The pentagonal bipyramid (or pentagonal dipyramid) is a polyhedron with ten triangular faces. It is constructed by attaching two pentagonal pyramids to each of their bases. If the triangular faces are equilateral, the pentagonal bipyramid is an example of deltahedra, composite polyhedron, and Johnson solid.
The pentagonal bipyramid may be represented as four-connected well-covered graph. This polyhedron may be used in the chemical compound as the description of an atom cluster known as pentagonal bipyramidal molecular geometry, as a solution in Thomson problem, as well as in decahedral nanoparticles.