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Borotellurate

Boron and tellurium combine to form borotellurates, heteropoly anion compounds featuring tellurate groups bonded to boron atoms. The ratio of tellurate to borate units indicates their condensation level, with structures ranging from chain-like [TeO4(BO3)2]8− anions to isolated zero-dimensional [TeO2(BO3)4]10− anions. Their oxygen arrangements often resemble those found in silicates. Tellurates adopt an octahedral TeO6 form, while borates are typically BO3 groups sharing oxygen atoms with tellurate units. The first mixed sodium rare earth borotellurates were discovered in 2015. Related compounds include boroantimonates and borophosphates, alongside other borate-based materials like boroselenates and borosulfates.

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Formation

Borotellurates are formed by heating boric acid, and tellurium dioxide, with metal carbonates or oxides at over 800 °C.⁵ Lower temperatures can be used with a flux like potassium carbonate.⁶

Reactions

When heated to around 800 °C the borotellurates decompose by emitting TeO3 vapour and form a metal borate⁷ or metal tellurite.⁸

List

	chem	mw	crystal system	space group	unit cell Å	volume	density	comment	references
	Rb3BaTeB7O15	837.02	monoclinic	P21/n	a=9.102 b=6.409 c=25.794 β=97.278 Z=4	1492.6	3.725	actually this is a tellurite	⁹
	Sr5TeO2(BO3)4	832.94	tetragonal	P4/mnc	a= 7.6005 c=10.401 Z=2	600.82	4.604	colourless; birefringence is 0.048 at 1064 nm	¹⁰
	Na2Y2TeO4(BO3)2	533.02	monoclinic	P21/c	a=6.3073, b=9.9279, c=6.7219; β=104.26°; Z=2	407.94	4.339		¹¹
barium tellurium borate	Ba4B8TeO19	1067.44	monoclinic	Cc	a=11.512 b=6.667 c=19.700 β=105.734 Z=4	1455.3	4.872	double layers; SHG 1×KH2PO4	¹²
	Ba2Mg2TeB2O10	632.52	orthorhombic	Cmca	a=6.177 b=10.383 c=12.956 Z=4	830.9	5		¹³
	Na2Dy2TeO4(BO3)2	680.20	monoclinic	P21/c	a=6.3089, b=9.9808, c=6.7489; β=104.394°; Z=2	411.62	5.488	decompose 842.1	¹⁴
	Na2Ho2TeO4(BO3)2	685.06	monoclinic	P21/c	a=6.3060, b=9.9360, c=6.7339; β=104.230°; Z=2	408.98	5.563	decompose 844.2	¹⁵
	Na2Er2TeO4(BO3)2	689.72	monoclinic	P21/c	a=6.2964, b=9.9056, c=6.7089; β=104.110°; Z=2	405.81	5.645	decompose 850.5	¹⁶
	Na2Tm2TeO4(BO3)2	693.06	monoclinic	P21/c	a=6.2801, b=9.8594, c=6.6918; β=104.010°; Z=2	401.89	5.727	decompose 852.0	¹⁷
	Na2Yb2TeO4(BO3)2	701.28	monoclinic	P21/c	a=6.2631, b=9.8269, c=6.6741; β=103.972°; Z=2	398.62	5.843	decompose 871.0	¹⁸
	Na2Lu2TeO4(BO3)2	705.14	monoclinic	P21/c	a=6.2588, b=9.7998, c=6.6539; β=103.714°; Z=2	396.48	5.907	decompose 878.5	¹⁹
	Pb2Mg2TeB2O10	772.22	orthorhombic	Cmca	a=6.055 b=10.300 c=12.521 Z=4	780.9	7		²⁰

References

Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Kong, Fang; Ma, Yunxiang; Mao, Jianggao (January 2018). "Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations: Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations". Chinese Journal of Chemistry. 36 (1): 63–72. doi:10.1002/cjoc.201700597. /wiki/Doi_(identifier) ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Liu, Lili; Young, Joshua; Smeu, Manuel; Halasyamani, P. Shiv (2018-04-16). "Ba 4 B 8 TeO 19 : A UV Nonlinear Optical Material". Inorganic Chemistry. 57 (8): 4771–4776. doi:10.1021/acs.inorgchem.8b00510. ISSN 0020-1669. PMID 29613780. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b00510 ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Daub, Michael; Krummer, Michael; Hoffmann, Anke; Bayarjargal, Lkhamsuren; Hillebrecht, Harald (2017-01-26). "Synthesis, Crystal Structure, and Properties of Bi 3 TeBO 9 or Bi 3 (TeO 6 )(BO 3 ): A Non-Centrosymmetric Borate-Tellurate(VI) of Bismuth". Chemistry - A European Journal. 23 (6): 1331–1337. doi:10.1002/chem.201602480. PMID 27981647. http://doi.wiley.com/10.1002/chem.201602480 ↩
Sun, Jun; Mutailipu, Miriding; Cheng, Shichao; Yang, Zhihua; Pan, Shilie (2020). "Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra". Dalton Transactions. 49 (26): 8911–8917. doi:10.1039/D0DT01102A. ISSN 1477-9226. PMID 32555807. S2CID 219910405. http://xlink.rsc.org/?DOI=D0DT01102A ↩
Tang, Ruling; Hu, Chunli; Feng, Jianghe; Fang, Zhi; Chen, Yan; Kong, Fang; Mao, Jianggao (2020). "Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions". Dalton Transactions. 49 (12): 3743–3749. doi:10.1039/C9DT03839F. ISSN 1477-9226. PMID 31729509. S2CID 208037429. http://xlink.rsc.org/?DOI=C9DT03839F ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Liu, Lili; Young, Joshua; Smeu, Manuel; Halasyamani, P. Shiv (2018-04-16). "Ba 4 B 8 TeO 19 : A UV Nonlinear Optical Material". Inorganic Chemistry. 57 (8): 4771–4776. doi:10.1021/acs.inorgchem.8b00510. ISSN 0020-1669. PMID 29613780. https://pubs.acs.org/doi/10.1021/acs.inorgchem.8b00510 ↩
Wen, Ming; Wu, Hongping; Hu, Cong; Yang, Zhihua; Pan, Shilie (2019-08-19). "Experiment and First-Principles Calculations of A 2 Mg 2 TeB 2 O 10 (A = Pb, Ba): Influences of the Cosubstitution on the Structure Transformation and Optical Properties". Inorganic Chemistry. 58 (16): 11127–11132. doi:10.1021/acs.inorgchem.9b01693. ISSN 0020-1669. PMID 31355637. S2CID 198965987. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b01693 ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Feng, Jiang-He; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2 March 2015). "Na 2 RE 2 TeO 4 (BO 3 ) 2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates". Inorganic Chemistry. 54 (5): 2447–2454. doi:10.1021/ic503068s. PMID 25692324. /wiki/Doi_(identifier) ↩
Wen, Ming; Wu, Hongping; Hu, Cong; Yang, Zhihua; Pan, Shilie (2019-08-19). "Experiment and First-Principles Calculations of A 2 Mg 2 TeB 2 O 10 (A = Pb, Ba): Influences of the Cosubstitution on the Structure Transformation and Optical Properties". Inorganic Chemistry. 58 (16): 11127–11132. doi:10.1021/acs.inorgchem.9b01693. ISSN 0020-1669. PMID 31355637. S2CID 198965987. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b01693 ↩