Uranium-214 is the lightest known isotope of uranium. It was discovered at the Spectrometer for Heavy Atoms and Nuclear Structure (SHANS) at the Heavy Ion Research Facility in Lanzhou, China in 2021, produced by firing argon-36 at tungsten-182. It alpha-decays with a half-life of 0.5 ms.
Uranium-233 is produced by neutron irradiation of thorium-232. When thorium-232 absorbs a neutron, it becomes thorium-233, which has a half-life of only 22 minutes. Thorium-233 beta decays into protactinium-233. Protactinium-233 has a half-life of 27 days and beta decays into uranium-233; some proposed molten salt reactor designs attempt to physically isolate the protactinium from further neutron capture before beta decay can occur.
Uranium-233 usually fissions on neutron absorption but sometimes retains the neutron, becoming uranium-234. The capture-to-fission ratio is smaller than the other two major fissile fuels, uranium-235 and plutonium-239; it is also lower than that of short-lived plutonium-241, but bested by very difficult-to-produce neptunium-236.
234U occurs in natural uranium as an indirect decay product of uranium-238, but makes up only 55 parts per million of the uranium because its half-life of 245,500 years is only about 1/18,000 that of 238U. The path of production of 234U is this: 238U alpha decays to thorium-234. Next, with a short half-life, 234Th beta decays to protactinium-234. Finally, 234Pa beta decays to 234U.
Uranium-236 has a half-life of about 23 million years; and is neither fissile with thermal neutrons, nor very good fertile material, but is generally considered a nuisance and long-lived radioactive waste. It is found in spent nuclear fuel and in the reprocessed uranium made from spent nuclear fuel.
About 99.284% of natural uranium is uranium-238, which has a half-life of 1.41×1017 seconds (4.468×109 years). Depleted uranium has an even higher concentration of 238U, and even low-enriched uranium (LEU) is still mostly 238U. Reprocessed uranium is also mainly 238U, with about as much uranium-235 as natural uranium, a comparable proportion of uranium-236, and much smaller amounts of other isotopes of uranium such as uranium-234, uranium-233, and uranium-232.
"Uranium Isotopes". GlobalSecurity.org. Retrieved 14 March 2012. http://www.globalsecurity.org/wmd/intro/u-isotopes.htm
mU – Excited nuclear isomer. /wiki/Nuclear_isomer
Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf. /wiki/Doi_(identifier)
( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
# – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
https://www-nds.iaea.org/amdc/ame2020/NUBASE2020.pdf
Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
https://www-nds.iaea.org/amdc/ame2020/NUBASE2020.pdf
Modes of decay:
EC:Electron captureCD:Cluster decaySF:Spontaneous fission /wiki/Electron_capture
Bold italics symbol as daughter – Daughter product is nearly stable.
Bold symbol as daughter – Daughter product is stable.
Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
https://www-nds.iaea.org/amdc/ame2020/NUBASE2020.pdf
( ) spin value – Indicates spin with weak assignment arguments.
# – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
# – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
https://www-nds.iaea.org/amdc/ame2020/NUBASE2020.pdf
Zhang, Z. Y.; Yang, H. B.; Huang, M. H.; Gan, Z. G.; Yuan, C. X.; Qi, C.; Andreyev, A. N.; Liu, M. L.; Ma, L.; Zhang, M. M.; Tian, Y. L.; Wang, Y. S.; Wang, J. G.; Yang, C. L.; Li, G. S.; Qiang, Y. H.; Yang, W. Q.; Chen, R. F.; Zhang, H. B.; Lu, Z. W.; Xu, X. X.; Duan, L. M.; Yang, H. R.; Huang, W. X.; Liu, Z.; Zhou, X. H.; Zhang, Y. H.; Xu, H. S.; Wang, N.; Zhou, H. B.; Wen, X. J.; Huang, S.; Hua, W.; Zhu, L.; Wang, X.; Mao, Y. C.; He, X. T.; Wang, S. Y.; Xu, W. Z.; Li, H. W.; Ren, Z. Z.; Zhou, S. G. (2021). "New α-Emitting Isotope U214 and Abnormal Enhancement of α-Particle Clustering in Lightest Uranium Isotopes". Physical Review Letters. 126 (15): 152502. arXiv:2101.06023. Bibcode:2021PhRvL.126o2502Z. doi:10.1103/PhysRevLett.126.152502. PMID 33929212. S2CID 231627674. /wiki/ArXiv_(identifier)
Zhang, M. M.; Tian, Y. L.; Wang, Y. S.; Zhang, Z. Y.; Gan, Z. G.; Yang, H. B.; Huang, M. H.; Ma, L.; Yang, C. L.; Wang, J. G.; Yuan, C. X.; Qi, C.; Andreyev, A. N.; Huang, X. Y.; Xu, S. Y.; Zhao, Z.; Chen, L. X.; Wang, J. Y.; Liu, M. L.; Qiang, Y. H.; Li, G. S.; Yang, W. Q.; Chen, R. F.; Zhang, H. B.; Lu, Z. W.; Xu, X. X.; Duan, L. M.; Yang, H. R.; Huang, W. X.; Liu, Z.; Zhou, X. H.; Zhang, Y. H.; Xu, H. S.; Wang, N.; Zhou, H. B.; Wen, X. J.; Huang, S.; Hua, W.; Zhu, L.; Wang, X.; Mao, Y. C.; He, X. T.; Wang, S. Y.; Xu, W. Z.; Li, H. W.; Niu, Y. F.; Guo, L.; Ren, Z. Z.; Zhou, S. G. (4 August 2022). "Fine structure in the α decay of the 8+ isomer in 216, 218U". Physical Review C. 106 (2): 024305. doi:10.1103/PhysRevC.106.024305. ISSN 2469-9985. S2CID 251359451. /wiki/Doi_(identifier)
Gan, ZaiGuo; Jiang, Jian; Yang, HuaBin; Zhang, ZhiYuan; Ma, Long; Yu, Lin; Wang, JianGuo; Tian, YuLin; Ding, Bing; Huang, TianHeng; Wang, YongSheng; Guo, Song; Sun, MingDao; Wang, KaiLong; Zhou, ShanGui; Ren, ZhongZhou; Zhou, XiaoHong; Xu, HuShan (1 August 2016). "α decay studies of the neutron-deficient uranium isotopes 215-217U". Chinese Science Bulletin. 61 (22): 2502–2511. doi:10.1360/N972015-01316. Retrieved 24 June 2023. https://www.researchgate.net/publication/312030836
Zhang, M. M.; Tian, Y. L.; Wang, Y. S.; Zhang, Z. Y.; Gan, Z. G.; Yang, H. B.; Huang, M. H.; Ma, L.; Yang, C. L.; Wang, J. G.; Yuan, C. X.; Qi, C.; Andreyev, A. N.; Huang, X. Y.; Xu, S. Y.; Zhao, Z.; Chen, L. X.; Wang, J. Y.; Liu, M. L.; Qiang, Y. H.; Li, G. S.; Yang, W. Q.; Chen, R. F.; Zhang, H. B.; Lu, Z. W.; Xu, X. X.; Duan, L. M.; Yang, H. R.; Huang, W. X.; Liu, Z.; Zhou, X. H.; Zhang, Y. H.; Xu, H. S.; Wang, N.; Zhou, H. B.; Wen, X. J.; Huang, S.; Hua, W.; Zhu, L.; Wang, X.; Mao, Y. C.; He, X. T.; Wang, S. Y.; Xu, W. Z.; Li, H. W.; Niu, Y. F.; Guo, L.; Ren, Z. Z.; Zhou, S. G. (4 August 2022). "Fine structure in the α decay of the 8+ isomer in 216, 218U". Physical Review C. 106 (2): 024305. doi:10.1103/PhysRevC.106.024305. ISSN 2469-9985. S2CID 251359451. /wiki/Doi_(identifier)
Intermediate decay product of 237Np /wiki/Neptunium-237
Used in uranium–thorium dating /wiki/Uranium%E2%80%93thorium_dating
Used in uranium–uranium dating /wiki/Uranium%E2%80%93uranium_dating
Intermediate decay product of 238U /wiki/Decay_product
Primordial radionuclide /wiki/Radionuclide
Used in Uranium–lead dating /wiki/Uranium%E2%80%93lead_dating
Important in nuclear reactors
Trenn, Thaddeus J. (1978). "Thoruranium (U-236) as the extinct natural parent of thorium: The premature falsification of an essentially correct theory". Annals of Science. 35 (6): 581–97. doi:10.1080/00033797800200441. /wiki/Doi_(identifier)
Intermediate decay product of 244Pu, also produced by neutron capture of 235U /wiki/Plutonium-244
Bonetti, R.; Guglielmetti, A. (2007). "Cluster radioactivity: an overview after twenty years" (PDF). Romanian Reports in Physics. 59: 301–310. Archived from the original (PDF) on 19 September 2016. https://web.archive.org/web/20160919014152/http://www.rrp.infim.ro/2007_59_2/10_bonetti.pdf
Bonetti, R.; Guglielmetti, A. (2007). "Cluster radioactivity: an overview after twenty years" (PDF). Romanian Reports in Physics. 59: 301–310. Archived from the original (PDF) on 19 September 2016. https://web.archive.org/web/20160919014152/http://www.rrp.infim.ro/2007_59_2/10_bonetti.pdf
Neutron capture product, parent of trace quantities of 237Np /wiki/Neptunium-237
Used in uranium–uranium dating /wiki/Uranium%E2%80%93uranium_dating
Primordial radionuclide /wiki/Radionuclide
Used in Uranium–lead dating /wiki/Uranium%E2%80%93lead_dating
Kromer, Kathrin; Lyu, Chunhai; Bieroń, Jacek; Door, Menno; Enzmann, Lucia; Filianin, Pavel; Gaigalas, Gediminas; Harman, Zoltán; Herkenhoff, Jost; Huang, Wenjia; Keitel, Christoph H.; Eliseev, Sergey; Blaum, Klaus (2024-02-06). "Atomic mass determination of uranium-238". Physical Review C. 109 (2). American Physical Society (APS). arXiv:2312.17041. doi:10.1103/physrevc.109.l021301. ISSN 2469-9985. /wiki/ArXiv_(identifier)
Neutron capture product; parent of trace quantities of 239Pu
Intermediate decay product of 244Pu
Niwase, T.; Watanabe, Y. X.; Hirayama, Y.; et al. (2023). "Discovery of New Isotope 241U and Systematic High-Precision Atomic Mass Measurements of Neutron-Rich Pa-Pu Nuclei Produced via Multinucleon Transfer Reactions" (PDF). Physical Review Letters. 130 (13): 132502-1 – 132502-6. doi:10.1103/PhysRevLett.130.132502. PMID 37067317. S2CID 257976576. https://eprints.whiterose.ac.uk/197980/1/PhysRevLett.130.132502.pdf
Mukunth, Vasudevan (2023-04-05). "In pursuit of a 'magic number', physicists discover new uranium isotope". The Hindu. ISSN 0971-751X. Retrieved 2023-04-12. https://www.thehindu.com/sci-tech/science/in-pursuit-of-a-magic-number-physicists-discover-new-uranium-isotope/article66699249.ece
Yirka, Bob (April 5, 2023). "Previously unknown isotope of uranium discovered". Phys.org. Retrieved 2023-04-12. https://phys.org/news/2023-04-previously-unknown-isotope-uranium.html
Niwase, T.; Watanabe, Y. X.; Hirayama, Y.; et al. (2023). "Discovery of New Isotope 241U and Systematic High-Precision Atomic Mass Measurements of Neutron-Rich Pa-Pu Nuclei Produced via Multinucleon Transfer Reactions" (PDF). Physical Review Letters. 130 (13): 132502-1 – 132502-6. doi:10.1103/PhysRevLett.130.132502. PMID 37067317. S2CID 257976576. https://eprints.whiterose.ac.uk/197980/1/PhysRevLett.130.132502.pdf
Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here. /wiki/Polonium
Specifically from thermal neutron fission of uranium-235, e.g. in a typical nuclear reactor. /wiki/Thermal_neutron
Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. Bibcode:1965NucPh..71..299M. doi:10.1016/0029-5582(65)90719-4."The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk248 with a half-life greater than 9 [years]. No growth of Cf248 was detected, and a lower limit for the β− half-life can be set at about 104 [years]. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 [years]." /wiki/Bibcode_(identifier)
This is the heaviest nuclide with a half-life of at least four years before the "sea of instability". /wiki/Sea_of_instability
Excluding those "classically stable" nuclides with half-lives significantly in excess of 232Th; e.g., while 113mCd has a half-life of only fourteen years, that of 113Cd is eight quadrillion years. /wiki/Primordial_nuclide
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"Physicists have created a new and extremely rare kind of uranium". New Scientist. Retrieved 15 May 2021. https://www.newscientist.com/article/2274847-physicists-have-created-a-new-and-extremely-rare-kind-of-uranium/
"Uranium 232". Nuclear Power. Archived from the original on 26 February 2019. Retrieved 3 June 2019. https://www.nuclear-power.net/nuclear-power-plant/nuclear-fuel/uranium/uranium-232/
"INCIDENT NEUTRON DATA". atom.kaeri.re.kr. 2011-12-14. http://atom.kaeri.re.kr/nuchart/getEvaf.jsp?mat=9219&lib=endfb7.1
C. W. Forsburg; L. C. Lewis (1999-09-24). "Uses For Uranium-233: What Should Be Kept for Future Needs?" (PDF). Ornl-6952. Oak Ridge National Laboratory. http://moltensalt.org/references/static/downloads/pdf/ORNL-6952.pdf
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https://www-nds.iaea.org/amdc/ame2016/NUBASE2016.pdf
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Use of Reprocessed Uranium (PDF). Technical Document. Vienna: International Atomic Energy Agency. 2009. ISBN 978-92-0-157109-0. ISSN 1684-2073. 978-92-0-157109-0
B. C. Diven; J. Terrell; A. Hemmendinger (1 January 1958). "Capture-to-Fission Ratios for Fast Neutrons in U235". Physical Review Letters. 109 (1): 144–150. Bibcode:1958PhRv..109..144D. doi:10.1103/PhysRev.109.144. /wiki/Bibcode_(identifier)
Ikeda, Nagao (July 25, 2011). "The discoveries of uranium 237 and symmetric fission — From the archival papers of Nishina and Kimura". Proceedings of the Japan Academy. Series B, Physical and Biological Sciences. 87 (7): 371–376. doi:10.2183/pjab.87.371. PMC 3171289. PMID 21785255. https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3171289
CRC Handbook of Chemistry and Physics, 57th Ed. p. B-345
CRC Handbook of Chemistry and Physics, 57th Ed. p. B-423
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