Very roughly, the theory of a quantum Markov chain resembles that of a measure-many automaton, with some important substitutions: the initial state is to be replaced by a density matrix, and the projection operators are to be replaced by positive operator valued measures.
More precisely, a quantum Markov chain is a pair ( E , ρ ) {\displaystyle (E,\rho )} with ρ {\displaystyle \rho } a density matrix and E {\displaystyle E} a quantum channel such that
is a completely positive trace-preserving map, and B {\displaystyle {\mathcal {B}}} a C*-algebra of bounded operators. The pair must obey the quantum Markov condition, that
for all b 1 , b 2 ∈ B {\displaystyle b_{1},b_{2}\in {\mathcal {B}}} .