A jet of a Newtonian fluid, such as honey poured from a bottle, thins continuously and coils regularly.1 In contrast, a viscoelastic jet breaks up much more slowly. Typically, it evolves into a "beads-on-a-string" structure, where large drops are connected by thin threads. The slow breakup process provides the viscoelastic jet sufficient time to exhibit other phenomena, including:
The behaviors of non-Newtonian fluids result from the interplay of non-Newtonian properties (e.g. viscoelasticity, shear-thinning) with gravitational, viscous, and inertial effects.2[needs update]
The evolution of a viscoelastic fluid thread over time depends on the relative magnitude of the viscous, inertial, and elastic stresses and the capillary pressure. To study the inertio-elasto-capillary balance for a jet, two dimensionless parameters are defined: the Ohnesorge number (Oh)
which is the inverse of the Reynolds number based on a characteristic capillary velocity γ η 0 {\displaystyle {\frac {\gamma }{\eta _{0}}}} ; and the intrinsic Deborah number (De), defined as
where t r = ρ R 0 3 / γ {\displaystyle t_{r}={\sqrt[{}]{\rho R_{0}^{3}/\gamma }}} is the "Rayleigh time scale" for inertio-capillary breakup of an inviscid jet. In these expressions, ρ {\displaystyle \rho } is the fluid density, η 0 {\displaystyle \eta _{0}} is the fluid zero shear viscosity, γ {\displaystyle \gamma } is the surface tension, R 0 {\displaystyle R_{0}} is the initial radius of the jet, and λ {\displaystyle \lambda } is the relaxation time associated with the polymer solution.
Like other fluids, when considering viscoelastic flows, the velocity, pressure, and stress must satisfy equations of mass and momentum, supplemented with a constitutive equation involving the velocity and stress.
The behaviors of weakly viscoelastic jets can be described by the following set of mathematical equations:
where ( z , t ) {\displaystyle (z,t)} is the axial velocity; η s {\displaystyle \eta _{s}} and η p {\displaystyle \eta _{p}} are the solvent and polymer contribution to the total viscosity, respectively (total viscosity η 0 = η s + η p {\displaystyle \eta _{0}=\eta _{s}+\eta _{p}} ); R z {\displaystyle R_{z}} indicates the partial derivative ∂ R ∂ z {\displaystyle {\frac {\partial R}{\partial z}}} ; and σ z z {\displaystyle \sigma _{zz}} and σ r r {\displaystyle \sigma _{rr}} are the diagonal terms of the extra-stress tensor. Equation (1) represents mass conservation, and Equation (2) represents the momentum equation in one dimension. The extra-stress tensors σ z z {\displaystyle \sigma _{zz}} and σ r r {\displaystyle \sigma _{rr}} can be calculated as follows:
where λ {\displaystyle \lambda } is the relaxation time of the liquid, and α {\displaystyle \alpha } is the mobility factor, a positive dimensionless parameter corresponding to the anisotropy of the hydrodynamic drag on the polymer molecules.
McKinley, Gareth (Nov 18, 2013). "Viscoelastic Jet". Gareth McKinley's Non-Newtonian Fluid Dynamics Research Group. MIT. Retrieved 2025-01-24. https://web.mit.edu/nnf/research/phenomena/viscoelastic_jet.html ↩