Xenon tetrafluoride is a chemical compound with chemical formula XeF4. It was the first discovered binary compound of a noble gas. It is produced by the chemical reaction of xenon with fluorine:
This reaction is exothermic, releasing an energy of 251 kJ/mol.
Xenon tetrafluoride is a colorless crystalline solid that sublimes at 117 °C. Its structure was determined by both NMR spectroscopy and X-ray crystallography in 1963. The structure is square planar, as has been confirmed by neutron diffraction studies. According to VSEPR theory, in addition to four fluoride ligands, the xenon center has two lone pairs of electrons. These lone pairs are mutually trans.