Carbon sequestration for climate change mitigation can involve either enhancing natural carbon sinks or employing technological methods to capture and store carbon.
For carbon to be sequestered artificially—that is, outside the natural processes of the carbon cycle—it must first be captured, or its release into the atmosphere must be significantly delayed or prevented. This can be achieved by incorporating carbon-rich materials into long-lasting applications, such as construction, thereby avoiding release through processes like combustion or decay. Thereafter it can be passively stored or remain productively utilized over time in a variety of ways. For instance, upon harvesting, wood (as a carbon-rich material) can be incorporated into construction or a range of other durable products, thus sequestering its carbon over years or even centuries. In industrial production, engineers typically capture carbon dioxide from emissions from power plants or factories.
An important consideration in such efforts is that forests can turn from sinks to carbon sources. In 2019 forests took up a third less carbon than they did in the 1990s, due to higher temperatures, droughts and deforestation. The typical tropical forest may become a carbon source by the 2060s.
Earth offers enough room to plant an additional 0.9 billion ha of tree canopy cover, although this estimate has been criticized, and the true area that has a net cooling effect on the climate when accounting for biophysical feedbacks like albedo is 20-80% lower. Planting and protecting these trees would sequester 205 billion tons of carbon if the trees survive future climate stress to reach maturity. To put this number into perspective, this is about 20 years of current global carbon emissions (as of 2019) . This level of sequestration would represent about 25% of the atmosphere's carbon pool in 2019.
Life expectancy of forests varies throughout the world, influenced by tree species, site conditions, and natural disturbance patterns. In some forests, carbon may be stored for centuries, while in other forests, carbon is released with frequent stand replacing fires. Forests that are harvested prior to stand replacing events allow for the retention of carbon in manufactured forest products such as lumber. However, only a portion of the carbon removed from logged forests ends up as durable goods and buildings. The remainder ends up as sawmill by-products such as pulp, paper, and pallets. If all new construction globally utilized 90% wood products, largely via adoption of mass timber in low rise construction, this could sequester 700 million net tons of carbon per year. This is in addition to the elimination of carbon emissions from the displaced construction material such as steel or concrete, which are carbon-intense to produce.
A meta-analysis found that mixed species plantations would increase carbon storage alongside other benefits of diversifying planted forests.
Although a bamboo forest stores less total carbon than a mature forest of trees, a bamboo plantation sequesters carbon at a much faster rate than a mature forest or a tree plantation. Therefore, the farming of bamboo timber may have significant carbon sequestration potential.
Impacts on temperature are affected by the location of the forest. For example, reforestation in boreal or subarctic regions has less impact on climate. This is because it substitutes a high-albedo, snow-dominated region with a lower-albedo forest canopy. By contrast, tropical reforestation projects lead to a positive change such as the formation of clouds. These clouds then reflect the sunlight, lowering temperatures.: 1457
Wetland restoration involves restoring a wetland's natural biological, geological, and chemical functions through re-establishment or rehabilitation. It is a good way to reduce climate change. Wetland soil, particularly in coastal wetlands such as mangroves, sea grasses, and salt marshes, is an important carbon reservoir; 20–30% of the world's soil carbon is found in wetlands, while only 5–8% of the world's land is composed of wetlands. Studies have shown that restored wetlands can become productive CO2 sinks and many are being restored. Aside from climate benefits, wetland restoration and conservation can help preserve biodiversity, improve water quality, and aid with flood control.
The plants that makeup wetlands absorb carbon dioxide (CO2) from the atmosphere and convert it into organic matter. The waterlogged nature of the soil slows down the decomposition of organic material, resulting in the accumulation of carbon-rich sediments, that ast as a long-term carbon sink. Additionally, anaerobic conditions in waterlogged soils hinder the complete breakdown of organic matter, promoting the conversion of carbon into more stable forms.
As with forests, for the sequestration process to succeed, the wetland must remain undisturbed. If it is disturbed the carbon stored in the plants and sediments will be released back into the atmosphere, and the ecosystem will no longer function as a carbon sink. Additionally, some wetlands can release non-CO2 greenhouse gases, such as methane and nitrous oxide which could offset potential climate benefits. The amounts of carbon sequestered via blue carbon by wetlands can also be difficult to measure.
Climate change could alter wetland soil carbon storage, changing it from a sink to a source.[obsolete source]With rising temperatures comes an increase in greenhouse gasses from wetlands especially locations with permafrost. When this permafrost melts it increases the available oxygen and water in the soil. Because of this, bacteria in the soil would create large amounts of carbon dioxide and methane to be released into the atmosphere.[obsolete source]
Peatlands grow steadily over thousands of years, accumulating dead plant material – and the carbon contained within it – due to waterlogged conditions which greatly slow rates of decay. If peatlands are drained, for farmland or development, the plant material stored within them decomposes rapidly, releasing stored carbon. These degraded peatlands account for 5-10% of global carbon emissions from human activities. The loss of one peatland could potentially produce more carbon than 175–500 years of methane emissions.
Peatland protection and restoration are therefore important measures to mitigate carbon emissions, and also provide benefits for biodiversity, freshwater provision, and flood risk reduction.
Compared to natural vegetation, cropland soils are depleted in soil organic carbon (SOC). When soil is converted from natural land or semi-natural land, such as forests, woodlands, grasslands, steppes, and savannas, the SOC content in the soil reduces by about 30–40%. This loss is due to harvesting, as plants contain carbon. When land use changes, the carbon in the soil will either increase or decrease, and this change will continue until the soil reaches a new equilibrium. Deviations from this equilibrium can also be affected by variated climate.
The decreasing of SOC content can be counteracted by increasing the carbon input. This can be done with several strategies, e.g. leave harvest residues on the field, use manure as fertilizer, or include perennial crops in the rotation. Perennial crops have a larger below-ground biomass fraction, which increases the SOC content.
Researchers have found that rising temperatures can lead to population booms in soil microbes, converting stored carbon into carbon dioxide. In laboratory experiments heating soil, fungi-rich soils released less carbon dioxide than other soils.
Following carbon dioxide (CO2) absorption from the atmosphere, plants deposit organic matter into the soil. This organic matter, derived from decaying plant material and root systems, is rich in carbon compounds. Microorganisms in the soil break down this organic matter, and in the process, some of the carbon becomes further stabilized in the soil as humus - a process known as humification.
On a global basis, it is estimated that soil contains about 2,500 gigatons of carbon.[contradictory]This is greater than 3-fold the carbon found in the atmosphere and 4-fold of that found in living plants and animals. About 70% of the global soil organic carbon in non-permafrost areas is found in the deeper soil within the upper metre and is stabilized by mineral-organic associations.
Burying biomass (such as trees) directly mimics the natural processes that created fossil fuels. The global potential for carbon sequestration using wood burial is estimated to be 10 ± 5 GtC/yr and largest rates in tropical forests (4.2 GtC/yr), followed by temperate (3.7 GtC/yr) and boreal forests (2.1 GtC/yr). In 2008, Ning Zeng of the University of Maryland estimated 65 GtC[needs update] lying on the floor of the world's forests as coarse woody material which could be buried and costs for wood burial carbon sequestration run at US$50/tC which is much lower than carbon capture from e.g. power plant emissions. CO2 fixation into woody biomass is a natural process carried out through photosynthesis. This is a nature-based solution and methods being trialled include the use of "wood vaults" to store the wood-containing carbon under oxygen-free conditions.
In 2022, a certification organization published methodologies for biomass burial. Other biomass storage proposals have included the burial of biomass deep underwater, including at the bottom of the Black Sea.
Geological sequestration refers to the storage of CO2 underground in depleted oil and gas reservoirs, saline formations, or deep, coal beds unsuitable for mining.
Once CO2 is captured from a point source, such as a cement factory, it can be compressed to ≈100 bar into a supercritical fluid. In this form, the CO2 could be transported via pipeline to the place of storage. The CO2 could then be injected deep underground, typically around 1 km (0.6 mi), where it would be stable for hundreds to millions of years. Under these storage conditions, the density of supercritical CO2 is 600 to 800 kg/m3.
The important parameters in determining a good site for carbon storage are: rock porosity, rock permeability, absence of faults, and geometry of rock layers. The medium in which the CO2 is to be stored ideally has a high porosity and permeability, such as sandstone or limestone. Sandstone can have a permeability ranging from 1 to 10−5 Darcy, with a porosity as high as ≈30%. The porous rock must be capped by a layer of low permeability which acts as a seal, or caprock, for the CO2. Shale is an example of a very good caprock, with a permeability of 10−5 to 10−9 Darcy. Once injected, the CO2 plume will rise via buoyant forces, since it is less dense than its surroundings. Once it encounters a caprock, it will spread laterally until it encounters a gap. If there are fault planes near the injection zone, there is a possibility the CO2 could migrate along the fault to the surface, leaking into the atmosphere, which would be potentially dangerous to life in the surrounding area. Another risk related to carbon sequestration is induced seismicity. If the injection of CO2 creates pressures underground that are too high, the formation will fracture, potentially causing an earthquake.
Carbon, in the form of CO2 can be removed from the atmosphere by chemical processes, and stored in stable carbonate mineral forms. This process (CO2-to-stone) is known as "carbon sequestration by mineral carbonation" or mineral sequestration. The process involves reacting carbon dioxide with abundantly available metal oxides – either magnesium oxide (MgO) or calcium oxide (CaO) – to form stable carbonates. These reactions are exothermic and occur naturally (e.g., the weathering of rock over geologic time periods).
CaO + CO2 → CaCO3
MgO + CO2 → MgCO3
These reactions are slightly more favorable at low temperatures. This process occurs naturally over geologic time frames and is responsible for much of the Earth's surface limestone. The reaction rate can be made faster however, by reacting at higher temperatures and/or pressures, although this method requires some additional energy. Alternatively, the mineral could be milled to increase its surface area, and exposed to water and constant abrasion to remove the inert silica as could be achieved naturally by dumping olivine in the high energy surf of beaches.
When CO2 is dissolved in water and injected into hot basaltic rocks underground it has been shown that the CO2 reacts with the basalt to form solid carbonate minerals. A test plant in Iceland started up in October 2017, extracting up to 50 tons of CO2 a year from the atmosphere and storing it underground in basaltic rock.[needs update]
Several start-ups are trying to do this at scale.
The low temperatures, high pressure, and reduced oxygen levels in the deep sea slow down decomposition processes, preventing the rapid release of carbon back into the atmosphere and acting as a long-term storage reservoir.
Large-scale seaweed farming could sequester significant amounts of carbon. Wild seaweed will sequester large amount of carbon through dissolved particles of organic matter being transported to deep ocean seafloors where it will become buried and remain for long periods of time. With respect to carbon farming, the potential growth of seaweed for carbon farming would see the harvested seaweed transported to the deep ocean for long-term burial. Seaweed farming occurs mostly in the Asian Pacific coastal areas where it has been a rapidly increasing market. The IPCC Special Report on the Ocean and Cryosphere in a Changing Climate recommends "further research attention" on seaweed farming as a mitigation tactic.
Artificial upwelling or downwelling is an approach that would change the mixing layers of the ocean. Encouraging various ocean layers to mix can move nutrients and dissolved gases around. Mixing may be achieved by placing large vertical pipes in the oceans to pump nutrient rich water to the surface, triggering blooms of algae, which store carbon when they grow and export carbon when they die. This produces results somewhat similar to iron fertilization. One side-effect is a short-term rise in CO2, which limits its attractiveness.
Underwater basalt offers a good alternative to other forms of oceanic carbon storage because it has a number of trapping measures to ensure added protection against leakage. These measures include "geochemical, sediment, gravitational and hydrate formation." Because CO2 hydrate is denser than CO2 in seawater, the risk of leakage is minimal. Injecting the CO2 at depths greater than 2,700 meters (8,900 ft) ensures that the CO2 has a greater density than seawater, causing it to sink.
Single-step carbon sequestration and storage is a saline water-based mineralization technology extracting carbon dioxide from seawater and storing it in the form of solid minerals.
It was once suggested that CO2 could be stored in the oceans by direct injection into the deep ocean and storing it there for some centuries. At the time, this proposal was called "ocean storage" but more precisely it was known as "direct deep-sea carbon dioxide injection". However, the interest in this avenue of carbon storage has much reduced since about 2001 because of concerns about the unknown impacts on marine life: 279 , high costs and concerns about its stability or permanence. The "IPCC Special Report on Carbon Dioxide Capture and Storage" in 2005 did include this technology as an option.: 279 However, the IPCC Fifth Assessment Report in 2014 no longer mentioned the term "ocean storage" in its report on climate change mitigation methods. The most recent IPCC Sixth Assessment Report in 2022 also no longer includes any mention of "ocean storage" in its "Carbon Dioxide Removal taxonomy".: 12–37
Cost of carbon sequestration (not including capture and transport) varies but is below US$10 per tonne in some cases where onshore storage is available. For example Carbfix cost is around US$25 per tonne of CO2. A 2020 report estimated sequestration in forests (so including capture) at US$35 for small quantities to US$280 per tonne for 10% of the total required to keep to 1.5 C warming. But there is risk of forest fires releasing the carbon.
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