Nickeline or niccolite is the mineral form of nickel arsenide. The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.
Small quantities of sulfur, iron and cobalt are usually present, and sometimes the arsenic is largely replaced by antimony. This last forms an isomorphous series with breithauptite (nickel antimonide).