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Synthesis

Synthesis of ytterbium(II) sulfide can be via a reaction of pure substances in an inert atmosphere:³

An alternative synthesis is by comproportionation of ytterbium(III) sulfide and ytterbium metal in vacuum at 1000–1100 °C:

Physical properties

Ytterbium(II) sulfide forms black crystals of cubic symmetry, space group Fm3m, cell parameter a = 0.5658 nm, Z = 4.⁴

Ytterbium(II) sulfide demonstrates semiconductor behavior.⁵

References

1. O'Bannon, Loran (6 December 2012). Dictionary of Ceramic Science and Engineering. Springer Science & Business Media. p. 280. ISBN 978-1-4613-2655-7. Retrieved 4 April 2023. 978-1-4613-2655-7 ↩

2. Derz, Friedrich W. (18 May 2020). H-Z. Walter de Gruyter GmbH & Co KG. p. 1971. ISBN 978-3-11-232209-3. Retrieved 4 April 2023. 978-3-11-232209-3 ↩

3. Kudryashov, M. A.; Logunov, A. A.; Mochalov, L. A. (2001). "Direct one-stage plasma-chemical synthesis of chalcogenide films doped with ytterbium". Journal of Physics: Conference Series. 1967: 012005. doi:10.1088/1742-6596/1967/1/012005. https://doi.org/10.1088%2F1742-6596%2F1967%2F1%2F012005 ↩

4. "mp-1820: YbS (Cubic, Fm-3m, 225)". Materials Project. Retrieved 4 April 2023. https://materialsproject.org/materials/mp-1820 ↩

5. Chen, Yuqi; Li, Liang; Hirai, Shinji (1 April 2019). "Fabrication, sintering, heat capacity, magnetic and magnetroresistivity properties of ytterbium sulfides". Journal of Magnetism and Magnetic Materials. 476: 289–296. Bibcode:2019JMMM..476..289C. doi:10.1016/j.jmmm.2018.12.100. ISSN 0304-8853. S2CID 127540609. Retrieved 4 April 2023. https://ui.adsabs.harvard.edu/abs/2019JMMM..476..289C/abstract ↩