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Lithium bis(trifluoromethanesulfonyl)imide
Chemical compound

Lithium bis(trifluoromethanesulfonyl)imide, often simply referred to as LiTFSI, is a hydrophilic salt with the chemical formula LiC2F6NO4S2. It is commonly used as Li-ion source in electrolytes for Li-ion batteries as a safer alternative to commonly used lithium hexafluorophosphate. It is made up of one Li cation and a bistriflimide anion.

Because of its very high solubility in water (> 21 m), LiTFSI has been used as lithium salt in water-in-salt electrolytes for aqueous lithium-ion batteries.

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References

  1. Pubchem. "90076-65-6 | C2F6LiNO4S2 - PubChem". pubchem.ncbi.nlm.nih.gov. Retrieved 2017-03-11. https://pubchem.ncbi.nlm.nih.gov/compound/90076-65-6#section=Top

  2. Kalhoff, Julian; Bresser, Dominic; Bolloli, Marco; Alloin, Fannie; Sanchez, Jean-Yves; Passerini, Stefano (2014-10-01). "Enabling LiTFSI-based Electrolytes for Safer Lithium-Ion Batteries by Using Linear Fluorinated Carbonates as (Co)Solvent". ChemSusChem. 7 (10): 2939–2946. Bibcode:2014ChSCh...7.2939K. doi:10.1002/cssc.201402502. ISSN 1864-564X. PMID 25138922. /wiki/Bibcode_(identifier)

  3. Suo, Liumin; Borodin, Oleg; Gao, Tao; Olguin, Marco; Ho, Janet; Fan, Xiulin; Luo, Chao; Wang, Chunsheng; Xu, Kang (2015-11-20). ""Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries". Science. 350 (6263): 938–943. doi:10.1126/science.aab1595. ISSN 0036-8075. PMID 26586759. S2CID 206637574. /wiki/Doi_(identifier)

  4. Smith, Leland; Dunn, Bruce (2015-11-20). "Opening the window for aqueous electrolytes". Science. 350 (2015): 918. doi:10.1126/science.aad5575. ISSN 0036-8075. PMID 26586752. S2CID 206643843. /wiki/Doi_(identifier)