Halides cannot be reduced under the usual laboratory conditions, but they all can be oxidized to the parent halogens, which are diatomic. Especially for iodide and less so for the lighter halides, intermediates can be observed and isolated. Best characterized is triiodide. Many related species are known, including a host of polyiodides.
Halides are conjugate bases of hydrogen halides, which are all gases. When the protonation is conducted in aqueous solution, hydrohalic acids are produced.
Halide salts such as KCl, KBr and KI are highly soluble in water to give colorless solutions. The solutions react readily with a solution of silver nitrate AgNO3. These three halides form solid precipitates:4
Similar but slower reactions occur with alkyl halides in place of alkali metal halides, as described in the Beilstein test.
Metal halides are used in high-intensity discharge lamps called metal halide lamps, such as those used in modern street lights. These are more energy-efficient than mercury-vapor lamps, and have much better colour rendition than orange high-pressure sodium lamps. Metal halide lamps are also commonly used in greenhouses or in rainy climates to supplement natural sunlight.
Silver halides are used in photographic films and papers. When the film is developed, the silver halides which have been exposed to light are reduced to metallic silver, forming an image.
Halides are also used in solder paste, commonly as a Cl or Br equivalent.5
Synthetic organic chemistry often incorporates halogens into organohalide compounds.
"Definition of HALOGENIDE". www.merriam-webster.com. Retrieved 2022-01-07. https://www.merriam-webster.com/dictionary/halogenide ↩
Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 82. ISBN 978-0-08-037941-8. 978-0-08-037941-8 ↩
Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 694. ISBN 978-0-08-037941-8. 978-0-08-037941-8 ↩
Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 1184. ISBN 978-0-08-037941-8. 978-0-08-037941-8 ↩
"Halogen-Free Solder Paste" (PDF). Archived from the original (PDF) on 2012-03-17. Retrieved 2011-03-21. https://web.archive.org/web/20120317004413/http://www.indium.com/halogen-free/assets/PDF/Indium8_9HF_Overview.pdf ↩