Because a parametric process prohibits a net change in the energy state of the system, parametric processes are "instantaneous". For example, if an atom absorbs a photon with energy E, the atom's energy increases by ΔE = E, but as a parametric process, the quantum state cannot change and thus the elevated energy state must be a temporary virtual state. By the Heisenberg Uncertainty Principle we know that ΔEΔt~ħ/2, thus the lifetime of a parametric process is roughly Δt~ħ/2ΔE, which is appreciably small for any non-zero ΔE.2
In a linear optical system the dielectric polarization, P, responds linearly to the presence of an electric field, E, and thus we can write
where ε0 is the electric constant, χ is the (complex) electric susceptibility, and nr(ni) is the real(imaginary) component of the refractive index of the medium. The effects of a parametric process will affect only nr, whereas a nonzero value of ni can only be caused by a non-parametric process.
Thus in linear optics a parametric process will act as a lossless dielectric with the following effects:
Alternatively, non-parametric processes often involve loss (or gain) and give rise to:
Main article: Nonlinear optics
In a nonlinear media, the dielectric polarization P responds nonlinearly to the electric field E of the light. As a parametric process is in general coherent, many parametric nonlinear processes will depend on phase matching and will usually be polarization dependent.
Sample parametric nonlinear processes:
Sample non-parametric nonlinear processes:
See Boyd 2008, pp. 13–15 1.2.10 Parametric versus Nonparametric Processes - Boyd, Robert (2008). "1.2.10 Parametric versus Nonparametric Processes". Nonlinear Optics (3rd ed.). Academic Press. pp. 13–15. ISBN 978-0-12-369470-6. https://books.google.com/books?id=uoRUi1Yb7ooC&pg=PA13 ↩