The optical depth of a material, denoted τ {\textstyle \tau } , is given by:3 τ = ln ( Φ e i Φ e t ) = − ln T {\displaystyle \tau =\ln \!\left({\frac {\Phi _{\mathrm {e} }^{\mathrm {i} }}{\Phi _{\mathrm {e} }^{\mathrm {t} }}}\right)=-\ln T} where
The absorbance A {\textstyle A} is related to optical depth by: τ = A ln 10 {\displaystyle \tau =A\ln {10}}
The spectral optical depth in frequency (denoted τ ν {\displaystyle \tau _{\nu }} ) or in wavelength ( τ λ {\displaystyle \tau _{\lambda }} ) of a material is given by:4 τ ν = ln ( Φ e , ν i Φ e , ν t ) = − ln T ν {\displaystyle \tau _{\nu }=\ln \!\left({\frac {\Phi _{\mathrm {e} ,\nu }^{\mathrm {i} }}{\Phi _{\mathrm {e} ,\nu }^{\mathrm {t} }}}\right)=-\ln T_{\nu }} τ λ = ln ( Φ e , λ i Φ e , λ t ) = − ln T λ , {\displaystyle \tau _{\lambda }=\ln \!\left({\frac {\Phi _{\mathrm {e} ,\lambda }^{\mathrm {i} }}{\Phi _{\mathrm {e} ,\lambda }^{\mathrm {t} }}}\right)=-\ln T_{\lambda },} where
Spectral absorbance is related to spectral optical depth by: τ ν = A ν ln 10 , {\displaystyle \tau _{\nu }=A_{\nu }\ln 10,} τ λ = A λ ln 10 , {\displaystyle \tau _{\lambda }=A_{\lambda }\ln 10,} where
Main article: Attenuation
Optical depth measures the attenuation of the transmitted radiant power in a material. Attenuation can be caused by absorption, but also reflection, scattering, and other physical processes. Optical depth of a material is approximately equal to its attenuation when both the absorbance is much less than 1 and the emittance of that material (not to be confused with radiant exitance or emissivity) is much less than the optical depth: Φ e t + Φ e a t t = Φ e i + Φ e e , {\displaystyle \Phi _{\mathrm {e} }^{\mathrm {t} }+\Phi _{\mathrm {e} }^{\mathrm {att} }=\Phi _{\mathrm {e} }^{\mathrm {i} }+\Phi _{\mathrm {e} }^{\mathrm {e} },} T + A T T = 1 + E , {\displaystyle T+ATT=1+E,} where
and according to the Beer–Lambert law, T = e − τ , {\displaystyle T=e^{-\tau },} so: A T T = 1 − e − τ + E ≈ τ + E ≈ τ , if τ ≪ 1 and E ≪ τ . {\displaystyle ATT=1-e^{-\tau }+E\approx \tau +E\approx \tau ,\quad {\text{if}}\ \tau \ll 1\ {\text{and}}\ E\ll \tau .}
Optical depth of a material is also related to its attenuation coefficient by: τ = ∫ 0 l α ( z ) d z , {\displaystyle \tau =\int _{0}^{l}\alpha (z)\,\mathrm {d} z,} where
and if α(z) is uniform along the path, the attenuation is said to be a linear attenuation and the relation becomes: τ = α l {\displaystyle \tau =\alpha l}
Sometimes the relation is given using the attenuation cross section of the material, that is its attenuation coefficient divided by its number density: τ = ∫ 0 l σ n ( z ) d z , {\displaystyle \tau =\int _{0}^{l}\sigma n(z)\,\mathrm {d} z,} where
and if n {\displaystyle n} is uniform along the path, i.e., n ( z ) ≡ N {\displaystyle n(z)\equiv N} , the relation becomes: τ = σ N l {\displaystyle \tau =\sigma Nl}
In atomic physics, the spectral optical depth of a cloud of atoms can be calculated from the quantum-mechanical properties of the atoms. It is given by τ ν = d 2 n ν 2 c ℏ ε 0 σ γ {\displaystyle \tau _{\nu }={\frac {d^{2}n\nu }{2\mathrm {c} \hbar \varepsilon _{0}\sigma \gamma }}} where
See also: Beer–Lambert law
In atmospheric sciences, one often refers to the optical depth of the atmosphere as corresponding to the vertical path from Earth's surface to outer space; at other times the optical path is from the observer's altitude to outer space. The optical depth for a slant path is τ = mτ′, where τ′ refers to a vertical path, m is called the relative airmass, and for a plane-parallel atmosphere it is determined as m = sec θ where θ is the zenith angle corresponding to the given path. Therefore, T = e − τ = e − m τ ′ {\displaystyle T=e^{-\tau }=e^{-m\tau '}} The optical depth of the atmosphere can be divided into several components, ascribed to Rayleigh scattering, aerosols, and gaseous absorption. The optical depth of the atmosphere can be measured with a Sun photometer.
The optical depth with respect to the height within the atmosphere is given by5 τ ( z ) = k a w 1 ρ 0 H e − z / H {\displaystyle \tau (z)=k_{\text{a}}w_{1}\rho _{0}He^{-z/H}} and it follows that the total atmospheric optical depth is given by6 τ ( 0 ) = k a w 1 ρ 0 H {\displaystyle \tau (0)=k_{\text{a}}w_{1}\rho _{0}H}
In both equations:
The optical depth of a plane parallel cloud layer is given by7 τ = Q e [ 9 π L 2 H N 16 ρ l 2 ] 1 / 3 {\displaystyle \tau =Q_{\text{e}}\left[{\frac {9\pi L^{2}HN}{16\rho _{l}^{2}}}\right]^{1/3}} where:
So, with a fixed depth and total liquid water path, τ ∝ N 1 / 3 {\textstyle \tau \propto N^{1/3}} .8
Main article: Optical depth (astrophysics)
In astronomy, the photosphere of a star is defined as the surface where its optical depth is 2/3. This means that each photon emitted at the photosphere suffers an average of less than one scattering before it reaches the observer. At the temperature at optical depth 2/3, the energy emitted by the star (the original derivation is for the Sun) matches the observed total energy emitted.
Note that the optical depth of a given medium will be different for different colors (wavelengths) of light.
For planetary rings, the optical depth is the (negative logarithm of the) proportion of light blocked by the ring when it lies between the source and the observer. This is usually obtained by observation of stellar occultations.
IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Absorbance". doi:10.1351/goldbook.A00028 /wiki/International_Union_of_Pure_and_Applied_Chemistry ↩
Christopher Robert Kitchin (1987). Stars, Nebulae and the Interstellar Medium: Observational Physics and Astrophysics. CRC Press. /wiki/CRC_Press ↩
Petty, Grant W. (2006). A first course in atmospheric radiation. Sundog Pub. ISBN 9780972903318. OCLC 932561283. 9780972903318 ↩