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Mercury-vapor lamp
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<h2 id="origins">Origins</h2> <p><a href="/facts/Charles_Wheatstone/935jnRhj">Charles Wheatstone</a> observed the spectrum of an electric discharge in mercury vapor in 1835, and noted the ultraviolet lines in that spectrum. In 1860, John Thomas Way used arc lamps operated in a mixture of air and mercury vapor at atmospheric pressure for lighting.<a class="footnote-ref" id="fnref:11" href="#fn:11"><sup>11</sup></a> The German physicist <a href="/facts/Leo_Arons/ufEk1kb2">Leo Arons</a> (1860–1919) studied mercury discharges in 1892 and developed a lamp based on a mercury arc.<a class="footnote-ref" id="fnref:12" href="#fn:12"><sup>12</sup></a> In February 1896 Herbert John Dowsing and H. S. Keating of England patented a mercury-vapor lamp, considered by some to be the first true mercury-vapor lamp.<a class="footnote-ref" id="fnref:13" href="#fn:13"><sup>13</sup></a> </p><p>The first mercury-vapor lamp to achieve widespread success was invented in 1901 by American engineer <a href="/facts/Peter_Cooper_Hewitt/aDtP2N8C">Peter Cooper Hewitt</a>.<a class="footnote-ref" id="fnref:14" href="#fn:14"><sup>14</sup></a> Hewitt was issued <a href="https://patents.google.com/patent/US682692">U.S. patent 682,692</a> on September 17, 1901.<a class="footnote-ref" id="fnref:15" href="#fn:15"><sup>15</sup></a> In 1903, Hewitt created an improved version that possessed more satisfactory color qualities which eventually found widespread industrial use.<a class="footnote-ref" id="fnref:16" href="#fn:16"><sup>16</sup></a> The ultraviolet light from mercury-vapor lamps was applied to water treatment by 1910. The Hewitt lamps used a large amount of mercury. In the 1930s, improved lamps of the modern form, developed by the <a href="/facts/General_Electric_Company_plc/kvuCGYSg">Osram-GEC company</a>, <a href="/facts/General_Electric/bBm5CzVY">General Electric</a> company and others led to widespread use of mercury-vapor lamps for general lighting. </p> <h2 id="principle-of-operation">Principle of operation</h2> <p>The mercury in the tube is a liquid at normal temperatures. It needs to be vaporized and <a href="/facts/Ionization/W13Ceavd">ionized</a> before the lamp can produce its full light output.<a class="footnote-ref" id="fnref:17" href="#fn:17"><sup>17</sup></a> To facilitate starting of the lamp, a third <a href="/facts/Electrode/251PaKX8">electrode</a> is mounted near one of the main electrodes and connected through a <a href="/facts/Resistor/JrsGReM6">resistor</a> to the other main electrode. In addition to the mercury, the tube is filled with <a href="/facts/Argon/QX6NRH6d">argon</a> gas at low pressure. When power is applied, if there is sufficient <a href="/facts/Voltage/EN2po6N2">voltage</a> to ionize the argon, the ionized argon gas will strike a small arc between the starting electrode and the adjacent main electrode. As the ionized argon conducts, the heat from its arc vaporizes the liquid mercury; next, the voltage between the two main electrodes will ionize the mercury gas. An arc initiates between the two main electrodes and the lamp will then radiate<a class="footnote-ref" id="fnref:18" href="#fn:18"><sup>18</sup></a> mainly in the ultraviolet, violet and blue <a href="/facts/Spectral_line/HuI4Bj5f">emission lines</a>. Continued vaporization of the liquid mercury increases the arc tube pressure to between 2 and 18 <a href="/facts/Bar_(unit)/wwFWTTkT">bar</a>, depending on lamp size. The increase in pressure results in further brightening of the lamp.<a class="footnote-ref" id="fnref:19" href="#fn:19"><sup>19</sup></a><a class="footnote-ref" id="fnref:20" href="#fn:20"><sup>20</sup></a> The entire warm-up process takes roughly 4 to 7 minutes. Some bulbs include a thermal switch which shorts the starting electrode to the adjacent main electrode, extinguishing the starting arc once the main arc strikes. </p><p>The mercury-vapor lamp is a <a href="/facts/Negative_resistance/QgkR8esF">negative resistance</a> device. This means its <a href="/facts/Resistance_(electricity)/hxSt0UAj">resistance</a> decreases as the <a href="/facts/Electric_current/Dc1xdnUX">current</a> through the tube increases. So if the lamp is connected directly to a constant-voltage source like the power lines, the current through it will increase until it destroys itself. Therefore, it requires a <a href="/facts/Ballast_(electrical)/wI5HEsbh">ballast</a> to limit the current through it. Mercury-vapor lamp ballasts are similar to the ballasts used with <a href="/facts/Fluorescent_lamp/R8SlXCyg">fluorescent lamps</a>. In fact, the first British fluorescent lamps were designed to operate from 80-watt mercury-vapor ballasts. There are also self-ballasted mercury-vapor lamps available. These lamps use a tungsten filament in series with the arc tube both to act as a resistive ballast and add full spectrum light to that of the arc tube. Self-ballasted mercury-vapor lamps can be screwed into a standard incandescent light socket supplied with the proper voltage. </p> <h3>Metal halide</h3> <p>A very closely related lamp design called the <a href="/facts/Metal_halide_lamp/kxCKb1E9">metal halide lamp</a> uses various compounds in the form of <a href="/facts/Metal_halides/6jsbrvcC">metal halides</a> with the mercury. <a href="/facts/Sodium_iodide/wc8xz4D7">Sodium iodide</a> and <a href="/facts/Scandium/TJRt1chg">scandium</a> <a href="/facts/Iodine/JlfMecMf">iodide</a> are commonly in use. These lamps can produce much better quality light without resorting to phosphors. If they use a starting electrode, there is always a thermal shorting switch to eliminate any electrical potential between the main electrode and the starting electrode once the lamp is lit. (This electrical potential in the presence of the halides can cause the failure of the glass/metal seal). More modern metal halide systems do not use a separate starting electrode; instead, the lamp is started using high <a href="/facts/Voltage/EN2po6N2">voltage</a> pulses as with high-pressure sodium vapor lamps. </p> <h3>Self-ballasted lamps</h3> <p>Self-ballasted (SB) lamps are mercury-vapor lamps with a <a href="/facts/Tungsten_filament/31frjg0A">tungsten filament</a> inside connected in series with the arc tube that functions as an electrical ballast. This is the only kind of mercury-vapor lamp that can be connected directly to the mains without an external ballast. These lamps are considerably more efficient than incandescent lamps of similar size, and also have the added benefit of longer lifespans. They give light immediately on startup, but usually need a few minutes to restrike if power has been interrupted. Because of the light emitted by the filament, they have slightly better color rendering properties than mercury-vapor lamps. Self-ballasted lamps are typically more expensive than a standard mercury-vapor lamp. </p> <h2 id="operation">Operation</h2> <p>When a mercury-vapor lamp is first turned on, it will produce a dark <a href="/facts/Blue/DHWb8MUa">blue</a> glow because only a small amount of the mercury is ionized and the gas pressure in the arc tube is very low, so much of the light is produced in the <a href="/facts/Ultraviolet/kncBUqn5">ultraviolet</a> mercury bands. As the main arc strikes and the gas heats up and increases in pressure, the light shifts into the <a href="/facts/Visible_spectrum/frPBh8o5">visible range</a> and the high gas pressure causes the mercury emission bands to broaden somewhat, producing a light that appears more white to the human eye, although it is still not a <a href="/facts/Continuous_spectrum/CYz0fv0d">continuous spectrum</a>. Even at full intensity, the light from a mercury-vapor lamp with no phosphors is distinctly bluish in color. The pressure in the quartz arc-tube rises to approximately one atmosphere once the bulb has reached its working temperature. If the discharge should be interrupted (e.g. by interruption of the electric supply), it is not possible for the lamp to restrike until the bulb cools enough for the pressure to fall considerably. The reason for a prolonged period of time before the lamp restrikes is to due the elevated pressure, which leads to higher breakdown voltage of the gas inside (voltage needed to start an arc – <a href="/facts/Paschen%2527s_law/qSWw9dvP">Paschen's law</a>), which is outside the capabilities of the ballast. Because of this, many mercury-vapor lamps have a secondary lamp to function as a backup light source until the mercury-vapor lamp can restrike. This lamp is usually a halogen lamp of near or equal brightness. </p> <h3>Electrical parameters</h3> <p><a class="footnote-ref" id="fnref:21" href="#fn:21"><sup>21</sup></a> </p> <table><tbody><tr><td>Power</td><td>Voltage</td><td>Current</td></tr><tr><td>50W</td><td>95V</td><td>0.60A</td></tr><tr><td>80W</td><td>115V</td><td>0.80A</td></tr><tr><td>125W</td><td>125V</td><td>1.15A</td></tr><tr><td>250W</td><td>130V</td><td>2.15A</td></tr><tr><td>400W</td><td>135V</td><td>3.25A</td></tr><tr><td>700W</td><td>140V</td><td>5.40A</td></tr><tr><td>1000W</td><td>145V</td><td>7.50A</td></tr></tbody></table> <h3>Color considerations</h3> <p>To correct the bluish tinge, many mercury-vapor lamps are coated on the inside of the outer bulb with a <a href="/facts/Phosphor/vTLjrGDE">phosphor</a> that converts some portion of the ultraviolet emissions into red light. This helps to fill in the otherwise very-deficient red end of the <a href="/facts/Electromagnetic_spectrum/24LARvFY">electromagnetic spectrum</a>. These lamps are generally called "color corrected" lamps. Most modern mercury-vapor lamps have this coating. One of the original complaints against mercury-lights was they tended to make people look like "bloodless corpses" because of the lack of light from the red end of the spectrum.<a class="footnote-ref" id="fnref:22" href="#fn:22"><sup>22</sup></a> A common method of correcting this problem before phosphors were used was to operate the mercury lamp in conjunction with an <a href="/facts/Incandescent_lamp/31frjg0A">incandescent lamp</a>. There is also an increase in red color (e.g., due to the continuous radiation) in ultra-high-pressure mercury-vapor lamps (usually greater than 200 atm.), which has found application in modern media projectors. When outside, coated or color corrected lamps can usually be identified by a blue "halo" around the light being given off. </p> <h3>Emission line spectrum</h3> <p>The strongest peaks of the emission line spectrum are<a class="footnote-ref" id="fnref:23" href="#fn:23"><sup>23</sup></a><a class="footnote-ref" id="fnref:24" href="#fn:24"><sup>24</sup></a> </p> <table><tbody><tr><th>Wavelength (nm)</th><th>Name (see <a href="/facts/Photoresist/XNnIkCjU">photoresist</a>)</th><th>Color</th></tr><tr><td>184.45</td><td></td><td>ultraviolet (UVC)</td></tr><tr><td>253.7</td><td></td><td>ultraviolet (UVC)</td></tr><tr><td>365.0</td><td>I-line</td><td>ultraviolet (UVA)</td></tr><tr><td>404.7</td><td>H-line</td><td>violet</td></tr><tr><td>435.8</td><td>G-line</td><td>blue</td></tr><tr><td>546.1</td><td></td><td>green</td></tr><tr><td>578</td><td></td><td>yellow-orange</td></tr></tbody></table> <p>In low-pressure mercury-vapor lamps only the lines at 184 nm and 254 nm are present. Fused silica is used in the manufacturing to keep the 184 nm light from being absorbed. In medium-pressure mercury-vapor lamps, the lines from 200 to 600 nm are present. The lamps can be constructed to emit primarily in the UV-A (around 400 nm) or UV-C (around 250 nm). High-pressure mercury-vapor lamps are commonly used for general lighting purposes. They emit primarily in the blue and green. </p> <h2 id="ultraviolet-cleaning">Ultraviolet cleaning</h2> <p>Low-pressure mercury-vapor lamps<a class="footnote-ref" id="fnref:25" href="#fn:25"><sup>25</sup></a> usually have a <a href="/facts/Quartz/4n86tE2G">quartz</a> bulb in order to allow the transmission of short <a href="/facts/Wavelength/kcJU0ymz">wavelength</a> light. If synthetic quartz is used, then the <a href="/facts/Transparency_(optics)/PRryNNW6">transparency</a> of the quartz is increased further and an <a href="/facts/Emission_spectrum/fxumR717">emission line</a> at 185 nm is observed also. Such a lamp can then be used for <a href="/facts/Ultraviolet_germicidal_irradiation/C7SYu8QS">ultraviolet germicidal irradiation</a>.<a class="footnote-ref" id="fnref:26" href="#fn:26"><sup>26</sup></a> The 185 nm line will create <a href="/facts/Ozone/o0E5gn2p">ozone</a> in an oxygen containing atmosphere, which helps in the cleaning process, but is also a health hazard. </p> <h2 id="light-pollution-considerations">Light pollution considerations</h2> <p>For placements where <a href="/facts/Light_pollution/AD03VyzX">light pollution</a> is of prime importance (for example, the <a href="/facts/Parking_lot/MW9oDgTm">parking lot</a> of an <a href="/facts/Observatory/y0FVg7vS">observatory</a>), <a href="/facts/Low-pressure_sodium_lamp/STEH8FgR">low-pressure sodium</a> is preferred. As it emits narrow spectral lines at two very close wavelengths, it is the easiest to filter out. Mercury-vapor lamps without any phosphor are second best; they produce only a few distinct mercury lines that need to be filtered out. </p> <h2 id="bans">Bans</h2> <p>In the <a href="/facts/European_Union/6GYcR8qM">EU</a> the use of low efficiency mercury-vapor lamps for lighting purposes was banned in 2015. It does not affect the use of mercury in <a href="/facts/Compact_fluorescent_lamp/gRsYSlYD">compact fluorescent lamp</a>, nor the use of mercury lamps for purposes other than lighting.<a class="footnote-ref" id="fnref:27" href="#fn:27"><sup>27</sup></a> </p><p>In the US, ballasts for mercury-vapor lamps for general illumination, excluding specialty application mercury-vapor lamp ballasts, were banned after January 1, 2008.<a class="footnote-ref" id="fnref:28" href="#fn:28"><sup>28</sup></a> Because of this, several manufacturers have begun selling replacement compact fluorescent (CFL) and light emitting diode (LED) bulbs for mercury-vapor fixtures, which do not require modifications to the existing fixture. The US <a href="/facts/United_States_Department_of_Energy/PRp6Cz8g">Department of Energy</a> determined in 2015 that regulations proposed in 2010 for the mercury vapor type of <a href="/facts/High-intensity_discharge_lamp/T7179PrP">HID</a> lamps would not be implemented, because they would not yield substantial savings.<a class="footnote-ref" id="fnref:29" href="#fn:29"><sup>29</sup></a> </p> <h2 id="ultraviolet-hazards">Ultraviolet hazards</h2> <p>The arctube of mercury lamps produces large amount of short wave <a href="/facts/Ultraviolet/kncBUqn5">UV-C</a> radiation which can cause eye and skin burns. Usually the glass outer jacket of the lamp and in some lamps, also the phosphor coating, block this radiation. However, care should be taken if the outer jacket of the lamp breaks, because the arctube would continue to operate, presenting a safety hazard.<a class="footnote-ref" id="fnref:30" href="#fn:30"><sup>30</sup></a> There have been documented cases in the United States of lamps being damaged in <a href="/facts/Gym/qNkSeNIU">gymnasiums</a> by balls striking the lamps, resulting in <a href="/facts/Sun_burn/Ff6gMYHA">sun burns</a> and eye inflammation from shortwave ultraviolet radiation.<a class="footnote-ref" id="fnref:31" href="#fn:31"><sup>31</sup></a> When used in locations like gyms, the fixture should contain a strong outer guard or an outer lens to protect the lamp's outer bulb. As a result of the said documented cases, some American manufacturers made "safety" lamps that will deliberately burn out if the outer glass is broken. This is usually achieved by using a thin tungsten strip, which will <a href="/facts/Combustion/ohQoWj8z">burn up</a> in the presence of air, to connect one of the electrodes. </p><p>Typical mercury-vapor lamps with an outer envelope made of <a href="/facts/Soda%25E2%2580%2593lime_glass/CFYbacLU">soda lime</a> or <a href="/facts/Borosilicate_glass/Ywaqt7Ic">borosilicate</a> glass still allow a relatively large amount of 365 nm UV radiation to escape the lamp. This can cause the <a href="/facts/Photo-oxidation_of_polymers/JD3bkFtL">accelerated aging</a> of some plastics used in the construction of luminaires, leaving them significantly discolored after only a few years' service. <a href="/facts/Polycarbonate/QU8sH1c6">Polycarbonate</a> suffers particularly from this problem and it is not uncommon to see fairly new polycarbonate surfaces positioned near the lamp to have turned a dull, yellow color after only a short time. </p> <h2 id="uses">Uses</h2> <h3>Area and street lighting</h3> <p>Although other types of <a href="/facts/High-intensity_discharge_lamp/T7179PrP">HIDs</a> are becoming more common, mercury-vapor lamps are still sometimes used for area lighting and <a href="/facts/Street_lighting/Uuw2oH1y">street lighting</a> in the United States, Canada and Japan. </p> <h3>UV curing</h3> <p>Mercury-vapor lamps are used in the printing industry to cure inks. These are typically high powered to rapidly cure and set the inks used. They are enclosed and have protections to prevent human exposure as well as specialised exhaust systems to remove the ozone generated. </p> <h3>Molecular spectroscopy</h3> <p>High-pressure mercury-vapor (and some specially-designed metal-halide) lamps find application in molecular spectroscopy due to providing useful broadband continuum ("noise") energy at millimeter and terahertz wavelengths, owing to the high electron temperature of the arc plasma; the main UV emission line of ionized mercury (254 nm) correlates to a blackbody of T= 11,500 K. This property makes them among the very few simple, inexpensive sources available for generating such frequencies. For example, a standard 250-watt general-lighting mercury lamp produces significant output from 120 GHz to 6 THz. In addition, shorter wavelengths in the mid-infrared are emitted from the hot quartz arc-tube envelope. As with the ultraviolet output, the glass outer bulb is largely opaque at these frequencies and thus for this purpose needs to be removed (or omitted in purpose-made lamps).<a class="footnote-ref" id="fnref:32" href="#fn:32"><sup>32</sup></a> </p> <h3>Projection</h3> <p>Special ultra high-pressure mercury-vapor lamps called <a href="/facts/Ultra-high-performance_lamp/hS0k6uQ9">Ultra-high-performance lamps</a> or UHP lamps, are commonly used in digital <a href="/facts/Video_projector/5fIVG2sq">video projectors</a>, including <a href="/facts/Digital_Light_Processing/jxMs8emm">DLP</a>, <a href="/facts/3LCD/0ICWmyb0">3LCD</a> and <a href="/facts/Liquid_crystal_on_silicon/r65bD7X4">LCoS</a> projectors. </p> <h2 id="see-also">See also</h2> <ul><li><a href="/facts/History_of_street_lighting_in_the_United_States/YS1U1o8A">History of street lighting in the United States</a></li> <li><a href="/facts/List_of_light_sources/FRTheSWG">List of light sources</a></li> <li><a href="/facts/Ultra-high-performance_lamp/hS0k6uQ9">Ultra-high-performance lamp</a></li></ul> <h2 id="further-reading">Further reading</h2> <ul><li>Waymouth, John (1971). <a href="https://archive.org/details/electricdischarg00waym"><i>Electric Discharge Lamps</i></a>. Cambridge, MA: The M.I.T. Press. <a href="/facts/ISBN_(identifier)/15AdSPa9">ISBN</a> 978-0-262-23048-3.</li> <li><a href="http://www.lamptech.co.uk/">Museum of Electric Lamp Technology</a></li></ul> <h2 id="external-links">External links</h2> <ul><li> Media related to Mercury-vapor lamp at Wikimedia Commons</li></ul> <h2 id="references">References</h2> <ol> <li id="fn:1"><p>"What color is mercury discharge tube? – handlebar-online.com". <a href="http://www.handlebar-online.com/articles/what-color-is-mercury-discharge-tube/" target="_blank">http://www.handlebar-online.com/articles/what-color-is-mercury-discharge-tube/</a> <a href="#fnref:1" class="footnote-back-ref">↩</a></p></li> <li id="fn:2"><p>"What color is mercury discharge tube? – handlebar-online.com". <a href="http://www.handlebar-online.com/articles/what-color-is-mercury-discharge-tube/" target="_blank">http://www.handlebar-online.com/articles/what-color-is-mercury-discharge-tube/</a> <a href="#fnref:2" class="footnote-back-ref">↩</a></p></li> <li id="fn:3"><p>"What color is mercury discharge tube? – handlebar-online.com". <a href="http://www.handlebar-online.com/articles/what-color-is-mercury-discharge-tube/" target="_blank">http://www.handlebar-online.com/articles/what-color-is-mercury-discharge-tube/</a> <a href="#fnref:3" class="footnote-back-ref">↩</a></p></li> <li id="fn:4"><p>"What color is mercury discharge tube? – handlebar-online.com". <a href="http://www.handlebar-online.com/articles/what-color-is-mercury-discharge-tube/" target="_blank">http://www.handlebar-online.com/articles/what-color-is-mercury-discharge-tube/</a> <a href="#fnref:4" class="footnote-back-ref">↩</a></p></li> <li id="fn:5"><p>Schiler, Marc (1997). Simplified Design of Building Lighting, 4th Ed. USA: John Wiley and Sons. p. 27. ISBN 978-0-471-19210-7. <a href="978-0-471-19210-7" target="_blank">978-0-471-19210-7</a> <a href="#fnref:5" class="footnote-back-ref">↩</a></p></li> <li id="fn:6"><p>"What color is mercury discharge tube? – handlebar-online.com". <a href="http://www.handlebar-online.com/articles/what-color-is-mercury-discharge-tube/" target="_blank">http://www.handlebar-online.com/articles/what-color-is-mercury-discharge-tube/</a> <a href="#fnref:6" class="footnote-back-ref">↩</a></p></li> <li id="fn:7"><p>Schiler, Marc (1997). Simplified Design of Building Lighting, 4th Ed. USA: John Wiley and Sons. p. 27. ISBN 978-0-471-19210-7. <a href="978-0-471-19210-7" target="_blank">978-0-471-19210-7</a> <a href="#fnref:7" class="footnote-back-ref">↩</a></p></li> <li id="fn:8"><p>Schiler, Marc (1997). Simplified Design of Building Lighting, 4th Ed. USA: John Wiley and Sons. p. 27. ISBN 978-0-471-19210-7. <a href="978-0-471-19210-7" target="_blank">978-0-471-19210-7</a> <a href="#fnref:8" class="footnote-back-ref">↩</a></p></li> <li id="fn:9"><p>Schiler, Marc (1997). Simplified Design of Building Lighting, 4th Ed. USA: John Wiley and Sons. p. 27. ISBN 978-0-471-19210-7. <a href="978-0-471-19210-7" target="_blank">978-0-471-19210-7</a> <a href="#fnref:9" class="footnote-back-ref">↩</a></p></li> <li id="fn:10"><p>Gendre, Maxime F. (2011). "Two Centuries of Electric Light Source Innovations" (PDF). Eindhoven Institute for Lighting Technology, Eindhoven Univ. of Technology, Eindhoven, Netherlands. Retrieved April 3, 2012. {{cite journal}}: Cite journal requires |journal= (help) <a href="http://www.einlightred.tue.nl/lightsources/history/light_history.pdf" target="_blank">http://www.einlightred.tue.nl/lightsources/history/light_history.pdf</a> <a href="#fnref:10" class="footnote-back-ref">↩</a></p></li> <li id="fn:11"><p>Gendre, Maxime F. Two Centuries of Electric Light Sources Innovations. p. 4. (PDF) . Retrieved on 2012-01-02. <a href="http://www.einlightred.tue.nl/lightsources/history/light_history.pdf" target="_blank">http://www.einlightred.tue.nl/lightsources/history/light_history.pdf</a> <a href="#fnref:11" class="footnote-back-ref">↩</a></p></li> <li id="fn:12"><p>Child, Clement D. (2002) Electric Arcs-Experiment Upon Arcs Between Different Electrodes in Various Environments, Watchmaker Publishing. ISBN 0-9726596-1-7, p. 88 <a href="/wiki/ISBN_(identifier)" target="_blank">/wiki/ISBN_(identifier)</a> <a href="#fnref:12" class="footnote-back-ref">↩</a></p></li> <li id="fn:13"><p>Perkin, Frederick Mollwo (January 1, 1911). "Mercury vapour lamps and action of ultra violet rays". 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