Mathematically, the atomic percent is
where Ni are the number of atoms of interest and Ntot are the total number of atoms, while the atomic ratio is
For example, the atomic percent of hydrogen in water (H2O) is at.%H2O = 2/3 x 100 ≈ 66.67%, while the atomic ratio of hydrogen to oxygen is AH:O = 2:1.
Another application is in radiochemistry, where this may refer to isotopic ratios or isotopic abundances. Mathematically, the isotopic abundance is
where Ni are the number of atoms of the isotope of interest and Ntot is the total number of atoms, while the atomic ratio is
For example, the isotopic ratio of deuterium (D) to hydrogen (H) in heavy water is roughly D:H = 1:7000 (corresponding to an isotopic abundance of 0.00014%).
In laser physics however, the atomic ratio may refer to the doping ratio or the doping fraction.
McGraw-Hill Dictionary of Chemistry. McGraw-Hill. 27 January 2003. pp. 31. ISBN 0-07-141046-5. 0-07-141046-5 ↩