was discovered by the organic chemist Mario Amadori (1886–1941), who in 1925 reported this reaction while studying the <a href="/facts/Maillard_reaction/7vtYtpGk">Maillard reaction</a>.<a class="footnote-ref" id="fnref:5" href="#fn:5"><sup>5</sup></a><a class="footnote-ref" id="fnref:6" href="#fn:6"><sup>6</sup></a>
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<h2 id="see-also">See also</h2>
<ul><li><a href="/facts/Fructoselysine/fnu7G76o">Fructoselysine</a>, the Amadori product derived from glucose and lysine</li>
<li><a href="/facts/Glycated_hemoglobin/jTNaU7Jv">Glycated hemoglobin</a>, the Amadori product used in the HbA1c diagnostic test for diabetes</li></ul>

<h2 id="external-links">External links</h2>
<ul><li><a href="https://web.archive.org/web/20061028061710/http://www.cfs.purdue.edu/class/f%26n630/amadori_rearrangement.ppt">Amadori Rearrangement</a>, PowerPoint presentation detailing the reaction mechanism</li></ul>

<h2 id="references">References</h2>

<ol>
<li id="fn:1"><p>Strategic Applications of Named Reactions in Organic Synthesis (Paperback) by Laszlo Kurti,  BN 0-12-429785-4 <a href="#fnref:1" class="footnote-back-ref">↩</a></p></li>
<li id="fn:2"><p>Koenig, R. J.; Cerami, A. (1980). "Hemoglobin A Ic and diabetes mellitus". Annual Review of Medicine. 31: 29–34. doi:10.1146/annurev.me.31.020180.000333. PMID 6994614. <a href="/wiki/Doi_(identifier)" target="_blank">/wiki/Doi_(identifier)</a> <a href="#fnref:2" class="footnote-back-ref">↩</a></p></li>
<li id="fn:3"><p>This vo Kientza, Hervé. "IMARS Highligh". www.imarsonline.com/. <a href="https://www.imarsonline.com/" target="_blank">https://www.imarsonline.com/</a> <a href="#fnref:3" class="footnote-back-ref">↩</a></p></li>
<li id="fn:4"><p>Berillo, Dmitriy; Natalia Volkova (2014). "Preparation and physicochemical characteristics of cryogel based on gelatin and oxidised dextran". Journal of Materials Science. 49 (14): 4855–4868. Bibcode:2014JMatS..49.4855B. doi:10.1007/s10853-014-8186-3. S2CID 96843083. <a href="/wiki/Bibcode_(identifier)" target="_blank">/wiki/Bibcode_(identifier)</a> <a href="#fnref:4" class="footnote-back-ref">↩</a></p></li>
<li id="fn:5"><p>M. Amadori, Atti. reale accad. nazl. Lincei, [6] 2, 337 (1925); [6] 9, 68, 226 (1929); [6] 13, 72 (1931) <a href="#fnref:5" class="footnote-back-ref">↩</a></p></li>
<li id="fn:6"><p>Strategic Applications of Named Reactions in Organic Synthesis (Paperback) by Laszlo Kurti,  BN 0-12-429785-4 <a href="#fnref:6" class="footnote-back-ref">↩</a></p></li>
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Amadori rearrangement open-in-new

Amadori rearrangement