The scalar potential is a useful quantity in describing the magnetic field, especially for permanent magnets.
Where there is no free current, ∇ × H = 0 , {\displaystyle \nabla \times \mathbf {H} =\mathbf {0} ,} so if this holds in simply connected domain we can define a magnetic scalar potential, ψ, as1 H = − ∇ ψ . {\displaystyle \mathbf {H} =-\nabla \psi .} The dimension of ψ in SI base units is A {\displaystyle {\mathsf {A}}} , which can be expressed in SI units as amperes.
Using the definition of H: ∇ ⋅ B = μ 0 ∇ ⋅ ( H + M ) = 0 , {\displaystyle \nabla \cdot \mathbf {B} =\mu _{0}\nabla \cdot \left(\mathbf {H} +\mathbf {M} \right)=0,} it follows that ∇ 2 ψ = − ∇ ⋅ H = ∇ ⋅ M . {\displaystyle \nabla ^{2}\psi =-\nabla \cdot \mathbf {H} =\nabla \cdot \mathbf {M} .}
Here, ∇ ⋅ M acts as the source for magnetic field, much like ∇ ⋅ P acts as the source for electric field. So analogously to bound electric charge, the quantity ρ m = − ∇ ⋅ M {\displaystyle \rho _{m}=-\nabla \cdot \mathbf {M} } is called the bound magnetic charge density. Magnetic charges q m = ∫ ρ m d V {\textstyle q_{m}=\int \rho _{m}\,dV} never occur isolated as magnetic monopoles, but only within dipoles and in magnets with a total magnetic charge sum of zero. The energy of a localized magnetic charge qm in a magnetic scalar potential is Q = μ 0 q m ψ , {\displaystyle Q=\mu _{0}\,q_{m}\psi ,} and of a magnetic charge density distribution ρm in space Q = μ 0 ∫ ρ m ψ d V , {\displaystyle Q=\mu _{0}\int \rho _{m}\psi \,dV,} where µ0 is the vacuum permeability. This is analog to the energy Q = q V E {\displaystyle Q=qV_{E}} of an electric charge q in an electric potential V E {\displaystyle V_{E}} .
If there is free current, one may subtract the contributions of free current per Biot–Savart law from total magnetic field and solve the remainder with the scalar potential method.
Vanderlinde 2005, pp. 194–199 - Vanderlinde, Jack (2005). Classical Electromagnetic Theory. Bibcode:2005cet..book.....V. doi:10.1007/1-4020-2700-1. ISBN 1-4020-2699-4. https://cds.cern.ch/record/1250088 ↩