Main article: Atomic electron transition
Atomic electron transitions cause the emission or absorption of photons. Their statistics are Poissonian, and the time between jumps is exponentially distributed.1 The damping time constant (which ranges from nanoseconds to a few seconds) relates to the natural, pressure, and field broadening of spectral lines. The larger the energy separation of the states between which the electron jumps, the shorter the wavelength of the photon emitted.
In an ion trap, quantum jumps can be directly observed by addressing a trapped ion with radiation at two different frequencies to drive electron transitions.2 This requires one strong and one weak transition to be excited (denoted ω {\displaystyle \omega } 12 and ω {\displaystyle \omega } 13 respectively in the figure to the right). The electron energy level, | 2 ⟩ {\displaystyle |2\rangle } , has a short lifetime, Γ {\displaystyle \Gamma } 2 which allows for constant emission of photons at a frequency ω {\displaystyle \omega } 12 which can be collected by a camera and/or photomultiplier tube. State | 3 ⟩ {\displaystyle |3\rangle } has a relatively long lifetime Γ {\displaystyle \Gamma } 3 which causes an interruption of the photon emission as the electron gets shelved in state through application of light with frequency ω {\displaystyle \omega } 13. The ion going dark is a direct observation of quantum jumps.
Main article: Molecular electronic transition
Deléglise, S. "Observing the quantum jumps of light" (PDF). Archived from the original (PDF) on November 7, 2010. Retrieved September 17, 2010. https://web.archive.org/web/20101107043403/http://www.mpq.mpg.de/Theorygroup/CIRAC/wiki/images/8/86/Samuel.pdf ↩
Foot, C. J. (2005). Atomic physics. Oxford: Oxford University Press. ISBN 978-0-19-152314-4. OCLC 181750270. 978-0-19-152314-4 ↩