The headspace equipment involves a hollow dome or sphere-like objects which forms an airtight seal and surrounds the objects of interest. Inert gases are passed into the space containing the object or a vacuum is established such that the odor compounds are removed from the headspace.4 These compounds are in turn captured using a variety of techniques, among them cold surfaces, solvent traps, and adsorbent materials, with the latter techniques capable of longer periods of collection. The samples can then be analyzed using techniques such as gas chromatography, mass spectrometry, or Carbon-13 NMR.5
Several companies have patented similar headspace technologies:
Omar, Jone; Olivares, Maitane; Alonso, Ibone; Vallejo, Asier; Aizpurua-Olaizola, Oier; Etxebarria, Nestor (2016-04-01). "Quantitative Analysis of Bioactive Compounds from Aromatic Plants by Means of Dynamic Headspace Extraction and Multiple Headspace Extraction-Gas Chromatography-Mass Spectrometry". Journal of Food Science. 81 (4): C867 – C873. doi:10.1111/1750-3841.13257. ISSN 1750-3841. PMID 26925555. S2CID 21443154. https://figshare.com/articles/journal_contribution/5028548 ↩
Kaiser, Roman (1997), "Environmental Scents at the Ligurian Coast", Perfumer & Flavorist, 22: 7–18 ↩
Knudsen, Jette T.; Tollsten, Lars; Bergström, L.Gunnar (1993), "Floral scents—a checklist of volatile compounds isolated by head-space techniques", Phytochemistry, 33 (2): 253–280, Bibcode:1993PChem..33..253K, doi:10.1016/0031-9422(93)85502-i /wiki/Bibcode_(identifier) ↩
Charles (Ed.), Sell; Karen Jenner (2005). "Chapter 14. The Search for Fragrance Ingredients". The Chemistry of Fragrances (2nd ed.). Royal Society of Chemistry Publishing. pp. 254–293. ISBN 978-0-85404-824-3. 978-0-85404-824-3 ↩
Charles (Ed.), Sell; Robin Clery (2005). "Chapter 12. Natural Product Analysis in the Fragrance Industry". The Chemistry of Fragrances (2nd ed.). Royal Society of Chemistry Publishing. pp. 214–228. ISBN 978-0-85404-824-3. 978-0-85404-824-3 ↩