In terms of DSPACE and NSPACE,
An example of an EXPSPACE-complete problem is the problem of recognizing whether two regular expressions represent different languages, where the expressions are limited to four operators: union, concatenation, the Kleene star (zero or more copies of an expression), and squaring (two copies of an expression).1
Alur and Henzinger extended linear temporal logic with times (integer) and prove that the validity problem of their logic is EXPSPACE-complete.2
Reasoning in the first-order theor of the real numbers with +, ×, = is in EXPSPACE and was conjectured to be EXPSPACE-complete in 1986.3
The coverability problem for Petri Nets is EXPSPACE-complete.4
The reachability problem for Petri nets was known to be EXPSPACE-hard for a long time,5 but shown to be nonelementary,6 so probably not in EXPSPACE. In 2022 it was shown to be Ackermann-complete.78
Meyer, A.R. and L. Stockmeyer. The equivalence problem for regular expressions with squaring requires exponential space. 13th IEEE Symposium on Switching and Automata Theory, Oct 1972, pp.125–129. /wiki/Larry_Stockmeyer ↩
Alur, Rajeev; Henzinger, Thomas A. (1994-01-01). "A Really Temporal Logic". J. ACM. 41 (1): 181–203. doi:10.1145/174644.174651. ISSN 0004-5411. https://doi.org/10.1145%2F174644.174651 ↩
Ben-Or, Michael; Kozen, Dexter; Reif, John (1986-04-01). "The complexity of elementary algebra and geometry". Journal of Computer and System Sciences. 32 (2): 251–264. doi:10.1016/0022-0000(86)90029-2. ISSN 0022-0000. https://www.sciencedirect.com/science/article/pii/0022000086900292 ↩
Charles Rackoff (1978). "The covering and boundedness problems for vector addition systems". Theoretical Computer Science: 223–231. ↩
Lipton, R. (1976). "The Reachability Problem Requires Exponential Space". Technical Report 62. Yale University. http://citeseer.ist.psu.edu/contextsummary/115623/0 ↩
Wojciech Czerwiński Sławomir Lasota Ranko S Lazić Jérôme Leroux Filip Mazowiecki (2019). "The reachability problem for Petri nets is not elementary". STOC 19. ↩
Leroux, Jerome (February 2022). "The Reachability Problem for Petri Nets is Not Primitive Recursive". 2021 IEEE 62nd Annual Symposium on Foundations of Computer Science (FOCS). IEEE. pp. 1241–1252. arXiv:2104.12695. doi:10.1109/FOCS52979.2021.00121. ISBN 978-1-6654-2055-6. 978-1-6654-2055-6 ↩
Brubaker, Ben (4 December 2023). "An Easy-Sounding Problem Yields Numbers Too Big for Our Universe". Quanta Magazine. https://www.quantamagazine.org/an-easy-sounding-problem-yields-numbers-too-big-for-our-universe-20231204/ ↩