The formula to calculate API gravity from specific gravity (SG) is:
Conversely, the specific gravity of petroleum liquids can be derived from their API gravity value as
Thus, a heavy oil with a specific gravity of 1.0 (i.e., with the same density as pure water at 60 °F) has an API gravity of:
In the oil industry, quantities of crude oil are often measured in metric tons. One can calculate the approximate number of barrels per metric ton for a given crude oil based on its API gravity:
For example, a metric ton of West Texas Intermediate (39.6° API) has a volume of about 7.6 barrels.
To derive the API gravity, the specific gravity (i.e., density relative to water) is first measured using either the hydrometer, detailed in ASTM D1298 or with the oscillating U-tube method detailed in ASTM D4052.
Density adjustments at different temperatures, corrections for soda-lime glass expansion and contraction and meniscus corrections for opaque oils are detailed in the Petroleum Measurement Tables, details of usage specified in ASTM D1250. The specific gravity is defined by the formula below.
With the formula presented in the previous section, the API gravity can be readily calculated. When converting oil density to specific gravity using the above definition, it is important to use the correct density of water, according to the standard conditions used when the measurement was made. The official density of water at 60 °F according to the 2008 edition of ASTM D1250 is 999.016 kg/m3.2 The 1980 value is 999.012 kg/m3.3 In some cases the standard conditions may be 15 °C (59 °F) and not 60 °F (15.56 °C), in which case a different value for the water density would be appropriate (see standard conditions for temperature and pressure).
There are advantages to field testing and on-board conversion of measured volumes to volume correction. This method is detailed in ASTM D287.4
The hydrometer method is a standard technique for directly measuring API gravity of petroleum and petroleum products.5 This method is based on the principle of buoyancy and utilizes a specially calibrated hydrometer to determine the API gravity of a liquid sample.6
The procedure typically involves the following steps:
The hydrometer method is widely used due to its simplicity and low cost. However, it requires a relatively large sample volume and may not be suitable for highly viscous or opaque fluids.12 Proper cleaning and handling of the hydrometer are crucial to maintain accuracy, and for volatile liquids, special precautions may be necessary to prevent evaporation during measurement.13
Generally speaking, oil with an API gravity between 40 and 45° commands the highest prices. Above 45°, the molecular chains become shorter and less valuable to refineries.14
Crude oil is classified as light, medium, or heavy according to its measured API gravity.
However, not all parties use the same grading.15 The United States Geological Survey uses slightly different ranges.16
Crude oil with API gravity less than 10° is referred to as extra heavy oil or bitumen. Bitumen derived from oil sands deposits in Alberta, Canada, has an API gravity of around 8°. It can be diluted with lighter hydrocarbons to produce diluted bitumen, which has an API gravity of less than 22.3°, or further "upgraded" to an API gravity of 31 to 33° as synthetic crude.17
API Degree history http://www.sizes.com/units/hydrometer_api.htm ↩
Report on the Development, Construction, Calculation and Preparation of the ASTM – IP Petroleum Measurement Tables (ASTM D1250; IP 200), 1960, published by the Institute of Petroleum, 61 New Cavendish Street, London, W.1 and American Society for Testing Materials, 1916 Race Street, Philadelphia 3, Pa. ↩
API Manual of Petroleum Measurement Standards, Chapter 11.1 – 1980, Volume XI/XII, Adjunct to: ASTM D1250-80 and IP 200/80 ↩
"Standard Test Method for API Gravity of Crude Petroleum and Petroleum Products (Hydrometer/Method)". www.astm.org. Retrieved 2024-08-07. https://www.astm.org/d0287-22.html ↩
"Standard Test Method for Density, Relative Density, or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method". www.astm.org. Retrieved 2024-08-07. https://www.astm.org/d1298-12br17e01.html ↩
Speight, James G. (2014-12-12). Handbook of Petroleum Product Analysis (1 ed.). Wiley. doi:10.1002/9781118986370. ISBN 978-1-118-36926-5. 978-1-118-36926-5 ↩
Riazi, M. R., ed. (2007). Characterization and Properties of Petroleum Fractions. doi:10.1520/mnl50-eb. ISBN 978-0-8031-3361-7. Retrieved 2024-08-07. {{cite book}}: |website= ignored (help) 978-0-8031-3361-7 ↩
"Comments on Crude Oil Gravity Adjustments". Louisiana Department of Natural Resources. Archived from the original on 2 May 2006. Retrieved 6 January 2014. https://web.archive.org/web/20060502160519/http://dnr.louisiana.gov/sec/execdiv/techasmt/oil_gas/crude_oil_gravity/comments_1989.htm ↩
Crude oil grades, Crudemonitor.ca, web PDF file: CMonitor-Gr-PDF Archived October 8, 2007, at the Wayback Machine http://www.crudemonitor.ca/quickfacts/misc/grades.pdf ↩
USGS FS2006-3133_508, web PDF file: USGS-508-PDF https://pubs.usgs.gov/fs/2006/3133/pdf/FS2006-3133_508.pdf ↩
Canadian Centre for Energy Information. "What is crude oil?" Archived 2014-07-10 at the Wayback Machine. Retrieved on: 2012-09-10. http://www.centreforenergy.com/AboutEnergy/ONG/Oil/Overview.asp?page=2 ↩