The effect can be classified into two types, namely the +E effect and the -E effect. This classification is based on the direction of electron pair transfer. When the attacking reagent is electrophile, the +E effect is generally observed and π-electrons are transferred to the positively charged atom. When the attacking reagent is a nucleophile, there is generally an -E effect, where π electrons are transferred to atoms to which the attacking reagent will not bind.
IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "electromeric effect". doi:10.1351/goldbook.E01973 /wiki/International_Union_of_Pure_and_Applied_Chemistry ↩
IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "mesomeric effect". doi:10.1351/goldbook.M03844 /wiki/International_Union_of_Pure_and_Applied_Chemistry ↩