Some 238U atoms, however, could capture another amount of neutrons (most likely, 16 or 17).
The discovery of the new elements, and the new data on neutron capture, was initially kept secret on the orders of the U.S. military until 1955 due to Cold War tensions. Nevertheless, the Berkeley team was able to prepare elements 99 and 100 by civilian means, through the neutron bombardment of plutonium-239, and published this work in 1954 with the disclaimer that it was not the first studies that had been carried out on the elements. The "Ivy Mike" studies were declassified and published in 1955.
The Berkeley team had been worried that another group might discover lighter isotopes of element 100 through ion-bombardment techniques before they could publish their classified research, and this proved to be the case. A group at the Nobel Institute for Physics in Stockholm independently discovered the element, producing an isotope later confirmed to be 250Fm (t1/2 = 30 min) by bombarding a 23892U target with oxygen-16 ions, and published their work in May 1954. Nevertheless, the priority of the Berkeley team was generally recognized, and with it the prerogative to name the new element in honour of Enrico Fermi, the developer of the first artificial self-sustained nuclear reactor. Fermi was still alive when the name was proposed, but had died by the time it became official.
There are 20 isotopes of fermium listed in NUBASE 2016, with atomic weights of 241 to 260, of which 257Fm is the longest-lived with a half-life of 100.5 days. 253Fm has a half-life of 3 days, while 251Fm of 5.3 h, 252Fm of 25.4 h, 254Fm of 3.2 h, 255Fm of 20.1 h, and 256Fm of 2.6 hours. All the remaining ones have half-lives ranging from 30 minutes to less than a millisecond.
The neutron capture product of fermium-257, 258Fm, undergoes spontaneous fission with a half-life of just 370(14) microseconds; 259Fm and 260Fm also undergo spontaneous fission (t1/2 = 1.5(3) s and 4 ms respectively). This means that neutron capture cannot be used to create nuclides with a mass number greater than 257, unless carried out in a nuclear explosion. As 257Fm alpha decays to 253Cf, and no known fermium isotopes undergo beta minus decay to the next element, mendelevium, fermium is also the last element that can be synthesized by neutron-capture. Because of this impediment in forming heavier isotopes, these short-lived isotopes 258–260Fm constitute the "fermium gap."
The atmospheric results were supplemented by the underground test data accumulated in the 1960s at the Nevada Test Site, as it was hoped that powerful explosions conducted in confined space might result in improved yields and heavier isotopes. Apart from traditional uranium charges, combinations of uranium with americium and thorium have been tried, as well as a mixed plutonium-neptunium charge. They were less successful in terms of yield, which was attributed to stronger losses of heavy isotopes due to enhanced fission rates in heavy-element charges. Isolation of the products was found to be rather problematic, as the explosions were spreading debris through melting and vaporizing rocks under the great depth of 300–600 meters, and drilling to such depth in order to extract the products was both slow and inefficient in terms of collected volumes.
Among the nine underground tests, which were carried between 1962 and 1969 and codenamed Anacostia (5.2 kilotons, 1962), Kennebec (<5 kilotons, 1963), Par (38 kilotons, 1964), Barbel (<20 kilotons, 1964), Tweed (<20 kilotons, 1965), Cyclamen (13 kilotons, 1966), Kankakee (20-200 kilotons, 1966), Vulcan (25 kilotons, 1966) and Hutch (20-200 kilotons, 1969), the last one was most powerful and had the highest yield of transuranium elements. In the dependence on the atomic mass number, the yield showed a saw-tooth behavior with the lower values for odd isotopes, due to their higher fission rates. The major practical problem of the entire proposal, however, was collecting the radioactive debris dispersed by the powerful blast. Aircraft filters adsorbed only about 4×10−14 of the total amount and collection of tons of corals at Enewetak Atoll increased this fraction by only two orders of magnitude. Extraction of about 500 kilograms of underground rocks 60 days after the Hutch explosion recovered only about 10−7 of the total charge. The amount of transuranium elements in this 500-kg batch was only 30 times higher than in a 0.4 kg rock picked up 7 days after the test. This observation demonstrated the highly nonlinear dependence of the transuranium elements yield on the amount of retrieved radioactive rock. In order to accelerate sample collection after the explosion, shafts were drilled at the site not after but before the test, so that the explosion would expel radioactive material from the epicenter, through the shafts, to collecting volumes near the surface. This method was tried in the Anacostia and Kennebec tests and instantly provided hundreds of kilograms of material, but with actinide concentrations 3 times lower than in samples obtained after drilling; whereas such a method could have been efficient in scientific studies of short-lived isotopes, it could not improve the overall collection efficiency of the produced actinides.
Though no new elements (apart from einsteinium and fermium) could be detected in the nuclear test debris, and the total yields of transuranium elements were disappointingly low, these tests did provide significantly higher amounts of rare heavy isotopes than previously available in laboratories. For example, 6×109 atoms of 257Fm could be recovered after the Hutch detonation. They were then used in the studies of thermal-neutron induced fission of 257Fm and in discovery of a new fermium isotope 258Fm. Also, the rare isotope 250Cm was synthesized in large quantities, which is very difficult to produce in nuclear reactors from its progenitor 249Cm; the half-life of 249Cm (64 minutes) is much too short for months-long reactor irradiations, but is very "long" on the explosion timescale.
The chemistry of fermium has only been studied in solution using tracer techniques, and no solid compounds have been prepared. Under normal conditions, fermium exists in solution as the Fm3+ ion, which has a hydration number of 16.9 and an acid dissociation constant of 1.6×10−4 (pKa = 3.8). Fm3+ forms complexes with a wide variety of organic ligands with hard donor atoms such as oxygen, and these complexes are usually more stable than those of the preceding actinides. It also forms anionic complexes with ligands such as chloride or nitrate and, again, these complexes appear to be more stable than those formed by einsteinium or californium. It is believed that the bonding in the complexes of the later actinides is mostly ionic in character: the Fm3+ ion is expected to be smaller than the preceding An3+ ions because of the higher effective nuclear charge of fermium, and hence fermium would be expected to form shorter and stronger metal–ligand bonds.
Silva, Robert J. (2006). "Fermium, Mendelevium, Nobelium, and Lawrencium" (PDF). In Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements. Vol. 3 (3rd ed.). Dordrecht: Springer. pp. 1621–1651. doi:10.1007/1-4020-3598-5_13. ISBN 978-1-4020-3555-5. Archived from the original (PDF) on 17 July 2010. 978-1-4020-3555-5
"Einsteinium". Archived from the original on 26 October 2007. Retrieved 7 December 2007. https://web.archive.org/web/20071026052909/http://periodic.lanl.gov/elements/99.html
Fermium – National Research Council Canada Archived 2010-12-25 at the Wayback Machine. Retrieved 2 December 2007 http://www.nrc-cnrc.gc.ca/eng/education/elements/el/fm.html
Ghiorso, Albert (2003). "Einsteinium and Fermium". Chemical and Engineering News. 81 (36): 174–175. doi:10.1021/cen-v081n036.p174. /wiki/Albert_Ghiorso
Ghiorso, Albert (2003). "Einsteinium and Fermium". Chemical and Engineering News. 81 (36): 174–175. doi:10.1021/cen-v081n036.p174. /wiki/Albert_Ghiorso
Ghiorso, Albert (2003). "Einsteinium and Fermium". Chemical and Engineering News. 81 (36): 174–175. doi:10.1021/cen-v081n036.p174. /wiki/Albert_Ghiorso
"Einsteinium". Archived from the original on 26 October 2007. Retrieved 7 December 2007. https://web.archive.org/web/20071026052909/http://periodic.lanl.gov/elements/99.html
Fermium – National Research Council Canada Archived 2010-12-25 at the Wayback Machine. Retrieved 2 December 2007 http://www.nrc-cnrc.gc.ca/eng/education/elements/el/fm.html
Ghiorso, Albert (2003). "Einsteinium and Fermium". Chemical and Engineering News. 81 (36): 174–175. doi:10.1021/cen-v081n036.p174. /wiki/Albert_Ghiorso
Ghiorso, Albert (2003). "Einsteinium and Fermium". Chemical and Engineering News. 81 (36): 174–175. doi:10.1021/cen-v081n036.p174. /wiki/Albert_Ghiorso
Ghiorso, Albert (2003). "Einsteinium and Fermium". Chemical and Engineering News. 81 (36): 174–175. doi:10.1021/cen-v081n036.p174. /wiki/Albert_Ghiorso
Ghiorso, A.; Thompson, S.; Higgins, G.; Seaborg, Glenn T.; Studier, M.; Fields, P.; Fried, S.; Diamond, H.; et al. (1955). "New Elements Einsteinium and Fermium, Atomic Numbers 99 and 100" (PDF). Phys. Rev. 99 (3): 1048–1049. Bibcode:1955PhRv...99.1048G. doi:10.1103/PhysRev.99.1048.Mikheev, N. B.; Spitsyn, V. I.; Kamenskaya, A. N.; Konovalova, N. A.; Rumer, I. A.; Auerman, L. N.; Podorozhnyi, A. M. (1977). "Determination of oxidation potential of the pair Fm2+/Fm3+". Inorg. Nucl. Chem. Lett. 13 (12): 651–656. doi:10.1016/0020-1650(77)80074-3. https://cloudfront.escholarship.org/dist/prd/content/qt70q401ct/qt70q401ct.pdf
Fields, P. R.; Studier, M. H.; Diamond, H.; Mech, J. F.; Inghram, M. G. Pyle, G. L.; Stevens, C. M.; Fried, S.; Manning, W. M. (Argonne National Laboratory, Lemont, Illinois); Ghiorso, A.; Thompson, S. G.; Higgins, G. H.; Seaborg, G. T. (University of California, Berkeley, California): "Transplutonium Elements in Thermonuclear Test Debris", in: Fields, P.; Studier, M.; Diamond, H.; Mech, J.; Inghram, M.; Pyle, G.; Stevens, C.; Fried, S.; Manning, W.; Ghiorso, A.; Thompson, S.; Higgins, G.; Seaborg, G. (1956). "Transplutonium Elements in Thermonuclear Test Debris". Physical Review. 102 (1): 180. Bibcode:1956PhRv..102..180F. doi:10.1103/PhysRev.102.180. /wiki/Bibcode_(identifier)
Thompson, S. G.; Ghiorso, A.; Harvey, B. G.; Choppin, G. R. (1954). "Transcurium Isotopes Produced in the Neutron Irradiation of Plutonium" (PDF). Physical Review. 93 (4): 908. Bibcode:1954PhRv...93..908T. doi:10.1103/PhysRev.93.908.Nugent, L. J. (1975). MTP Int. Rev. Sci.: Inorg. Chem. 7: 195–219. {{cite journal}}: Missing or empty |title= (help) /wiki/Albert_Ghiorso
Choppin, G. R.; Thompson, S. G.; Ghiorso, A.; Harvey, B. G. (1954). "Nuclear Properties of Some Isotopes of Californium, Elements 99 and 100". Physical Review. 94 (4): 1080–1081. Bibcode:1954PhRv...94.1080C. doi:10.1103/PhysRev.94.1080. /wiki/Albert_Ghiorso
Ghiorso, A.; Thompson, S.; Higgins, G.; Seaborg, Glenn T.; Studier, M.; Fields, P.; Fried, S.; Diamond, H.; et al. (1955). "New Elements Einsteinium and Fermium, Atomic Numbers 99 and 100" (PDF). Phys. Rev. 99 (3): 1048–1049. Bibcode:1955PhRv...99.1048G. doi:10.1103/PhysRev.99.1048.Mikheev, N. B.; Spitsyn, V. I.; Kamenskaya, A. N.; Konovalova, N. A.; Rumer, I. A.; Auerman, L. N.; Podorozhnyi, A. M. (1977). "Determination of oxidation potential of the pair Fm2+/Fm3+". Inorg. Nucl. Chem. Lett. 13 (12): 651–656. doi:10.1016/0020-1650(77)80074-3. https://cloudfront.escholarship.org/dist/prd/content/qt70q401ct/qt70q401ct.pdf
Ghiorso, Albert (2003). "Einsteinium and Fermium". Chemical and Engineering News. 81 (36): 174–175. doi:10.1021/cen-v081n036.p174. /wiki/Albert_Ghiorso
Atterling, Hugo; Forsling, Wilhelm; Holm, Lennart W.; Melander, Lars; Åström, Björn (1954). "Element 100 Produced by Means of Cyclotron-Accelerated Oxygen Ions". Physical Review. 95 (2): 585–586. Bibcode:1954PhRv...95..585A. doi:10.1103/PhysRev.95.585.2. /wiki/Bibcode_(identifier)
Hoffman, D. C.; Ghiorso, A.; Seaborg, G. T. (2000). The Transuranium People: The Inside Story. World Scientific. pp. 187–189. ISBN 978-1-78-326244-1. 978-1-78-326244-1
Audi, G.; Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S. (2017). "The NUBASE2016 evaluation of nuclear properties" (PDF). Chinese Physics C. 41 (3): 030001. Bibcode:2017ChPhC..41c0001A. doi:10.1088/1674-1137/41/3/030001.
https://www-nds.iaea.org/amdc/ame2016/NUBASE2016.pdf
The discovery of 260Fm is considered "unproven" in NUBASE 2003.[16]
Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001Sewtz, M.; Backe, H.; Dretzke, A.; Kube, G.; Lauth, W.; Schwamb, P.; Eberhardt, K.; Grüning, C.; Thörle, P.; Trautmann, N.; Kunz, P.; Lassen, J.; Passler, G.; Dong, C.; Fritzsche, S.; Haire, R. (2003). "First Observation of Atomic Levels for the Element Fermium (Z=100)". Phys. Rev. Lett. 90 (16): 163002. Bibcode:2003PhRvL..90p3002S. doi:10.1103/PhysRevLett.90.163002. PMID 12731975. S2CID 16234935. /wiki/Aaldert_Wapstra
Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001Sewtz, M.; Backe, H.; Dretzke, A.; Kube, G.; Lauth, W.; Schwamb, P.; Eberhardt, K.; Grüning, C.; Thörle, P.; Trautmann, N.; Kunz, P.; Lassen, J.; Passler, G.; Dong, C.; Fritzsche, S.; Haire, R. (2003). "First Observation of Atomic Levels for the Element Fermium (Z=100)". Phys. Rev. Lett. 90 (16): 163002. Bibcode:2003PhRvL..90p3002S. doi:10.1103/PhysRevLett.90.163002. PMID 12731975. S2CID 16234935. /wiki/Aaldert_Wapstra
Silva, Robert J. (2006). "Fermium, Mendelevium, Nobelium, and Lawrencium" (PDF). In Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements. Vol. 3 (3rd ed.). Dordrecht: Springer. pp. 1621–1651. doi:10.1007/1-4020-3598-5_13. ISBN 978-1-4020-3555-5. Archived from the original (PDF) on 17 July 2010. 978-1-4020-3555-5
Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. p. 1262. ISBN 978-0-08-022057-4.Samhoun, K.; David, F.; Hahn, R. L.; O'Kelley, G. D.; Tarrant, J. R.; Hobart, D. E. (1979). "Electrochemical study of mendelevium in aqueous solution: No evidence for monovalent ions". J. Inorg. Nucl. Chem. 41 (12): 1749–1754. doi:10.1016/0022-1902(79)80117-7. 978-0-08-022057-4
Sonzogni, Alejandro. "Interactive Chart of Nuclides". National Nuclear Data Center: Brookhaven National Laboratory. Archived from the original on 21 June 2018. Retrieved 6 June 2008. https://web.archive.org/web/20180621170934/http://www.nndc.bnl.gov/chart/reCenter.jsp?z=100&n=147
Zagrebaev, Valeriy; Karpov, Alexander; Greiner, Walter (2013). "Future of superheavy element research: Which nuclei could be synthesized within the next few years?" (PDF). Journal of Physics. 420 (12001): 11. arXiv:1207.5700. Bibcode:2013JPhCS.420a2001Z. doi:10.1088/1742-6596/420/1/012001. S2CID 55434734.Hoff, R. W.; Hulet, E. K. (1970). "Engineering with Nuclear Explosives". 2: 1283–1294. {{cite journal}}: Cite journal requires |journal= (help) http://nrv.jinr.ru/pdf_file/J_phys_2013.pdf
All isotopes of elements Z > 100 can only be produced by accelerator-based nuclear reactions with charged particles and can be obtained only in tracer quantities (e.g., 1 million atoms for Md (Z = 101) per hour of irradiation (see Silva 2006).
Luig, Heribert; Keller, Cornelius; Wolf, Walter; Shani, Jashovam; Miska, Horst; Zyball, Alfred; Gervé, Andreas; Balaban, Alexandru T.; Kellerer, Albrecht M.; Griebel, Jürgen (2000). "Radionuclides". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a22_499. ISBN 978-3527306732. 978-3527306732
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Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001Sewtz, M.; Backe, H.; Dretzke, A.; Kube, G.; Lauth, W.; Schwamb, P.; Eberhardt, K.; Grüning, C.; Thörle, P.; Trautmann, N.; Kunz, P.; Lassen, J.; Passler, G.; Dong, C.; Fritzsche, S.; Haire, R. (2003). "First Observation of Atomic Levels for the Element Fermium (Z=100)". Phys. Rev. Lett. 90 (16): 163002. Bibcode:2003PhRvL..90p3002S. doi:10.1103/PhysRevLett.90.163002. PMID 12731975. S2CID 16234935. /wiki/Aaldert_Wapstra
Zagrebaev, Valeriy; Karpov, Alexander; Greiner, Walter (2013). "Future of superheavy element research: Which nuclei could be synthesized within the next few years?" (PDF). Journal of Physics. 420 (12001): 11. arXiv:1207.5700. Bibcode:2013JPhCS.420a2001Z. doi:10.1088/1742-6596/420/1/012001. S2CID 55434734.Hoff, R. W.; Hulet, E. K. (1970). "Engineering with Nuclear Explosives". 2: 1283–1294. {{cite journal}}: Cite journal requires |journal= (help) http://nrv.jinr.ru/pdf_file/J_phys_2013.pdf
Silva, Robert J. (2006). "Fermium, Mendelevium, Nobelium, and Lawrencium" (PDF). In Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements. Vol. 3 (3rd ed.). Dordrecht: Springer. pp. 1621–1651. doi:10.1007/1-4020-3598-5_13. ISBN 978-1-4020-3555-5. Archived from the original (PDF) on 17 July 2010. 978-1-4020-3555-5
Choppin, G. R.; Harvey, B. G.; Thompson, S. G. (1956). "A new eluant for the separation of the actinide elements" (PDF). J. Inorg. Nucl. Chem. 2 (1): 66–68. doi:10.1016/0022-1902(56)80105-X. https://escholarship.org/content/qt73d377r3/qt73d377r3.pdf?t=p0fvlf
Silva, Robert J. (2006). "Fermium, Mendelevium, Nobelium, and Lawrencium" (PDF). In Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements. Vol. 3 (3rd ed.). Dordrecht: Springer. pp. 1621–1651. doi:10.1007/1-4020-3598-5_13. ISBN 978-1-4020-3555-5. Archived from the original (PDF) on 17 July 2010. 978-1-4020-3555-5
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Mikheev, N. B.; Kamenskaya, A. N.; Konovalova, N. A.; Rumer, I. A.; Kulyukhin, S. A. (1983). "High-speed method for the separation of fermium from actinides and lanthanides". Radiokhimiya. 25 (2): 158–161.
Silva, Robert J. (2006). "Fermium, Mendelevium, Nobelium, and Lawrencium" (PDF). In Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements. Vol. 3 (3rd ed.). Dordrecht: Springer. pp. 1621–1651. doi:10.1007/1-4020-3598-5_13. ISBN 978-1-4020-3555-5. Archived from the original (PDF) on 17 July 2010. 978-1-4020-3555-5
Seaborg, p. 39
Seaborg, p. 39
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Seaborg, p. 40United States Nuclear Tests July 1945 through September 1992 Archived June 15, 2010, at the Wayback Machine, DOE/NV--209-REV 15, December 2000 http://www.nv.doe.gov/library/publications/historical/DOENV_209_REV15.pdf
Seaborg, p. 40United States Nuclear Tests July 1945 through September 1992 Archived June 15, 2010, at the Wayback Machine, DOE/NV--209-REV 15, December 2000 http://www.nv.doe.gov/library/publications/historical/DOENV_209_REV15.pdf
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Seaborg, p. 47
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Silva, Robert J. (2006). "Fermium, Mendelevium, Nobelium, and Lawrencium" (PDF). In Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean (eds.). The Chemistry of the Actinide and Transactinide Elements. Vol. 3 (3rd ed.). Dordrecht: Springer. pp. 1621–1651. doi:10.1007/1-4020-3598-5_13. ISBN 978-1-4020-3555-5. Archived from the original (PDF) on 17 July 2010. 978-1-4020-3555-5
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Dictionary of Inorganic Compounds. Vol. 3 (1 ed.). Chapman & Hall. 1992. p. 2873. ISBN 0412301202. 0412301202
Ghiorso, A.; Thompson, S.; Higgins, G.; Seaborg, Glenn T.; Studier, M.; Fields, P.; Fried, S.; Diamond, H.; et al. (1955). "New Elements Einsteinium and Fermium, Atomic Numbers 99 and 100" (PDF). Phys. Rev. 99 (3): 1048–1049. Bibcode:1955PhRv...99.1048G. doi:10.1103/PhysRev.99.1048.Mikheev, N. B.; Spitsyn, V. I.; Kamenskaya, A. N.; Konovalova, N. A.; Rumer, I. A.; Auerman, L. N.; Podorozhnyi, A. M. (1977). "Determination of oxidation potential of the pair Fm2+/Fm3+". Inorg. Nucl. Chem. Lett. 13 (12): 651–656. doi:10.1016/0020-1650(77)80074-3. https://cloudfront.escholarship.org/dist/prd/content/qt70q401ct/qt70q401ct.pdf
Thompson, S. G.; Ghiorso, A.; Harvey, B. G.; Choppin, G. R. (1954). "Transcurium Isotopes Produced in the Neutron Irradiation of Plutonium" (PDF). Physical Review. 93 (4): 908. Bibcode:1954PhRv...93..908T. doi:10.1103/PhysRev.93.908.Nugent, L. J. (1975). MTP Int. Rev. Sci.: Inorg. Chem. 7: 195–219. {{cite journal}}: Missing or empty |title= (help) /wiki/Albert_Ghiorso
Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. p. 1262. ISBN 978-0-08-022057-4.Samhoun, K.; David, F.; Hahn, R. L.; O'Kelley, G. D.; Tarrant, J. R.; Hobart, D. E. (1979). "Electrochemical study of mendelevium in aqueous solution: No evidence for monovalent ions". J. Inorg. Nucl. Chem. 41 (12): 1749–1754. doi:10.1016/0022-1902(79)80117-7. 978-0-08-022057-4
Koch, Lothar (2000). "Transuranium Elements". Transuranium Elements, in Ullmann's Encyclopedia of Industrial Chemistry. Wiley. doi:10.1002/14356007.a27_167. ISBN 978-3527306732. 978-3527306732