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Fluoroacetone
Chemical compound

Fluoroacetone is an organofluorine compound with the chemical formula C3H5FO. Under normal conditions, the substance is a colorless liquid. Fluoroacetone is also a highly toxic and flammable compound. Fumes of fluoroacetone can form an explosive mixture with air.

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Synthesis

Fluoroacetone can be obtained by a reaction of triethylamine tris-hydrofluoride with bromoacetone.

Applications

Fluoroacetone is used as a catalyst to study the kinetics of the ketone-catalysed decomposition of peroxymonosulfuric acid (Caro's acid).4 It is also a precursor material for the production of higher fluoroketones.

Fluoroacetone has not been used as a lachrymatory substance in contrast to other halogenated acetone derivatives, such as bromoacetone or chloroacetone.

See also

References

  1. "Fluoroacetone Basic information". chemicalbook.com. Retrieved 1 June 2017. http://www.chemicalbook.com/ProductChemicalPropertiesCB7853623_EN.htm

  2. Newallis, Peter E.; Lombardo, Pasquale (1965). "Fluoro Ketones. III. Preparation and Thermal Decomposition of Fluoroacetone Hemiketal Esters". J. Org. Chem. 30 (11): 3834–3837. doi:10.1021/jo01022a055. /wiki/J._Org._Chem.

  3. "Substance information". echa.europa.eu. Retrieved 1 June 2017. https://echa.europa.eu/substance-information/-/substanceinfo/100.006.423

  4. "Fluoroacetone". Sigma Aldrich. sigmaaldrich.com. Retrieved 1 June 2017. http://www.sigmaaldrich.com/catalog/product/aldrich/115460?lang=en®ion=RU&gclid=Cj0KEQjw9r7JBRCj37PlltTskaMBEiQAKTzTfCCBAPuOAJJ4w2PZ2SbhBA617Fli51x_CgVDFxLCdd8aAh5w8P8HAQ