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Carbon monoxide (data page)
Chemical data page

This page provides supplementary chemical data on carbon monoxide.

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Material safety data sheet

The handling of this chemical may incur notable safety precautions. It is highly recommended that you seek the material safety data sheet (MSDS) for this chemical from a reliable source such as SIRI, and follow its directions.

Structure and properties

Structure and properties
Index of refraction, nD1.0003364
Abbe number?
Dielectric constant, εr? ε0 at ? °C
Bond strength1850 N/m
Bond length0.111 nm
Bond energy1079 kJ/mol
Bond angleLinear
Magnetic susceptibility?

Thermodynamic properties

Phase behavior
Triple point67.9 K (−205.1 °C), 15.35 kPa
Critical point132.7 K (−140.3 °C), 3498 kPa, 11.1 mol/L (3.1×102 kg/m3)
Std enthalpy changeof fusion, ΔfusHo? kJ/mol
Std entropy changeof fusion, ΔfusSo? J/(mol K)
Std enthalpy changeof vaporization, ΔvapHo? kJ/mol
Std entropy changeof vaporization, ΔvapSo? J/(mol K)
Std enthalpy changeof sublimation, ΔsubHo8 kJ/mol (at 51–68 K)
Std entropy changeof sublimation, ΔsubSo? J/(mol·K)
Solid properties
Std enthalpy changeof formation, ΔfHosolid−110.5 kJ/mol
Standard molar entropy,Sosolid? J/(mol K)
Heat capacity, cp? J/(mol K)
Liquid properties
Std enthalpy changeof formation, ΔfHoliquid? kJ/mol
Standard molar entropy,Soliquid? J/(mol K)
Heat capacity, cp? J/(mol K)
Gas properties
Std enthalpy changeof formation, ΔfHogas−110.53 kJ/mol
Std enthalpy changeof combustion, ΔcHogas−283.0 kJ/mol
Standard molar entropy,Sogas197.66 J/(mol K)
Heat capacity, cp29 J/(mol K)

Spectral data

UV-Vis
λmax55 nm
Extinction coefficient, ε?
IR
Major absorption bands2143 cm−1
13CO2099.2 ± 4 cm−1
NMR
Proton NMR 
Carbon-13 NMR 
Other NMR data 
MS
Masses of main fragments 
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