For strong gradients the transport equation typically has to be modified with higher order terms (and higher order Transport coefficients).2
Water in Biology, Chemistry, and Physics: Experimental Overviews and Computational Methodologies, G. Wilse Robinson, ISBN 9789810224516, p. 80, Google Books /wiki/ISBN_(identifier) ↩
Kockmann, N. (2007). Transport Phenomena in Micro Process Engineering. Deutschland: Springer Berlin Heidelberg, page 66, Google books https://books.google.com/books?id=40fQkEDXiQ0C&dq=transport+coefficient+of+higher+order&pg=PA66 ↩