An inorganic peroxide is a peroxide of an inorganic compound. Metal peroxides are metal-containing peroxides with ionically- or covalently-bonded peroxide (O2−2) groups. This large family of compounds can be divided into ionic and covalent peroxide. The first class mostly contains the peroxides of the alkali and alkaline earth metals whereas the covalent peroxides are represented by such compounds as hydrogen peroxide and peroxymonosulfuric acid (H2SO5). In contrast to the purely ionic character of alkali metal peroxides, peroxides of transition metals have a more covalent character.
Main group peroxides are peroxide derivatives of the main group elements (many of which are metals). Many compounds of the main group elements form peroxides, and a few are of commercial significance.