The skeletons of these organisms are composed of opal-A, an amorphous form of silica, lacking long-range crystal structure. This is gradually transformed to opal-CT, a microcrystalline form of silica composed mostly of bladed crystals of cristobalite and tridymite. Much opal-CT takes the form of lepispheres, which are clusters of bladed crystals about 10 microns in diameter. Opal-CT in turn transforms to microquartz. In deep ocean water, the transition to opal-CT occurs at a temperature of about 45 °C (113 °F) while the transition to microquartz occurs at a temperature of about 80 °C (176 °F). However, the transition temperature varies considerably, and the transition is hastened by the presence of magnesium hydroxide, which provides a nucleus for the recrystallization. Megaquartz forms at elevated temperatures typical of metamorphism.
Bedded cherts can be further subdivided by the kinds of organisms that produced the silica skeletons.
Some bedded cherts appear devoid of fossils even under close microscopic examination. Their origin is uncertain, but they may form from fossil remains that are completely dissolved in fluids that then migrate to precipitate their silica load in a nearby bed. Eolian quartz has also been suggested as a source of silica for chert beds. Precambrian bedded cherts are common, making up 15% of middle Precambrian sedimentary rock, and may have been deposited nonbiologically in oceans more saturated in silica than the modern ocean. The high degree of silica saturation was due either to intense volcanic activity or to the lack of modern organisms that remove silica from seawater.
The silica in nodular chert likely precipitates as opal-A, based on internal banding in nodules, and may recrystallize directly to microquartz without first recrystallizing to opal-CT. Some nodular chert may precipitate directly as microquartz, due to low levels of supersaturation of silica.
Nonmarine cherts may form in saline alkaline lakes as thin lenses or nodules showing sedimentary structures suggestive of evaporite origin. Such cherts are forming today in the alkaline lakes of the East African Rift Valley. These lakes are characterized by sodium carbonate brines with very high pH that can contain as much as 2700 ppm silica. Episodes of runoff of fresh water into the lakes lowers the pH and precipitates the unusual sodium silicate minerals magadiite or kenyaite, After burial and diagenesis, these are altered to Magadi-type chert. The Morrison Formation contains Magadi-type chert that may have formed in the alkaline Lake T'oo'dichi'.
Chert is of only modest economic importance today as a source of silica (quartz sand being much more important.) However, chert deposits may be associated with valuable deposits of iron, uranium, manganese, phosphorite, and petroleum.
In prehistoric times, chert was often used as a raw material for the construction of stone tools. Like obsidian, as well as some rhyolites, felsites, quartzites, and other tool stones used in lithic reduction, chert fractures in a Hertzian cone when struck with sufficient force. This results in conchoidal fractures, a characteristic of all minerals with no cleavage planes. In this kind of fracture, a cone of force propagates through the material from the point of impact, eventually removing a full or partial cone, like when a plate-glass window is struck by a small object such as an air gun projectile. The partial Hertzian cones produced during lithic reduction are called flakes, and exhibit features characteristic of this sort of breakage, including striking platforms, bulbs of force, and occasionally eraillures, which are small secondary flakes detached from the flake's bulb of force.
When a chert stone is struck against an iron-bearing surface, sparks result. This makes chert an excellent tool for starting fires, and both flint and common chert were used in various types of fire-starting tools, such as tinderboxes, throughout history. A primary historic use of common chert and flint was for flintlock firearms, in which the chert striking a metal plate produces a spark that ignites a small reservoir containing black powder, discharging the firearm.
Cherts can cause several problems when used as concrete aggregates. Deeply weathered chert develops surface pop-outs when used in concrete that undergoes freezing and thawing because of the high porosity of weathered chert. The other concern is that certain cherts undergo an alkali-silica reaction with high-alkali cements. This reaction leads to cracking and expansion of concrete and ultimately to failure of the material.
There are numerous varieties of chert, classified based on their visible, microscopic and physical characteristics. Examples are:
Other lesser used archaic terms for chert are firestone and silex.
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