I think it not too venturesome to predict that a day will come when the metallic nature of the base of alum will be incontestably proven.
— French chemist Théodore Baron d'Hénouville in 1760 at the This amalgam quickly separates in air, and by distillation, in an inert atmosphere, gives a lump of metal which in color and luster somewhat resembles tin.
— Danish physicist In 1760, Baron de Hénouville unsuccessfully attempted to reduce alumina to its metal. He claimed he had tried every method of reduction known at the time, though his methods were unpublished. It is probable he mixed alum with carbon or some organic substance, with salt or soda for flux, and heated it in a charcoal fire. Austrian chemists Anton Leopold Ruprecht and Matteo Tondi repeated Baron's experiments in 1790, significantly increasing the temperatures. They found small metallic particles they believed were the sought-after metal; but later experiments by other chemists showed these were iron phosphide from impurities in the charcoal and bone ash. German chemist Martin Heinrich Klaproth commented in an aftermath, "if there exists an earth which has been put in conditions where its metallic nature should be disclosed, if it had such, an earth exposed to experiments suitable for reducing it, tested in the hottest fires by all sorts of methods, on a large as well as on a small scale, that earth is certainly alumina, yet no one has yet perceived its metallization." Lavoisier in 1794 and French chemist Louis-Bernard Guyton de Morveau in 1795 melted alumina to a white enamel in a charcoal fire fed by pure oxygen but found no metal. American chemist Robert Hare melted alumina with an oxyhydrogen blowpipe in 1802, also obtaining the enamel, but still found no metal.
Berzelius tried isolating the metal in 1825 by carefully washing the potassium analog of the base salt in cryolite in a crucible. Prior to the experiment, he had correctly identified the formula of this salt as K3AlF6. He found no metal, but his experiment came very close to succeeding and was successfully reproduced many times later. Berzelius's mistake was in using an excess of potassium, which made the solution too alkaline and dissolved all the newly formed aluminium.
My first thought was I had laid my hands on this intermediate metal which would find its place in man's uses and needs when we would find the way of taking it out of the chemists' laboratory and putting it in the industry.
— Preface of Since Wöhler's method could not yield large amounts of aluminium, the metal remained uncommon; its cost had exceeded that of gold before a new method was devised. In 1852, aluminium was sold at US$34 per ounce. In comparison, the price of gold at the time was $19 per ounce.
Twelve small ingots of aluminium were later exhibited for the first time to the public at the Exposition Universelle of 1855. The metal was presented as "the silver from clay" (aluminium is very similar to silver visually), and this name was soon widely used. It attracted widespread attention; it was suggested aluminium be used in arts, music, medicine, cooking, and tableware. The metal was noticed by the avant-garde writers of the time—Charles Dickens, Nikolay Chernyshevsky, and Jules Verne—who envisioned its use in the future. However, not all attention was favorable. Newspapers wrote, "The Parisian expo put an end to the fairy tale of the silver from clay", saying that much of what had been said about the metal was exaggerated if not untrue and that the amount of the presented metal—about a kilogram—contrasted with what had been expected and was "not a lot for a discovery that was said to turn the world upside down". Overall, the fair led to the eventual commercialization of the metal. That year, aluminium was put to the market at a price of 300 F per kilogram. At the next fair in Paris in 1867, visitors were presented with aluminium wire and foil as well a new alloy—aluminium bronze, notable for its low cost of production, high resistance to corrosion, and desirable mechanical properties.
Manufacturers did not wish to divert resources from producing well-known (and marketable) metals, such as iron and bronze, to experiment with a new one; moreover, produced aluminium was still not of great purity and differed in properties by sample. This led to an initial general reluctance to produce the new metal. Deville and partners established the world's first industrial production of aluminium at a smelter in Rouen in 1856. Deville's smelter moved that year to La Glacière and then Nanterre, and in 1857 to Salindres. For the factory in Nanterre, an output of 2 kilograms of aluminium per day was recorded, with a purity of 98%. Originally, production started with synthesis of pure alumina, which was obtained from calcination of ammonium alum. In 1858, Deville was introduced to bauxite and, in collaboration with Louis Le Châtelier, soon developed what became known as the Deville–Pechiney process, employing the mineral as a source for alumina production.: 122 In 1860, Deville sold his aluminium interests to Henri Merle, a founder of Compagnie d'Alais et de la Camargue; this company dominated the aluminium market in France decades later.
Some chemists, including Deville, sought to use cryolite as the source ore, but with little success. British engineer William Gerhard set up a plant with cryolite as the primary raw material in Battersea, London, in 1856, but technical and financial difficulties forced the closure of the plant in three years. British ironmaster Isaac Lowthian Bell produced aluminium from 1860 to 1874. During the opening of his factory, he waved to the crowd with a unique and costly aluminium top hat. No statistics about this production can be recovered, but it "cannot be very high". Deville's output grew to 1 metric ton per year in 1860; 1.7 metric tons in 1867; and 1.8 metric tons in 1872. At the time, demand for aluminium was low: for example, sales of Deville's aluminium by his British agents equaled 15 kilograms in 1872. Aluminium at the time was often compared with silver; like silver, it was found to be suitable for making jewelry and objéts d'art. Price for aluminium steadily declined to 240 F in 1859; 200 F in 1862; 120 F in 1867.
Other production sites began to appear in the 1880s. British engineer James Fern Webster launched the industrial production of aluminium by reduction with sodium in 1882; his aluminium was much purer than Deville's (it contained 0.8% impurities whereas Deville's typically contained 2%). World production of aluminium in 1884 equaled 3.6 metric tons. In 1884, American architect William Frishmuth combined production of sodium, alumina, and aluminium into a single technological process; this contrasted with the previous need to collect sodium, which combusts in water and sometimes air; his aluminium production cost was about $16 per pound (compare to silver's cost of $19 per pound, or the French price, an equivalent of $12 per pound). In 1885, Aluminium- und Magnesiumfabrik started production in Hemelingen. Its production figures strongly exceeded those of the factory in Salindres but the factory stopped production in 1888. In 1886, American engineer Hamilton Castner devised a method of cheaper production of sodium, which decreased the cost of aluminium production to $8 per pound, but he did not have enough capital to construct a large factory like Deville's. In 1887, he constructed a factory in Oldbury; Webster constructed a plant nearby and bought Castner's sodium to use it in his own production of aluminium. In 1889, German metallurgist Curt Netto launched a method of reduction of cryolite with sodium that produced aluminium containing 0.5–1.0% of impurities.
I'm going for that metal.
— Purportedly, American student Aluminium was first produced independently using electrolysis in 1854 by the German chemist Robert Wilhelm Bunsen and Deville. Their methods did not become the basis for industrial production of aluminium because electrical supplies were inefficient at the time. This changed only with Belgian engineer Zénobe-Théophile Gramme's invention of the dynamo in 1870, which made creation of large amounts of electricity possible. The invention of the three-phase current by Russian engineer Mikhail Dolivo-Dobrovolsky in 1889 made transmission of this electricity over long distances achievable. Soon after his discovery, Bunsen moved on to other areas of interest while Deville's work was noticed by Napoleon III; this was the reason Deville's Napoleon-funded research on aluminium production had been started. Deville quickly realized electrolytic production was impractical at the time and moved on to chemical methods, presenting results later that year.
Electrolytic mass production remained difficult because electrolytic baths could not withstand prolonged contact with molten salts, succumbing to corrosion. The first attempt to overcome this for aluminium production was made by American engineer Charles Bradley in 1883. Bradley heated aluminium salts internally: the highest temperature was inside the bath and the lowest was on its walls, where salts would solidify and protect the bath. Bradley then sold his patent claim to brothers Alfred and Eugene Cowles, who used it at a smelter in Lockport and later in Stoke-upon-Trent but the method was modified to yield alloys rather than pure aluminium. Bradley applied for a patent in 1883; due to his broad wordings, it was rejected as composed of prior art. After a necessary two-year break, he re-applied. This process lasted for six years, as the patent office questioned whether Bradley's ideas were original. When Bradley was granted a patent, electrolytic aluminium production had already been in place for several years.
The first large-scale production method was independently developed by French engineer Paul Héroult and American engineer Charles Martin Hall in 1886; it is now known as the Hall–Héroult process. Electrolysis of pure alumina is impractical, given its very high melting point; both Héroult and Hall realized it could be greatly lowered by the presence of molten cryolite. Héroult was granted a patent in France in April and subsequently in several other European countries; he also applied for a U.S. patent in May. After securing a patent, Héroult could not find interest in his invention. When asking professionals for advice, he was told there was no demand for aluminium but some for aluminium bronze. The factory in Salindres did not wish to improve its process. In 1888, Héroult and his companions founded Aluminium Industrie Aktiengesellschaft and started industrial production of aluminium bronze in Neuhausen am Rheinfall. Then, Société électrométallurgique française was founded in Paris. They convinced Héroult to return to France, purchased his patents, and appointed him as the director of a smelter in Isère, which produced aluminium bronze on a large scale at first and pure aluminium in a few months.
The total amount of unalloyed aluminium produced using Deville's chemical method from 1856 to 1889 equaled 200 metric tons. Production in 1890 alone was 175 metric tons. It grew to 715 metric tons in 1893 and to 4,034 metric tons in 1898. The price fell to $2 per pound in 1889 and to $0.5 per pound in 1894.
By the end of 1889, a consistently high purity of aluminium produced via electrolysis had been achieved. In 1890, Webster's factory went obsolete after an electrolysis factory was opened in England. Netto's main advantage, the high purity of the resulting aluminium, was outmatched by electrolytic aluminium and his company closed the following year. Compagnie d'Alais et de la Camargue also decided to switch to electrolytic production, and their first plant using this method was opened in 1895.
Modern production of the aluminium is based on the Bayer and Hall–Héroult processes. It was further improved in 1920 by a team led by Swedish chemist Carl Wilhelm Söderberg. Previously, anode electrodes had been made from pre-baked coal blocks, which quickly corrupted and required replacement; the team introduced continuous electrodes made from a coke and tar paste in a reduction chamber. This advance greatly increased the world output of aluminium.
Give us aluminum in the right quantity, and we will be able to fight for another four years.
— Soviet leader Prices for aluminium declined, and by the early 1890s, the metal had become widely used in jewelry, eyeglass frames, optical instruments, and many everyday items. Aluminium cookware began to be produced in the late 19th century and gradually supplanted copper and cast iron cookware in the first decades of the 20th century. Aluminium foil was popularized at that time. Aluminium is soft and light, but it was soon discovered that alloying it with other metals could increase its hardness while preserving its low density. Aluminium alloys found many uses in the late 19th and early 20th centuries. For instance, aluminium bronze is applied to make flexible bands, sheets, and wire, and is widely employed in the shipbuilding and aviation industries. Aviation used a new aluminium alloy, duralumin, invented in 1903. Aluminium recycling began in the early 1900s and has been used extensively since as aluminium is not impaired by recycling and thus can be recycled repeatedly. At this point, only the metal that had not been used by end-consumers was recycled. During World War I, major governments demanded large shipments of aluminium for light strong airframes. They often subsidized factories and the necessary electrical supply systems. Overall production of aluminium peaked during the war: world production of aluminium in 1900 was 6,800 metric tons; in 1916, annual production exceeded 100,000 metric tons. The war created a greater demand for aluminium, which the growing primary production was unable to fully satisfy, and recycling grew intensely as well. The peak in production was followed by a decline, then a swift growth.
Aluminium obtained from recycling was considered inferior to primary aluminium because of poorer chemistry control as well as poor removal of dross and slags. Recycling grew overall but depended largely on the output of primary production: for instance, as electric energy prices declined in the United States in the late 1930s, more primary aluminium could be produced using the energy-expensive Hall–Héroult process. This rendered recycling less necessary, and thus aluminium recycling rates went down. By 1940, mass recycling of post-consumer aluminium had begun.
After the wartime peak, world production fell for three late-war and post-war years but then regained its rapid growth. In 1954, the world output equaled 2,810,000 metric tons; this production surpassed that of copper, historically second in production only to iron, making it the most produced non-ferrous metal.
Nothing stops time. One epoch follows another, and sometimes we don't even notice it. The Stone Age... The Bronze Age... The Iron Age... [...] However one may assert that it is now that we stand on the threshold of the Aluminium Age.
— Russian aluminium producing company In the late 1960s, governments became aware of waste from the industrial production; they enforced a series of regulations favoring recycling and waste disposal. Söderberg anodes, which save capital and labor to bake the anodes but are more harmful to the environment (because of a greater difficulty in collecting and disposing of the baking fumes), fell into disfavor, and production began to shift back to the pre-baked anodes. The aluminium industry began promoting the recycling of aluminium cans in an attempt to avoid restrictions on them. This sparked recycling of aluminium previously used by end-consumers: for example, in the United States, levels of recycling of such aluminium increased 3.5 times from 1970 to 1980 and 7.5 times to 1990. Production costs for primary aluminium grew in the 1970s and 1980s, and this also contributed to the rise of aluminium recycling. Closer composition control and improved refining technology diminished the quality difference between primary and secondary aluminium.
In the 1970s, the increased demand for aluminium made it an exchange commodity; it entered the London Metal Exchange, the world's oldest industrial metal exchange, in 1978. Since then, aluminium has been traded for United States dollars and its price fluctuated along with the currency's exchange rate. The need to exploit lower-grade poorer quality deposits and fast increasing input costs of energy, but also bauxite, as well as changes in exchange rates and greenhouse gas regulation, increased the net cost of aluminium; the real price grew in the 1970s.
The increase of the real price, and changes of tariffs and taxes, began the redistribution of world producers' shares: the United States, the Soviet Union, and Japan accounted for nearly 60% of world's primary production in 1972 (and their combined share of consumption of primary aluminium was also close to 60%); but their combined share only slightly exceeded 10% in 2012. The production shift began in the 1970s with production moving from the United States, Japan, and Western Europe to Australia, Canada, the Middle East, Russia, and China, where it was cheaper due to lower electricity prices and favorable state regulation, such as low taxes or subsidies. Production costs in the 1980s and 1990s declined because of advances in technology, lower energy and alumina prices, and high exchange rates of the United States dollar.
In the mid-2000s, increasing energy, alumina and carbon (used in anodes) prices caused an increase in production costs. This was amplified by a shift in currency exchange rates: not only a weakening of the United States dollar, but also a strengthening of the Chinese yuan. The latter became important as most Chinese aluminium was relatively cheap.
World output continued growing: in 2018, it was a record 63,600,000 metric tons before falling slightly in 2019. Aluminium is produced in greater quantities than all other non-ferrous metals combined. Its real price (in 1998 United States dollars) in 2019 was $1,400 per metric ton ($2,190 per ton in contemporary dollars).
Setton, Kenneth Meyer (1976). "Pius II, the Crusade, and the Venetian war against the Turks". The Papacy and the Levant, 1204–1571: The fifteenth century. American Philosophical Society. pp. 231–270. ISBN 978-0-87169-127-9. 978-0-87169-127-9
Drozdov 2007, p. 12. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Drozdov 2007, pp. 12–14. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Duboin, A. (1902). "Les Romains ont-ils connu l'aluminium ?" [Did the Romans know about aluminum?]. La Revue Scientifique (in French). 18 (24): 751–753. Archived from the original on 2018-11-16. Retrieved 2018-11-16. https://gallica.bnf.fr/ark:/12148/bpt6k2151370/f754.image
Pliny's Natural History. Translated by Rackham, H.; Jones, W. H. S.; Eichholz, D. E. Harvard University Press; William Heinemann. 1949–1954. Archived from the original on January 1, 2017. https://web.archive.org/web/20170101063545/http://www.masseiana.org/pliny.htm
Duboin, A. (1902). "Les Romains ont-ils connu l'aluminium ?" [Did the Romans know about aluminum?]. La Revue Scientifique (in French). 18 (24): 751–753. Archived from the original on 2018-11-16. Retrieved 2018-11-16. https://gallica.bnf.fr/ark:/12148/bpt6k2151370/f754.image
Deville had established that heating a mixture of sodium chloride, clay, and charcoal yields numerous aluminium globules. This was published in the Proceedings of the Academy of Sciences but eventually forgotten.[4] French chemist André Duboin discovered that heating a mixture of borax, alumina, and smaller quantities of dichromate and silica in a crucible formed impure aluminium. Boric acid is abundant in Italy. According to Duboin, this hints at the possibility that boric acid, potash, and clay under the reducing influence of coal may have produced aluminium in Rome.[4] /wiki/Sodium_chloride
A similar story is attributed to Pliny, which mentions instead a light bright metal extracted from clay—a description that matches that of aluminium. Both Petronius and Pliny, however, mentioned glass[6] (and Dio did not mention the material at all).[7] A possible source of the error is French general Louis Gaspard Gustave Adolphe Yvelin de Béville, who was openly cited by Deville in 1864. De Béville searched in the Roman sources for possible ancient mentions of the new metal and discovered among others the story in Satiricon. De Béville might have misinterpreted Petronius's expression aurum pro luto habere (literally "to have gold as dirt"), assuming that lutum stands for "clay" (a possible translation), whereas the word throughout the book actually means something valueless in general. German chemist Gerhard Eggert concluded that this story was erroneous.[6] After evaluating other possible explanations, he announced the original story was also probably made up; however, he did not evaluate Duboin's suggestion.[6]
Alumina was plentiful and could be reduced by coke in the presence of copper, giving aluminium–copper alloys. Existing works by Chinese alchemists show that alloys with a small aluminium content could be produced in China. The Chinese did not have the technology to produce pure aluminium and the temperatures needed (around 2000 °C) were unachievable. A number of high-aluminium artifacts were found in China supposedly relating to the times of the first Jin dynasty, but it was later shown the technology needed to make them was not available at the time and thus the artifacts were not authentic.[8]
Drozdov 2007, p. 16. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Clapham, John Harold; Power, Eileen Edna (1941). The Cambridge Economic History of Europe: From the Decline of the Roman Empire. CUP Archive. p. 207. ISBN 978-0-521-08710-0. 978-0-521-08710-0
Balston, John Noel (1998). "Appendix I – In Defence of Alum". The Whatmans and Wove Paper: Its Invention and Development in the West: Research Into the Origins of Wove Paper and of Genuine Loom-Woven Wirecloth. Vol. 3. John Balston. p. 198. ISBN 978-0-9519505-3-1. 978-0-9519505-3-1
Setton, Kenneth Meyer (1976). "Pius II, the Crusade, and the Venetian war against the Turks". The Papacy and the Levant, 1204–1571: The fifteenth century. American Philosophical Society. pp. 231–270. ISBN 978-0-87169-127-9. 978-0-87169-127-9
Drozdov 2007, pp. 17–18. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Richards 1896, p. 3. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Drozdov 2007, p. 25. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Weeks, Mary Elvira (1968). Discovery of the elements. Vol. 1 (7 ed.). Journal of Chemical Education. p. 187. ISBN 9780608300177. 9780608300177
Drozdov 2007, p. 25. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Richards 1896, p. 2. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Richards 1896, p. 2. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Richards 1896, p. 2. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Drozdov 2007, p. 26. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Wiegleb, Johann Christian (1790). Geschichte des wachsthums und der erfindungen in der chemie, in der neuern zeit [History of growth and inventions in chemistry in the modern time]. Nicolai, Christoph Friedrich. p. 357. /wiki/Johann_Christian_Wiegleb
Drozdov 2007, p. 27. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Pott, Johann Heinrich (1746). Chymische Untersuchungen, welche fürnehmlich von der Lithogeognosia oder Erkäntniß und Bearbeitung der gemeinen einfacheren Steine und Erden ingleichen von Feuer und Licht handeln [Chemical investigations which primarily concern lithogeognosia or knowledge and processing of common simple rocks and earths as well as fire and light]] (in German). Vol. 1. Voss, Christian Friedrich. p. 32. Archived from the original on 2016-12-22. Retrieved 2017-11-10. https://books.google.com/books?id=uxZAAAAAcAAJ&pg=PA32
Richards 1896, p. 2. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Chisholm, Hugh, ed. (1911). "Alum" . Encyclopædia Britannica. Vol. 01 (11th ed.). Cambridge University Press. pp. 766–767. /wiki/Hugh_Chisholm
Drozdov 2007, p. 27. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
The terms "earth of alum" and "alumina" refer to the same substance. German-speaking authors mentioned in this section used "earth of alum" (Alaun-Erde), while French authors used "alumina" (alumine).
Richards 1896, p. 3. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Richards 1896, p. 3. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Drozdov 2007, p. 25. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Lennartson, Anders (2017). The Chemical Works of Carl Wilhelm Scheele. Springer International Publishing. p. 32. ISBN 978-3-319-58181-1. 978-3-319-58181-1
Richards 1896, pp. 3–4. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Wurtz, Adolphe (1865). "An introduction to chemical philosophies, according to modern theories". Chemical News. 15: 99. https://books.google.com/books?id=p95uGKIJK4QC&pg=PA99
Drozdov 2007, p. 31. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Drozdov 2007, p. 31. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Royal Danish Academy of Sciences and Letters (1827). Det Kongelige Danske Videnskabernes Selskabs philosophiske og historiske afhandlinger [The philosophical and historical dissertations of the Royal Danish Academy of Sciences and Letters] (in Danish). Popp. pp. xxv–xxvi. Archived from the original on 2017-03-24. Retrieved 2017-11-10. /wiki/Royal_Danish_Academy_of_Sciences_and_Letters
Richards 1896, p. 3. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Richards 1896, p. 4. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Guyton, Louis-Bernard (1795). "Expériences comparatives sur les terres, pour déterminer leur fusibilité, leur manière de se comporter avec les flux salins ou vitreux, et l'action dissolvante qu'elles exercent réciproquement les unes sur les autres" [Comparative experiments on the earth, to determine their fusibility, their behavior with the saline or vitreous flows, and the dissolving action they exert on each other]. Journal de l'École Polytechnique (in French). 3: 299. Archived from the original on 2017-11-11. Retrieved 2017-11-11. /wiki/Louis-Bernard_Guyton_de_Morveau
Guyton, Louis-Bernard (1795). "Expériences comparatives sur les terres, pour déterminer leur fusibilité, leur manière de se comporter avec les flux salins ou vitreux, et l'action dissolvante qu'elles exercent réciproquement les unes sur les autres" [Comparative experiments on the earth, to determine their fusibility, their behavior with the saline or vitreous flows, and the dissolving action they exert on each other]. Journal de l'École Polytechnique (in French). 3: 299. Archived from the original on 2017-11-11. Retrieved 2017-11-11. /wiki/Louis-Bernard_Guyton_de_Morveau
Richards 1896, p. 4. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Richards 1896, p. 4. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
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Richards 1896, p. 4. - Richards, Joseph William (1896). Aluminium: Its history, occurrence, properties, metallurgy and applications, including its alloys (3 ed.). Henry Carey Baird & Co. https://archive.org/stream/cu31924003633751/cu31924003633751_djvu.txt
Davy, Humphry (1808). "Electro Chemical Researches, on the Decomposition of the Earths; with Observations on the Metals obtained from the alkaline Earths, and on the Amalgam procured from Ammonia". Philosophical Transactions of the Royal Society. 98: 353. Bibcode:1808RSPT...98..333D. doi:10.1098/rstl.1808.0023. S2CID 96364168. https://books.google.com/books?id=Kg9GAAAAMAAJ&pg=RA1-PA353
Davy, Humphry (1812). "Of metals; their primary compositions with other uncompounded bodies, and with each other". Elements of Chemical Philosophy: Part 1. Vol. 1. Bradford and Inskeep. p. 201. /wiki/Humphry_Davy
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Örsted, H. C., ed. (1825). "Physisk Classe". Oversigt over det Kongelige Danske Videnskabernes Selskabs Forhandlinger og dets Medlemmers Arbeider fra 31 Mai 1824 til 31 Mai 1825 (in Danish). København. pp. 15–16. hdl:2027/osu.32435054254693. ISSN 0369-7169. OCLC 32565767. https://babel.hathitrust.org/cgi/pt?id=osu.32435054254693&view=1up&seq=17
Wöhler, Friedrich (1827). "Ueber das Aluminium" [About aluminium]. Annalen der Physik und Chemie. 2 (in German). 11 (9): 146–161. Bibcode:1828AnP....87..146W. doi:10.1002/andp.18270870912. S2CID 122170259. /wiki/Friedrich_W%C3%B6hler
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Larned, Josephus Nelson (1923). The New Larned History for Ready Reference, Reading and Research: The Actual Words of the World's Best Historians, Biographers and Specialists; a Complete System of History for All Uses, Extending to All Countries and Subjects and Representing the Better and Newer Literature of History. C.A. Nichols Publishing Company. p. 4472. https://archive.org/details/newlarnedhistor10larn
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Christensen, Dan Ch. (2013). "Aluminium: Priority and Nationalism". Hans Christian Ørsted: Reading Nature's Mind. OUP Oxford. pp. 424–430. ISBN 978-0-19-164711-6. 978-0-19-164711-6
Bjerrum, Niels (1926). "Die Entdeckung des Aluminiums" [Discovery of aluminium]. Zeitschrift für Angewandte Chemie (in German). 39 (9): 316–317. Bibcode:1926AngCh..39..316B. doi:10.1002/ange.19260390907. ISSN 0044-8249. /wiki/Bibcode_(identifier)
Wöhler, Friedrich (1827). "Ueber das Aluminium" [About aluminium]. Annalen der Physik und Chemie. 2 (in German). 11 (9): 146–161. Bibcode:1828AnP....87..146W. doi:10.1002/andp.18270870912. S2CID 122170259. /wiki/Friedrich_W%C3%B6hler
Christensen, Dan Ch. (2013). "Aluminium: Priority and Nationalism". Hans Christian Ørsted: Reading Nature's Mind. OUP Oxford. pp. 424–430. ISBN 978-0-19-164711-6. 978-0-19-164711-6
Drozdov 2007, p. 38. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
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Holmes, Harry N. (1936). "Fifty Years of Industrial Aluminum". The Scientific Monthly. 42 (3): 236–239. Bibcode:1936SciMo..42..236H. JSTOR 15938. /wiki/Bibcode_(identifier)
Christensen, Dan Ch. (2013). "Aluminium: Priority and Nationalism". Hans Christian Ørsted: Reading Nature's Mind. OUP Oxford. pp. 424–430. ISBN 978-0-19-164711-6. 978-0-19-164711-6
Ørsted's description of the isolation of the new element, as recorded by the Royal Danish Academy of Sciences and Letters,[26] does not include a name for the metal, neither the name "aluminium" nor a suggestion of his own; in comparison, Wöhler put the word "aluminium" into the title of his article.[33]
Christensen, Dan Ch. (2013). "Aluminium: Priority and Nationalism". Hans Christian Ørsted: Reading Nature's Mind. OUP Oxford. pp. 424–430. ISBN 978-0-19-164711-6. 978-0-19-164711-6
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Note the difference between cost and price. Cost is the amount of money (and, sometimes, other resources, such as time) that was spent in making a product whereas price is the amount of money (or, sometimes, other goods or services) the product is sold for. Manufacturer's price equals cost plus manufacturer's profit. /wiki/Cost
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Nichols, Sarah C.; Agro, Elisabeth R.; Teller, Elizabeth; Antonelli (2000). Teller, Elizabeth; Antonelli, Paola (eds.). Aluminum by design. Carnegie Museum of Art. p. 66. ISBN 978-0-8109-6721-2. 978-0-8109-6721-2
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Essig, Charles James (1900). The American Text-book of Prosthetic Dentistry: In Contributions by Eminent Authorities. Lea Brothers. p. 148. https://archive.org/details/americantextbook1900essi
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Le Roux, Muriel (May 2015). "From Science to Industry: The Sites of Aluminium in France from the Nineteenth to the Twentieth Century". Ambix. 62 (2): 114–137. doi:10.1179/1745823415Y.0000000001. /wiki/Doi_(identifier)
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Howell, Georgina (2010). Gertrude Bell: Queen of the Desert, Shaper of Nations. Farrar, Straus and Giroux. pp. 4–5. ISBN 978-1-4299-3401-5. 978-1-4299-3401-5
"Aluminum". Report on Mineral Industries in the United States at the Eleventh Census, 1890. U.S. Government Printing Office. 1892. pp. 280–281. https://books.google.com/books?id=kHN3Tl2wAKsC&pg=PA280
"Aluminum". Report on Mineral Industries in the United States at the Eleventh Census, 1890. U.S. Government Printing Office. 1892. pp. 280–281. https://books.google.com/books?id=kHN3Tl2wAKsC&pg=PA280
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Büttner, Alex; Feez, Fred (1938). Metall aus Lehm. (Der hundertjährige Kampf um d. Wunderstoff Aluminium.) [Metal from clay. (The one-hundred-years-long struggle for the miraculous substance aluminium.)] (in German). Goldmann. p. 40. https://books.google.com/books?id=T8NNAAAAYAAJ
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Geller, Tom (2007). "Aluminum: Common Metal, Uncommon Past". Distillations. Science History Institute. Archived from the original on 2019-04-26. Retrieved 2018-12-04. https://www.sciencehistory.org/distillations/magazine/aluminum-common-metal-uncommon-past
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Friedrich, Horst E.; Mordike, Barry Leslie (2006). Magnesium Technology: Metallurgy, Design Data, Automotive Applications. Springer Science & Business Media. p. 3. ISBN 978-3-540-20599-9. 978-3-540-20599-9
Belli, Peter Josef (2012). Das Lautawerk der Vereinigte Aluminium-Werke AG (VAW) von 1917 bis 1948: ein Rüstungsbetrieb in regionalen, nationalen, internationalen und politischen Kontexten : (zugleich ein Beitrag zur Industriegeschichte der Niederlausitz) [The Lauta factory of Vereinigte Aluminium-Werke AG (VAW) from 1917 to 1948: an armament factory in regional, national, and political contexts: (at the same time, an entry to the history of the industry of Lower Lusatia)] (in German). LIT Verlag Münster. pp. 30–31. ISBN 978-3-643-11716-8. 978-3-643-11716-8
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Netto, C. (1889). "Die Herstellung von Aluminium". Zeitschrift für Angewandte Chemie (in German). 2 (16): 448–451. Bibcode:1889AngCh...2..448N. doi:10.1002/ange.18890021603. ISSN 0044-8249. https://zenodo.org/record/1424393
Geller, Tom (2007). "Aluminum: Common Metal, Uncommon Past". Distillations. Science History Institute. Archived from the original on 2019-04-26. Retrieved 2018-12-04. https://www.sciencehistory.org/distillations/magazine/aluminum-common-metal-uncommon-past
Drozdov 2007, pp. 52–53. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Geller, Tom (2007). "Aluminum: Common Metal, Uncommon Past". Distillations. Science History Institute. Archived from the original on 2019-04-26. Retrieved 2018-12-04. https://www.sciencehistory.org/distillations/magazine/aluminum-common-metal-uncommon-past
Crosland, Maurice (2002). Science Under Control: The French Academy of Sciences 1795-1914. Cambridge University Press. p. 252. ISBN 978-0-521-52475-9. 978-0-521-52475-9
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Meiers, Peter. "Manufacture of Aluminum". Retrieved 2019-06-15. http://www.fluoride-history.de/p-aluminum.htm
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Although very similar and now commonly seen as one, Hall and Héroult processes had some small initial differences. For instance, Héroult used coal anodes while Hall used copper.[80]
American Chemical Society Office of Public Outreach (1997). Production of aluminum metal by electrochemistry (PDF). American Chemical Society. http://www.pittsburghacs.org/wp-content/uploads/2012/11/National-Historic-Chemical-Landmark-Production-of-Al-Metal.pdf
Drozdov 2007, p. 56. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
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"Alusuisse" (in German). Historisches Lexikon der Schweiz. 2013. Archived from the original on 2017-10-27. Retrieved 2017-11-26. http://www.hls-dhs-dss.ch/textes/d/D41942.php
Sheller, Mimi (2014). Aluminum Dreams: The Making of Light Modernity. MIT Press. p. 41. ISBN 978-0-262-02682-6. 978-0-262-02682-6
The Cowles brothers did not wish to change their production method because they feared that mass production of aluminium would immediately reduce the metal's price. The president of the company considered purchasing Hall's patent (which was still not granted at the time) to ensure that competitors would not make use of it.[87]
Skrabec 2017, pp. 37–42. - Skrabec, Quentin R. (2017). Aluminum in America: A History. McFarland. ISBN 978-1-4766-2564-5. https://books.google.com/books?id=r8zTDQAAQBAJ
Drozdov 2007, p. 59. - Drozdov, Andrey (2007). Aluminium: The Thirteenth Element (PDF). RUSAL Library. ISBN 978-5-91523-002-5. Archived from the original (PDF) on 2016-04-16. Retrieved 2019-06-09. https://web.archive.org/web/20160416035813/http://www.rusal.ru/en/press-center/RUSAL%20Encyclopedia_full_engl_FINAL.pdf
Hall was able to prove his originality thanks to his keeping record on experiments. Hall documented the isolation of aluminium in February 1886, and his family members provided evidence for that. In contrast, the earliest date to which Héroult's invention could be traced back was the date of granting of the French patent in April.[81]
Because the principle of internal heating was missing from Hall's patent, the Cowles brothers believed Hall had stolen it from them and sued his company in 1891. This lawsuit was resolved only in 1903; the Pittsburgh Reduction Company had to pay a large indemnity.[89][90]
/wiki/Indemnity
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Habashi, Fathi (2016), "A Hundred Years of the Bayer Process for Alumina Production", in Donaldson, Don; Raahauge, Benny E. (eds.), Essential Readings in Light Metals, Springer International Publishing, pp. 85–93, doi:10.1007/978-3-319-48176-0_12, ISBN 9783319485744 9783319485744
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This campaign was not effective as a means to achieve the declared goal, collecting of aluminium for production of airplanes: the collected metal was not of high quality,[117] required manual working (such as removal of wooden handles of pans),[118] and aluminium was available as unused kitchenware in stores and as scrap;[117] already existing scrap in particular could be easily converted into the required grade purity of aluminium and could not be sold elsewhere.[119] However, the campaign boosted the morale of the British civilian public who engaged in the wartime effort.[117][120]
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