Atoms can organize in many ways which lead to many different orders and many different types of materials. Landau symmetry-breaking theory provides a general understanding of these different orders. It points out that different orders really correspond to different symmetries in the organizations of the constituent atoms. As a material changes from one order to another order (i.e., as the material undergoes a phase transition), what happens is that the symmetry of the organization of the atoms changes.
However, since the late 1980s, it has become gradually apparent that Landau symmetry-breaking theory may not describe all possible orders. In an attempt to explain high temperature superconductivity the chiral spin state was introduced. At first, physicists still wanted to use Landau symmetry-breaking theory to describe the chiral spin state. They identified the chiral spin state as a state that breaks the time reversal and parity symmetries, but not the spin rotation symmetry. This should be the end of the story according to Landau's symmetry breaking description of orders. However, it was quickly realized that there are many different chiral spin states that have exactly the same symmetry, so symmetry alone was not enough to characterize different chiral spin states. This means that the chiral spin states contain a new kind of order that is beyond the usual symmetry description. The proposed, new kind of order was named "topological order". The name "topological order" is motivated by the low energy effective theory of the chiral spin states which is a topological quantum field theory (TQFT). New quantum numbers, such as ground state degeneracy (which can be defined on a closed space or an open space with gapped boundaries, including both Abelian topological orders and non-Abelian topological orders) and the non-Abelian geometric phase of degenerate ground states, were introduced to characterize and define the different topological orders in chiral spin states. More recently, it was shown that topological orders can also be characterized by topological entropy.
Although topologically ordered states usually appear in strongly interacting boson/fermion systems, a simple kind of topological order can also appear in free fermion systems. This kind of topological order corresponds to integral quantum Hall state, which can be characterized by the Chern number of the filled energy band if we consider integer quantum Hall state on a lattice. Theoretical calculations have proposed that such Chern numbers can be measured for a free fermion system experimentally.
It is also well known that such a Chern number can be measured (maybe indirectly) by edge states.
The most important characterization of topological orders would be the underlying fractionalized excitations (such as anyons) and their fusion statistics and braiding statistics (which can go beyond the quantum statistics of bosons or fermions). Current research works show that the loop and string like excitations exist for topological orders in the 3+1 dimensional spacetime, and their multi-loop/string-braiding statistics are the crucial signatures for identifying 3+1 dimensional topological orders. The multi-loop/string-braiding statistics of 3+1 dimensional topological orders can be captured by the link invariants of particular topological quantum field theory in 4 spacetime dimensions.
The collective motions of condensed strings give rise to excitations above the string-net condensed states. Those excitations turn out to be gauge bosons. The ends of strings are defects which correspond to another type of excitations. Those excitations are the gauge charges and can carry Fermi or fractional statistics.
We know that group theory is the mathematical foundation of symmetry-breaking orders. What is the mathematical foundation of topological order?
It was found that a subclass of 2+1D topological orders—Abelian topological orders—can be classified by a K-matrix approach. The string-net condensation suggests that tensor category (such as fusion category or monoidal category) is part of the mathematical foundation of topological order in 2+1D. The more recent researches suggest that
(up to invertible topological orders that have no fractionalized excitations):
Topological order in higher dimensions may be related to n-Category theory. Quantum operator algebra is a very important mathematical tool in studying topological orders.
The materials described by Landau symmetry-breaking theory have had a substantial impact on technology. For example, ferromagnetic materials that break spin rotation symmetry can be used as the media of digital information storage. A hard drive made of ferromagnetic materials can store gigabytes of information. Liquid crystals that break the rotational symmetry of molecules find wide application in display technology. Crystals that break translation symmetry lead to well defined electronic bands which in turn allow us to make semiconducting devices such as transistors. Different types of topological orders are even richer than different types of symmetry-breaking orders. This suggests their potential for exciting, novel applications.
One theorized application would be to use topologically ordered states as media for quantum computing in a technique known as topological quantum computing. A topologically ordered state is a state with complicated non-local quantum entanglement. The non-locality means that the quantum entanglement in a topologically ordered state is distributed among many different particles. As a result, the pattern of quantum entanglements cannot be destroyed by local perturbations. This significantly reduces the effect of decoherence. This suggests that if we use different quantum entanglements in a topologically ordered state to encode quantum information, the information may last much longer. The quantum information encoded by the topological quantum entanglements can also be manipulated by dragging the topological defects around each other. This process may provide a physical apparatus for performing quantum computations. Therefore, topologically ordered states may provide natural media for both quantum memory and quantum computation. Such realizations of quantum memory and quantum computation may potentially be made fault tolerant.
Topologically ordered states in general have a special property that they contain non-trivial boundary states. In many cases, those boundary states become perfect conducting channel that can conduct electricity without generating heat. This can be another potential application of topological order in electronic devices.
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Note that superconductivity can be described by the Ginzburg–Landau theory with dynamical U(1) EM gauge field, which is a Z2 gauge theory, that is, an effective theory of Z2 topological order. The prediction of the vortex state in superconductors was one of the main successes of Ginzburg–Landau theory with dynamical U(1) gauge field. The vortex in the gauged Ginzburg–Landau theory is nothing but the Z2 flux line in the Z2 gauge theory. The Ginzburg–Landau theory without the dynamical U(1) gauge field fails to describe the real superconductors with dynamical electromagnetic interaction.[8][25][26][27] However, in condensed matter physics, superconductor usually refers to a state with non-dynamical EM gauge field. Such a state is a symmetry breaking state with no topological order. /wiki/Ginzburg%E2%80%93Landau_theory
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Levin & Wen 2005a See also Levin & Wen 2006a - Levin, Michael; Wen, Xiao-Gang (2005a). "Colloquium: Photons and electrons as emergent phenomena". Reviews of Modern Physics. 77 (3): 871–9. arXiv:cond-mat/0407140. Bibcode:2005RvMP...77..871L. doi:10.1103/RevModPhys.77.871. S2CID 117563047. https://arxiv.org/abs/cond-mat/0407140