Hall–Héroult process

<h2 id="process">Process</h2>
<h3>Difficulties faced</h3>
Elemental aluminium cannot be produced by the electrolysis of an <a href="/facts/Aqueous_solution/eRNr3MH2">aqueous</a> <a href="/facts/Aluminium_salt/7wmR8jYE">aluminium salt</a>, because <a href="/facts/Hydronium/HzE3BGYJ">hydronium</a> ions readily <a href="/facts/Redox/Pyd5RVcj">oxidize</a> elemental aluminium. Although a <a href="/facts/Molten_salt/b1vjSkwP">molten</a> aluminium salt could be used instead, <a href="/facts/Aluminium_oxide/wXM9P6pI">aluminium oxide</a> has a melting point of 2072 °C (3762°F)<a class="footnote-ref" id="fnref:4" href="#fn:4">4</a> so electrolysing it is impractical. In the Hall–Héroult process, alumina, Al2O3, is dissolved in molten synthetic <a href="/facts/Cryolite/AFPScQqQ">cryolite</a>, Na3AlF6, to lower its melting point for easier electrolysis.<a class="footnote-ref" id="fnref:5" href="#fn:5">5</a> The carbon source is generally a <a href="/facts/Coke_(fuel)/vD8xjd0m">coke (fossil fuel)</a>.<a class="footnote-ref" id="fnref:6" href="#fn:6">6</a>

<h3>Theory</h3>

In the Hall–Héroult process the following simplified reactions take place at the carbon electrodes:
<a href="/facts/Cathode/tqdlGayU">Cathode</a>:

Al3+ + 3 <a href="/facts/Electron/L0KBo5cW">e−</a> → Al
<a href="/facts/Anode/TjYt95zG">Anode</a>:

O2- + C → <a href="/facts/Carbon_monoxide/CKuLtEMJ">CO</a> + 2 e−
Overall:

Al2O3 + 3 C → 2 Al + 3 CO
In reality, much more <a href="/facts/Carbon_dioxide/xGzpppEp">CO2</a> is formed at the anode than CO:

2 O2- + C → <a href="/facts/Carbon_dioxide/xGzpppEp">CO2</a> + 4 e−
2 Al2O3 + 3 C → 4 Al + 3 CO2
Pure cryolite has a melting point of 1009±1 °C (1848°F). With a small percentage of alumina dissolved in it, its <a href="/facts/Freezing-point_depression/B5fSARUv">melting point drops</a> to about 1000 °C (1832°F). Besides having a relatively low melting point, cryolite is used as an electrolyte because, among other things, it also dissolves alumina well, conducts electricity, dissociates electrolytically at higher voltage than alumina, and is less dense than aluminum at the temperatures required by the electrolysis.<a class="footnote-ref" id="fnref:7" href="#fn:7">7</a>
<a href="/facts/Aluminium_fluoride/psF0WEqn">Aluminium fluoride</a> (AlF3) is usually added to the electrolyte. The ratio NaF/AlF3 is called the cryolite ratio and it is 3 in pure cryolite. In industrial production, AlF3 is added so that the cryolite ratio is 2–3 to further reduce the melting point, so that the electrolysis can happen at temperatures between 940 and 980 °C (1700 to 1800°F). The density of liquid aluminum is 2.3 g/ml at temperatures between 950 and 1000 °C (1750° to 1830°F). The density of the electrolyte should be less than 2.1 g/ml, so that the molten aluminum separates from the electrolyte and settles properly to the bottom of the electrolysis cell. In addition to AlF3, other additives like <a href="/facts/Lithium_fluoride/ujl6o884">lithium fluoride</a> may be added to alter different properties (melting point, density, conductivity etc.) of the electrolyte.<a class="footnote-ref" id="fnref:8" href="#fn:8">8</a>
The mixture is electrolysed by passing a low voltage (under 5 V) <a href="/facts/Electric_current/Dc1xdnUX">direct current</a> at 100–300 kA through it. This causes liquid aluminium to be deposited at the <a href="/facts/Cathode/tqdlGayU">cathode</a>, while the oxygen from the alumina combines with carbon from the <a href="/facts/Anode/TjYt95zG">anode</a> to produce mostly carbon dioxide.<a class="footnote-ref" id="fnref:9" href="#fn:9">9</a>
The theoretical minimum energy requirement for this process is 6.23 kWh/(kg of Al), but it commonly requires 15.37 kWh.<a class="footnote-ref" id="fnref:10" href="#fn:10">10</a>

<h3>Cell operation</h3>
Cells in factories are operated 24 hours per day so that the molten material in them will not solidify. Temperature within the cell is maintained via electrical resistance. Oxidation of the carbon <a href="/facts/Anode/TjYt95zG">anode</a> increases the electrical efficiency at a cost of consuming the carbon electrodes and producing carbon dioxide.<a class="footnote-ref" id="fnref:11" href="#fn:11">11</a>
While solid cryolite is <a href="/facts/Density/92p6hh9I">denser</a> than solid aluminium at room temperature, liquid aluminium is denser than molten cryolite at temperatures around 1,000 °C (1,830 °F). The aluminium sinks to the bottom of the electrolytic cell, where it is periodically collected. The liquid aluminium is <a href="/facts/Siphon/aEh4Ptkw">siphoned</a> every 1 to 3 days to avoid having to use extremely high temperature valves and pumps. Alumina is added to the cells as the aluminum is removed. Collected aluminium from different cells in a factory is finally melted together to ensure uniform product and made into metal sheets. The electrolytic mixture is sprinkled with coke to prevent the anode's oxidation by the oxygen involved.<a class="footnote-ref" id="fnref:12" href="#fn:12">12</a>
The cell produces gases at the anode, primarily CO2 produced from anode consumption and <a href="/facts/Hydrogen_fluoride/XfQxlqR6">hydrogen fluoride</a> (HF) from the cryolite and <a href="/facts/Flux_(metallurgy)/ruKFTPGD">flux</a> (AlF3). In modern facilities, fluorides are almost completely recycled to the cells and therefore used again in the electrolysis. Escaped HF can be neutralized to its sodium salt, <a href="/facts/Sodium_fluoride/HHcvwK7s">sodium fluoride</a>. <a href="/facts/Particulate/RleGr5E6">Particulates</a> are captured using <a href="/facts/Electrostatic_filter/mLPvIkah">electrostatic</a> or bag filters. The CO2 is usually vented into the atmosphere.<a class="footnote-ref" id="fnref:13" href="#fn:13">13</a>
Agitation of the molten material in the cell increases its production rate at the expense of an increase in cryolite impurities in the product. Properly designed cells can leverage <a href="/facts/Magnetohydrodynamics/7mQbJPPD">magnetohydrodynamic</a> forces induced by the electrolysing current to agitate the electrolyte. In non-agitating static pool cells, the impurities either rise to the top of the metallic aluminium, or sink to the bottom, leaving high-purity aluminium in the middle area.<a class="footnote-ref" id="fnref:14" href="#fn:14">14</a>

<h3>Electrodes</h3>
Electrodes in cells are mostly <a href="/facts/Coke_(fuel)/vD8xjd0m">coke</a> which has been purified at high temperatures. <a href="/facts/Pitch_(resin)/GpdKnQMa">Pitch resin</a> or <a href="/facts/Tar/7SplkFWL">tar</a> is used as a binder. The materials most often used in anodes, coke and pitch resin, are mainly residues from the petroleum industry and need to be of high enough purity so no impurities end up into the molten aluminum or the electrolyte.<a class="footnote-ref" id="fnref:15" href="#fn:15">15</a>
There are two primary anode technologies using the Hall–Héroult process: Söderberg technology and prebaked technology.
In cells using Söderberg or self-baking anodes, there is a single anode per electrolysis cell. The anode is contained within a frame and, as the bottom of the anode turns mainly into CO2 during the electrolysis, the anode loses mass and, being <a href="/facts/Amorphous_solid/YTIzmrR0">amorphous</a>, it slowly sinks within its frame. More material to the top of the anode is continuously added in the form of briquettes made from coke and pitch. The lost heat from the smelting operation is used to bake the briquettes into the carbon form required for the reaction with alumina. The baking process in Söderberg anodes during electrolysis releases more <a href="/facts/Carcinogen/soH8Y9CE">carcinogenic</a> <a href="/facts/Polycyclic_aromatic_hydrocarbon/K52xSfNC">PAHs</a> and other pollutants than electrolysis with prebaked anodes and, partially for this reason, prebaked anode-using cells have become more common in the aluminium industry. More alumina is added to the electrolyte from the sides of the Söderberg anode after the crust on top of the electrolyte mixture is broken.<a class="footnote-ref" id="fnref:16" href="#fn:16">16</a>
Prebaked anodes are baked in very large gas-fired ovens at high temperature before being lowered by various heavy industrial lifting systems into the electrolytic solution. There are usually 24 prebaked anodes in two rows per cell. Each anode is lowered vertically and individually by a computer, as the bottom surfaces of the anodes are eaten away during the electrolysis. Compared to Söderberg anodes, computer-controlled prebaked anodes can be brought closer to the molten aluminium layer at the bottom of the cell without any of them touching the layer and interfering with the electrolysis. This smaller distance decreases the resistance caused by the electrolyte mixture and increases the efficiency of prebaked anodes over Söderberg anodes. Prebake technology also has much lower risk of the anode effect (see below), but cells using it are more expensive to build and labor-intensive to use, as each prebaked anode in a cell needs to be removed and replaced once it has been used. Alumina is added to the electrolyte from between the anodes in prebake cells.<a class="footnote-ref" id="fnref:17" href="#fn:17">17</a>
Prebaked anodes contain a smaller percentage of pitch, as they need to be more solid than Söderberg anodes. The remains of prebaked anodes are used to make more new prebaked anodes. Prebaked anodes are either made in the same factory where electrolysis happens, or are brought there from elsewhere.<a class="footnote-ref" id="fnref:18" href="#fn:18">18</a>
The inside of the cell's bath is lined with cathode made from coke and pitch. Cathodes also degrade during electrolysis, but much more slowly than anodes do, so their purity and maintenance requirements are lower than the anodes. Cathodes are typically replaced every 2–6 years. This requires the whole cell to be shut down.<a class="footnote-ref" id="fnref:19" href="#fn:19">19</a>

<h3>Anode effect</h3>
The anode effect is a situation where too many gas bubbles form at the bottom of the anode and join, forming a layer. This increases the resistance of the cell, because smaller areas of the electrolyte touch the anode. These areas of the electrolyte and anode heat up when the density of the electric current of the cell focuses to go through only them. This heats up the gas layer and causes it to expand, thus further reducing the surface area where electrolyte and anode are in contact with each other. The anode effect decreases the energy-efficiency and the aluminium production of the cell. It also induces the formation of <a href="/facts/Tetrafluoromethane/gEGAWJnz">tetrafluoromethane</a> (CF4) in significant quantities, increases formation of CO and, to a lesser extent, also causes the formation of <a href="/facts/Hexafluoroethane/MIzBtCpY">hexafluoroethane</a> (C2F6). CF4 and C2F6 are not <a href="/facts/Chlorofluorocarbon/uLApxm7K">CFCs</a>, and, although not detrimental to the <a href="/facts/Ozone_layer/v4KfjalC">ozone layer</a>, are still potent <a href="/facts/Greenhouse_gas/HXaHqrT8">greenhouse gases</a>. The anode effect is mainly a problem in Söderberg technology cells, not in prebaked.<a class="footnote-ref" id="fnref:20" href="#fn:20">20</a>

<h2 id="history">History</h2>
<h3>Existing need</h3>
Aluminium is the most abundant <a href="/facts/Metal/pqQVs8QU">metallic element</a> in the Earth's crust, but it is rarely found in its <a href="/facts/Native_aluminium/C5Fk8Lo1">elemental state</a>. It occurs in many minerals, but its primary commercial source is <a href="/facts/Bauxite/CJ10QPc6">bauxite</a>, a mixture of hydrated aluminium oxides and compounds of other elements such as iron.
Prior to the Hall–Héroult process, elemental aluminium was made by heating ore along with elemental <a href="/facts/Sodium/eYuSPu2V">sodium</a> or <a href="/facts/Potassium/5lcumVgo">potassium</a> in a <a href="/facts/Vacuum/BTk3goyV">vacuum</a>. The method was complicated and consumed materials that were in themselves expensive at that time. This meant that the cost to produce the small amount of aluminium made in the early 19th century was very high, higher than for <a href="/facts/Gold/1znknojp">gold</a> or <a href="/facts/Platinum/qJC6lQf7">platinum</a>.<a class="footnote-ref" id="fnref:21" href="#fn:21">21</a> Bars of aluminium were exhibited alongside the French <a href="/facts/Crown_jewels/tEaaw4Ip">crown jewels</a> at the <a href="/facts/Exposition_Universelle_(1855)/xwc295r8">Exposition Universelle of 1855</a>, and <a href="/facts/Napoleon_III_of_France/F29546rc">Emperor Napoleon III</a> of France was said to have reserved his few sets of aluminium dinner plates and eating utensils for his most honored guests.<a class="footnote-ref" id="fnref:22" href="#fn:22">22</a><a class="footnote-ref" id="fnref:23" href="#fn:23">23</a><a class="footnote-ref" id="fnref:24" href="#fn:24">24</a>
Production costs using older methods did come down, but when aluminium was selected as the material for the cap/lightning rod to sit atop the <a href="/facts/Washington_Monument/3Ir2QT65">Washington Monument</a> in <a href="/facts/Washington%2c_D.C./enXPK156">Washington, D.C.</a> upon its completion in 1884, it was still more expensive than <a href="/facts/Silver/xXe41BGg">silver</a>.<a class="footnote-ref" id="fnref:25" href="#fn:25">25</a>

<h3>Independent discovery</h3>
The Hall–Héroult process was invented independently and almost simultaneously in 1886 by the <a href="/facts/United_States/P0sCdLe5">American</a> chemist <a href="/facts/Charles_Martin_Hall/FHavM9eo">Charles Martin Hall</a><a class="footnote-ref" id="fnref:26" href="#fn:26">26</a> and by the <a href="/facts/France/CxIeIKM3">Frenchman</a> <a href="/facts/Paul_H%25C3%25A9roult/tPLhnYVr">Paul Héroult</a><a class="footnote-ref" id="fnref:27" href="#fn:27">27</a>—both 22 years old. Some authors claim Hall was assisted by his sister <a href="/facts/Julia_Brainerd_Hall/aKtWM54z">Julia Brainerd Hall</a>;<a class="footnote-ref" id="fnref:28" href="#fn:28">28</a> however, the extent to which she was involved has been disputed.<a class="footnote-ref" id="fnref:29" href="#fn:29">29</a><a class="footnote-ref" id="fnref:30" href="#fn:30">30</a> In 1888, Hall opened the first large-scale aluminium production plant in <a href="/facts/Pittsburgh/42yPHyS0">Pittsburgh</a>. It later became the <a href="/facts/Alcoa/857N3lgp">Alcoa</a> corporation.
In 1997, the Hall–Héroult process was designated a <a href="/facts/National_Historic_Chemical_Landmarks/1ocK4A6d">National Historic Chemical Landmark</a> by the <a href="/facts/American_Chemical_Society/Alf3uhaF">American Chemical Society</a> in recognition of the importance of the process in the commercialization of aluminum.<a class="footnote-ref" id="fnref:31" href="#fn:31">31</a>

<h3>Economic impact</h3>
Aluminium produced via the Hall–Héroult process, in combination with cheaper <a href="/facts/Electric_power/w61ID9yQ">electric power</a>, helped make aluminium (and incidentally <a href="/facts/Magnesium/XyIhd2FG">magnesium</a>) an inexpensive commodity rather than a precious metal.
This, in turn, helped make it possible for pioneers like <a href="/facts/Hugo_Junkers/QqVlgtYc">Hugo Junkers</a> to utilize aluminium and <a href="/facts/Magnesium_alloy/mmKDGhDL">aluminium-magnesium alloys</a> to make items like metal airplanes by the thousands, or Howard Lund to make aluminium fishing boats.<a class="footnote-ref" id="fnref:32" href="#fn:32">32</a> In 2012 it was estimated that 12.7 tons of CO2 emissions are generated per ton of aluminium produced.<a class="footnote-ref" id="fnref:33" href="#fn:33">33</a>
In the 20th and 21st century the aluminum industry due to its large-scale requirements for cheap electricity has often been sited in locations where such electricity is available. For example Iceland, a country with no notable bauxite reserves and <a href="/facts/Demographics_of_Iceland/cyduLdaz">a population</a> of less than half a million, is the world's <a href="/facts/List_of_countries_by_aluminium_production/BMjMldop">twelfth largest aluminum producer</a> due to the availability of <a href="/facts/Energy_in_Iceland/30gxA7zW">cheap and plentiful</a> electricity, particularly <a href="/facts/Hydropower_in_Iceland/30gxA7zW">hydropower</a>. Similarly <a href="/facts/Aluminerie_Alouette/aAfbxaxx">Aluminerie Alouette</a> in <a href="/facts/Sept-%25C3%258Eles%2c_Quebec/N8Fmzrf9">Sept-Îles, Quebec</a> is dependent for its electricity needs on the 5,428 MW <a href="/facts/Churchill_Falls_Generating_Station/9lxdGJws">Churchill Falls Generating Station</a> operated by <a href="/facts/Churchill_Falls_(Labrador)_Corporation_Limited/YbX6SQkC">Churchill Falls (Labrador) Corporation Limited</a>. The <a href="/facts/Company_town/fcQbCyrI">company town</a> of <a href="/facts/Kitimat/Bus5PKcT">Kitimat</a> in <a href="/facts/British_Columbia/Ty3e3g1Q">British Columbia</a> was built by <a href="/facts/Alcan/lmAfy37f">Alcan</a> to meet the growing demand for aluminum in the postwar era. It makes use of the <a href="/facts/Kenney_Dam/mjeeqVhj">Kenney Dam</a> built to power the smelters. The <a href="/facts/Tiwai_Point_Aluminium_Smelter/90NsmzD5">Tiwai Point Aluminium Smelter</a> on the South Island of <a href="/facts/New_Zealand/4mpSlJdg">New Zealand</a> consumes some 570 MW of electricity, most of which is supplied by nearby <a href="/facts/Manap%25C5%258Duri_Power_Station/ru8tCyGs">Manapōuri Power Station</a>. This amounts to around a third of the electricity demand of South Island and 13% of that of the entirety of New Zealand. <a href="/facts/Borssele_Nuclear_Power_Station/4dPsvcGQ">Borssele Nuclear Power Station</a> was built primarily to supply electricity to an aluminum smelter operated by French <a href="/facts/Pechiney/rBN5UDUF">Pechiney</a> at the time.

<h2 id="see-also">See also</h2>
<ul><li><a href="/facts/Bayer_process/HH5NoTvu">Bayer process</a></li>
<li><a href="/facts/History_of_aluminium/eUEE3YA1">History of aluminium</a></li>
<li><a href="/facts/Tantalum/VwaxMm33">Solid oxide Hall–Héroult process</a></li>
<li><a href="/facts/Hoopes_process/6dGcL9rk">Hoopes process</a></li>
<li><a href="/facts/Downs_cell/o0hNyHGo">Downs cell</a></li></ul>

<h2 id="further-reading">Further reading</h2>
<ul><li>Grjotheim, U and Kvande, H., <a href="http://www.csa.com/partners/viewrecord.php?requester=gs&collection=TRD&recid=199501420050MD&recid=199501P10015AI">Introduction to Aluminium Electrolysis. Understanding the Hall–Heroult Process</a>, Aluminium Verlag GmbH, (Germany), 1993, pp. 260.</li>
<li>Prasad, Shiva (May–June 2000). <a href="https://doi.org/10.1590%2FS0103-50532000000300008">"Studies on the Hall-Heroult Aluminum Electrowinning Process"</a>. Journal of the Brazilian Chemical Society. 11 (3): 245–251. <a href="/facts/Doi_(identifier)/muM9Etpq">doi</a>:<a href="https://doi.org/10.1590%2FS0103-50532000000300008">10.1590/S0103-50532000000300008</a>.</li></ul>

<h2 id="references">References</h2>

<ol>
<li id="fn:1">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:1" class="footnote-back-ref">↩</a></li>
<li id="fn:2">Khaji, Khalil; Al Qassemi, Mohammed (2016). "The Role of Anode Manufacturing Processes in Net Carbon Consumption". Metals. 6 (6): 128. doi:10.3390/met6060128. <a href="https://doi.org/10.3390%2Fmet6060128" target="_blank">https://doi.org/10.3390%2Fmet6060128</a> <a href="#fnref:2" class="footnote-back-ref">↩</a></li>
<li id="fn:3">Marks, Jerry; Roberts, Ruth; Bakshi, Vikram; Dolin, Eric (January 2000). "Perfluorocarbon (PFC) Generation During Primary Aluminum Production" (PDF). <a href="https://www.epa.gov/sites/default/files/2016-02/documents/pfc_generation.pdf" target="_blank">https://www.epa.gov/sites/default/files/2016-02/documents/pfc_generation.pdf</a> <a href="#fnref:3" class="footnote-back-ref">↩</a></li>
<li id="fn:4">Haynes, W.M. (2015). CRC Handbook of Chemistry and Physics (96th ed.). Boca Raton, FL: Taylor & Francis. ISBN 978-1-4822-6096-0. <a href="978-1-4822-6096-0" target="_blank">978-1-4822-6096-0</a> <a href="#fnref:4" class="footnote-back-ref">↩</a></li>
<li id="fn:5">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:5" class="footnote-back-ref">↩</a></li>
<li id="fn:6">Khaji, Khalil; Al Qassemi, Mohammed (2016). "The Role of Anode Manufacturing Processes in Net Carbon Consumption". Metals. 6 (6): 128. doi:10.3390/met6060128. <a href="https://doi.org/10.3390%2Fmet6060128" target="_blank">https://doi.org/10.3390%2Fmet6060128</a> <a href="#fnref:6" class="footnote-back-ref">↩</a></li>
<li id="fn:7">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:7" class="footnote-back-ref">↩</a></li>
<li id="fn:8">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:8" class="footnote-back-ref">↩</a></li>
<li id="fn:9">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:9" class="footnote-back-ref">↩</a></li>
<li id="fn:10">Obaidat, Mazin; Al-Ghandoor, Ahmed; Phelan, Patrick; Villalobos, Rene; Alkhalidi, Ammar (17 April 2018). "Energy and Exergy Analyses of Different Aluminum Reduction Technologies". Sustainability. 10 (4): 1216. Bibcode:2018Sust...10.1216O. doi:10.3390/su10041216. <a href="https://doi.org/10.3390%2Fsu10041216" target="_blank">https://doi.org/10.3390%2Fsu10041216</a> <a href="#fnref:10" class="footnote-back-ref">↩</a></li>
<li id="fn:11">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:11" class="footnote-back-ref">↩</a></li>
<li id="fn:12">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:12" class="footnote-back-ref">↩</a></li>
<li id="fn:13">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:13" class="footnote-back-ref">↩</a></li>
<li id="fn:14">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:14" class="footnote-back-ref">↩</a></li>
<li id="fn:15">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:15" class="footnote-back-ref">↩</a></li>
<li id="fn:16">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:16" class="footnote-back-ref">↩</a></li>
<li id="fn:17">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:17" class="footnote-back-ref">↩</a></li>
<li id="fn:18">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:18" class="footnote-back-ref">↩</a></li>
<li id="fn:19">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:19" class="footnote-back-ref">↩</a></li>
<li id="fn:20">Totten, George E.; MacKenzie, D. Scott (2003). Handbook of Aluminum: Volume 2: Alloy production and materials manufacturing. New York, NY: Marcel Dekker, Inc. ISBN 0-8247-0896-2. <a href="0-8247-0896-2" target="_blank">0-8247-0896-2</a> <a href="#fnref:20" class="footnote-back-ref">↩</a></li>
<li id="fn:21">Kean, Sam (2010-07-30). "Aluminum: It Used To Be More Precious Than Gold". Slate Magazine. Retrieved 2024-02-23. <a href="http://www.slate.com/articles/health_and_science/elements/features/2010/blogging_the_periodic_table/aluminum_it_used_to_be_more_precious_than_gold.html" target="_blank">http://www.slate.com/articles/health_and_science/elements/features/2010/blogging_the_periodic_table/aluminum_it_used_to_be_more_precious_than_gold.html</a> <a href="#fnref:21" class="footnote-back-ref">↩</a></li>
<li id="fn:22">"When Aluminum Plates Were Cool". Los Angeles Times. 5 September 2001. <a href="https://www.latimes.com/archives/la-xpm-2001-sep-05-fo-42149-story.html" target="_blank">https://www.latimes.com/archives/la-xpm-2001-sep-05-fo-42149-story.html</a> <a href="#fnref:22" class="footnote-back-ref">↩</a></li>
<li id="fn:23">"Did Napoleon III reserve a special set of aluminum cutlery for special guests?". <a href="https://www.hollymelody.com/history/9/did-napoleon-iii-reserve-a-special-set-of-aluminum-cutlery-for-special-guests" target="_blank">https://www.hollymelody.com/history/9/did-napoleon-iii-reserve-a-special-set-of-aluminum-cutlery-for-special-guests</a> <a href="#fnref:23" class="footnote-back-ref">↩</a></li>
<li id="fn:24">https://www.alcirclebiz.com/blogs/from-emperors-table-to-the-moon-the-fascinating-history-of-aluminium <a href="https://www.alcirclebiz.com/blogs/from-emperors-table-to-the-moon-the-fascinating-history-of-aluminium" target="_blank">https://www.alcirclebiz.com/blogs/from-emperors-table-to-the-moon-the-fascinating-history-of-aluminium</a> <a href="#fnref:24" class="footnote-back-ref">↩</a></li>
<li id="fn:25">George J. Binczewski (1995). "The Point of a Monument: A History of the Aluminum Cap of the Washington Monument". JOM. 47 (11): 20–25. Bibcode:1995JOM....47k..20B. doi:10.1007/BF03221302. S2CID 111724924. <a href="http://www.tms.org/pubs/journals/JOM/9511/Binczewski-9511.html" target="_blank">http://www.tms.org/pubs/journals/JOM/9511/Binczewski-9511.html</a> <a href="#fnref:25" class="footnote-back-ref">↩</a></li>
<li id="fn:26">US patent 400664, Charles Martin Hall, "Process of Reducing Aluminium from its Fluoride Salts by Electrolysis", issued 1889-04-02
 <a href="https://worldwide.espacenet.com/textdoc?DB=EPODOC&IDX=US400664" target="_blank">https://worldwide.espacenet.com/textdoc?DB=EPODOC&IDX=US400664</a> <a href="#fnref:26" class="footnote-back-ref">↩</a></li>
<li id="fn:27">Héroult, Paul; French patent no. 175,711 (filed: 23 April 1886; issued: 1 September 1886). <a href="#fnref:27" class="footnote-back-ref">↩</a></li>
<li id="fn:28">Kass-Simon, Gabrielle; Farnes, Patricia; Nash, Deborah, eds. (1990). Women of Science: Righting the Record. Indiana University Press. pp. 173–176. ISBN 0-253-20813-0. <a href="0-253-20813-0" target="_blank">0-253-20813-0</a> <a href="#fnref:28" class="footnote-back-ref">↩</a></li>
<li id="fn:29">Sheller, Mimi (2014). Aluminum dreams : the making of light modernity. Cambridge, MA: MIT Press. p. 270. ISBN 978-0262026826. Retrieved 19 April 2016. <a href="978-0262026826" target="_blank">978-0262026826</a> <a href="#fnref:29" class="footnote-back-ref">↩</a></li>
<li id="fn:30">Giddens, Paul H. (1953). "Alcoa, An. American Enterprise. By Charles C. Carr. (Book review)". Pennsylvania History. 20 (2): 209–210. <a href="https://journals.psu.edu/phj/article/view/22279/22048" target="_blank">https://journals.psu.edu/phj/article/view/22279/22048</a> <a href="#fnref:30" class="footnote-back-ref">↩</a></li>
<li id="fn:31">"Production of Aluminum: The Hall–Héroult Process". National Historic Chemical Landmarks. American Chemical Society. Retrieved 2014-02-21. <a href="http://www.acs.org/content/acs/en/education/whatischemistry/landmarks/aluminumprocess.html" target="_blank">http://www.acs.org/content/acs/en/education/whatischemistry/landmarks/aluminumprocess.html</a> <a href="#fnref:31" class="footnote-back-ref">↩</a></li>
<li id="fn:32">"Lund Boat Company Founder Dies at 91". In-Depth Outdoors. October 24, 2003. <a href="https://www.in-depthoutdoors.com/community/forums/topic/ftlgeneral_69525/" target="_blank">https://www.in-depthoutdoors.com/community/forums/topic/ftlgeneral_69525/</a> <a href="#fnref:32" class="footnote-back-ref">↩</a></li>
<li id="fn:33">Das, Subodh (2012). "Achieving Carbon Neutrality in the Global Aluminum Industry". JOM. 64 (2): 285–290. Bibcode:2012JOM....64b.285D. doi:10.1007/s11837-012-0237-0. ISSN 1047-4838. S2CID 59383624. <a href="/wiki/Bibcode_(identifier)" target="_blank">/wiki/Bibcode_(identifier)</a> <a href="#fnref:33" class="footnote-back-ref">↩</a></li>
</ol>

Hall–Héroult process open-in-new

Hall–Héroult process