In thermodynamics, thermal diffusivity is the thermal conductivity divided by density and specific heat capacity at constant pressure. It is a measure of the rate of heat transfer inside a material and has SI units of m2/s. It is an intensive property. Thermal diffusivity is usually denoted by lowercase alpha (α), but a, h, κ (kappa), K, D, D T {\displaystyle D_{T}} are also used.
The formula is α = k ρ c p , {\displaystyle \alpha ={\frac {k}{\rho c_{p}}},} where
Together, ρcp can be considered the volumetric heat capacity (J/(m3·K)).
Thermal diffusivity is a positive coefficient in the heat equation: ∂ T ∂ t = α ∇ 2 T . {\displaystyle {\frac {\partial T}{\partial t}}=\alpha \nabla ^{2}T.}
One way to view thermal diffusivity is as the ratio of the time derivative of temperature to its curvature, quantifying the rate at which temperature concavity is "smoothed out". In a substance with high thermal diffusivity, heat moves rapidly through it because the substance conducts heat quickly relative to its energy storage capacity or "thermal bulk".
Thermal diffusivity and thermal effusivity are related concepts and quantities used to simulate non-equilibrium thermodynamics. Diffusivity is the more fundamental concept and describes the stochastic process of heat spread throughout some local volume of a substance. Effusivity describes the corresponding transient process of heat flow through some local area of interest. Upon reaching a steady state, where the stored energy distribution stabilizes, the thermal conductivity (k) may be sufficient to describe heat transfers inside solid or rigid bodies by applying Fourier's law.
Thermal diffusivity is often measured with the flash method. It involves heating a strip or cylindrical sample with a short energy pulse at one end and analyzing the temperature change (reduction in amplitude and phase shift of the pulse) a short distance away.