Tarnish is a product of a chemical reaction between a metal and a nonmetal compound, especially oxygen and sulfur dioxide. It is usually a metal oxide, the product of oxidation; sometimes it is a metal sulfide. The metal oxide sometimes reacts with water to make the hydroxide, or with carbon dioxide to make the carbonate. It is a chemical change. There are various methods to prevent metals from tarnishing.
Heavy tarnish can be mechanically removed by using tools such as a file or abrasive materials such as steel wool, sandpaper, emery paper, and heavy polishing compounds. Lighter tarnish may be abrasively removed with lighter polishing compounds or chemicals such as baking soda. Gentler abrasives, such as calcium carbonate, are often used by museums to clean tarnished silver, which will not scratch it or leave unwanted residues.4 Objects such as silverware may have their tarnish non-destructively reversed electrochemically by resting them on a piece of aluminium foil in a pot of boiling water with a small amount of salt or baking soda.56
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