Cave of the Crystals or Giant Crystal Cave is a cave connected to the Naica Mine at a depth of 300 metres (980 ft), in Naica, Chihuahua, Mexico. It takes the form of a chamber within the limestone host rock of the mine, and is about 109 metres (358 ft) long with a volume of 5,000 to 6,000 cubic metres (180,000 to 210,000 cu ft).
The chamber contains giant selenite crystals (gypsum, CaSO4 · 2 H2O), some of the largest natural crystals ever found. The largest is 11.40 metres (37.4 ft), with a volume of about 5 cubic metres (180 cu ft), and an estimated mass of 12 tonnes. When not flooded, the cave is extremely hot, with air temperatures reaching up to 58 °C (136 °F) with 90 to 99 percent humidity. This is comparable to temperature records in Death Valley, but with much wetter air that results in a much higher wet bulb temperature; this prevents cooling via sweating. The cave is relatively unexplored because of these factors. Without proper protection, people can only endure approximately ten minutes of exposure at a time.
The cave was discovered in April 2000 by brothers Juan and Pedro Sánchez while drilling in the mine. As of October 2015[update], the mine had reflooded and the cavern filled once more with the water rich in minerals required for the crystals to grow.
A group of scientists in the Naica Project have been studying these caverns.