Basalt is composed mostly of oxides of silicon, iron, magnesium, potassium, aluminum, titanium, and calcium. Geologists classify igneous rock by its mineral content whenever possible; the relative volume percentages of quartz (crystalline silica (SiO2)), alkali feldspar, plagioclase, and feldspathoid (QAPF) are particularly important. An aphanitic (fine-grained) igneous rock is classified as basalt when its QAPF fraction is composed of less than 10% feldspathoid and less than 20% quartz, and plagioclase makes up at least 65% of its feldspar content. This places basalt in the basalt/andesite field of the QAPF diagram. Basalt is further distinguished from andesite by its silica content of under 52%.
It is often not practical to determine the mineral composition of volcanic rocks, due to their very small grain size, in which case geologists instead classify the rocks chemically, with particular emphasis on the total content of alkali metal oxides and silica (TAS); in that context, basalt is defined as volcanic rock with a content of between 45% and 52% silica and no more than 5% alkali metal oxides. This places basalt in the B field of the TAS diagram. Such a composition is described as mafic.
The physical properties of basalt result from its relatively low silica content and typically high iron and magnesium content. The average density of basalt is 2.9 g/cm3, compared, for example, to granite’s typical density of 2.7 g/cm3. The viscosity of basaltic magma is relatively low—around 104 to 105 cP—similar to the viscosity of ketchup, but that is still several orders of magnitude higher than the viscosity of water, which is about 1 cP).
Decompression melting can occur in a variety of tectonic settings, including in continental rift zones, at mid-ocean ridges, above geological hotspots, and in back-arc basins. Basalt also forms in subduction zones, where mantle rock rises into a mantle wedge above the descending slab. The slab releases water vapor and other volatiles as it descends, which further lowers the melting point, further increasing the amount of decompression melting. Each tectonic setting produces basalt with its own distinctive characteristics.
The mineralogy of basalt is characterized by a preponderance of calcic plagioclase feldspar and pyroxene. Olivine can also be a significant constituent. Accessory minerals present in relatively minor amounts include iron oxides and iron-titanium oxides, such as magnetite, ulvöspinel, and ilmenite. Because of the presence of such oxide minerals, basalt can acquire strong magnetic signatures as it cools, and paleomagnetic studies have made extensive use of basalt.
The majority of tholeiitic basalts are formed at approximately 50–100 km depth within the mantle. Many alkali basalts may be formed at greater depths, perhaps as deep as 150–200 km. The origin of high-alumina basalt continues to be controversial, with disagreement over whether it is a primary melt or derived from other basalt types by fractionation.: 65
Mid-ocean ridge basalts (MORB) and their intrusive equivalents, gabbros, are the characteristic igneous rocks formed at mid-ocean ridges. They are tholeiitic basalts particularly low in total alkalis and in incompatible trace elements, and they have relatively flat REE patterns normalized to mantle or chondrite values. In contrast, alkali basalts have normalized patterns highly enriched in the light REE, and with greater abundances of the REE and of other incompatible elements. Because MORB basalt is considered a key to understanding plate tectonics, its compositions have been much studied. Although MORB compositions are distinctive relative to average compositions of basalts erupted in other environments, they are not uniform. For instance, compositions change with position along the Mid-Atlantic Ridge, and the compositions also define different ranges in different ocean basins. Mid-ocean ridge basalts have been subdivided into varieties such as normal (NMORB) and those slightly more enriched in incompatible elements (EMORB).
Source rocks for the partial melts that produce basaltic magma probably include both peridotite and pyroxenite.
The character of submarine basalt eruptions is largely determined by depth of water, since increased pressure restricts the release of volatile gases and results in effusive eruptions. It has been estimated that at depths greater than 500 metres (1,600 ft), explosive activity associated with basaltic magma is suppressed.[73] Above this depth, submarine eruptions are often explosive, tending to produce pyroclastic rock rather than basalt flows. These eruptions, described as Surtseyan, are characterised by large quantities of steam and gas and the creation of large amounts of pumice.
When basalt erupts underwater or flows into the sea, contact with the water quenches the surface and the lava forms a distinctive pillow shape, through which the hot lava breaks to form another pillow. This "pillow" texture is very common in underwater basaltic flows and is diagnostic of an underwater eruption environment when found in ancient rocks. Pillows typically consist of a fine-grained core with a glassy crust and have radial jointing. The size of individual pillows varies from 10 cm up to several metres.
Basalt is the most common volcanic rock type on Earth, making up over 90% of all volcanic rock on the planet. The crustal portions of oceanic tectonic plates are composed predominantly of basalt, produced from upwelling mantle below the ocean ridges. Basalt is also the principal volcanic rock in many oceanic islands, including the islands of Hawaiʻi, the Faroe Islands, and Réunion. The eruption of basalt lava is observed by geologists at about 20 volcanoes per year.
As well as forming large parts of the Earth's crust, basalt also occurs in other parts of the Solar System. Basalt commonly erupts on Io (the third largest moon of Jupiter), and has also formed on the Moon, Mars, Venus, and the asteroid Vesta.
Lunar basalts differ from their Earth counterparts principally in their high iron contents, which typically range from about 17 to 22 wt% FeO. They also possess a wide range of titanium concentrations (present in the mineral ilmenite), ranging from less than 1 wt% TiO2, to about 13 wt.%. Traditionally, lunar basalts have been classified according to their titanium content, with classes being named high-Ti, low-Ti, and very-low-Ti. Nevertheless, global geochemical maps of titanium obtained from the Clementine mission demonstrate that the lunar maria possess a continuum of titanium concentrations, and that the highest concentrations are the least abundant.
The common corrosion features of underwater volcanic basalt suggest that microbial activity may play a significant role in the chemical exchange between basaltic rocks and seawater. The significant amounts of reduced iron, Fe(II), and manganese, Mn(II), present in basaltic rocks provide potential energy sources for bacteria. Some Fe(II)-oxidizing bacteria cultured from iron-sulfide surfaces are also able to grow with basaltic rock as a source of Fe(II). Fe- and Mn- oxidizing bacteria have been cultured from weathered submarine basalts of Kamaʻehuakanaloa Seamount (formerly Loihi). The impact of bacteria on altering the chemical composition of basaltic glass (and thus, the oceanic crust) and seawater suggest that these interactions may lead to an application of hydrothermal vents to the origin of life.
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