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Vanadium(V) oxytrifluoride
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<h2 id="reactions">Reactions</h2> <p>In <a href="/facts/Organic_synthesis/aprl6Iq7">organic synthesis</a>, VOF3 is used for the <a href="/facts/Oxidative_coupling_of_phenols/agXogh57">oxidative coupling of phenols</a>, for example in the syntheses of vancomycin and its analogues.<a class="footnote-ref" id="fnref:3" href="#fn:3"><sup>3</sup></a> For these applications VOF3 is typically dissolved in <a href="/facts/Trifluoroacetic_acid/2SAfAXWv">trifluoroacetic acid</a>. </p><p>Vanadium(V) oxytrifluoride reacts with <a href="/facts/Hexamethyldisiloxane/UmIspJ7U">hexamethyldisiloxane</a> to give <a href="/facts/Vanadium_dioxide_fluoride/4o2aVdCH">vanadium dioxide fluoride</a>:<a class="footnote-ref" id="fnref:4" href="#fn:4"><sup>4</sup></a> </p> (CH3)3SiOSi(CH3)3 + VOF3 → VO2F + 2 (CH3)3SiF <h2 id="references">References</h2> <ol> <li id="fn:1"><p>Perry, Dale L. (2011). Handbook of Inorganic Compounds. CRC Press. ISBN 978-1-4398-1461-1. <a href="978-1-4398-1461-1" target="_blank">978-1-4398-1461-1</a> <a href="#fnref:1" class="footnote-back-ref">↩</a></p></li> <li id="fn:2"><p>Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5. <a href="/wiki/ISBN_(identifier)" target="_blank">/wiki/ISBN_(identifier)</a> <a href="#fnref:2" class="footnote-back-ref">↩</a></p></li> <li id="fn:3"><p>Vanasse, Benoit; O'Brien, Michael K. (2001). "Vanadyl Trifluoride". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rv005. ISBN 0471936235. <a href="0471936235" target="_blank">0471936235</a> <a href="#fnref:3" class="footnote-back-ref">↩</a></p></li> <li id="fn:4"><p>Davis, Martin F.; Jura, Marek; Leung, Alethea; Levason, William; Littlefield, Benjamin; Reid, Gillian; Webster, Michael (2008). "Synthesis, Chemistry and Structures of Complexes of the Dioxovanadium(v) Halides VO2F and VO2Cl". Dalton Transactions (44): 6265–6273. doi:10.1039/b811422f. PMID 18985260. <a href="/wiki/Doi_(identifier)" target="_blank">/wiki/Doi_(identifier)</a> <a href="#fnref:4" class="footnote-back-ref">↩</a></p></li> </ol>