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Enthalpy of sublimation
The heat required to change one mole of a substance from solid state to gaseous state

In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid. For elemental metals, it is also equal to the standard enthalpy of formation of the gaseous metal atoms. The heat of sublimation is usually expressed in kJ/mol, although the less customary kJ/kg is also encountered.

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Sublimation enthalpies

symbolsubstancesSublimation enthalpy (kJ/mol)
Lilithium1592
Nasodium1073
Kpotassium894
Rbrubidium815
Cscaesium766
Mgmagnesium1487
Cacalcium1788
Srstrontium1649
Babarium18010
Feiron41611
Ninickel43012
Cucopper33813
Znzinc13114
Agsilver28515
Wtungsten84916
Augold36617
Cgraphite71718
Cdiamond71519
Sisilicon45620
Sntin30221
Pblead19522
Fmfermium14123
I2iodine62.424
C10H8naphthalene72.925
CO2carbon dioxide2526
H2Owater51.1

See also

References

  1. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  2. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  3. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  4. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  5. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  6. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  7. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  8. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  9. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  10. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  11. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  12. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  13. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  14. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  15. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  16. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  17. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  18. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  19. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  20. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  21. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  22. Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).Principles of Modern Chemistry, Brooks Cole. Appendix D. ISBN 978-1305079113 ↩

  23. Haire, Richard G.; Gibson, John K. "The enthalpy of sublimation and thermodynamic functions of fermium". The Journal of Chemical Physics. 91: 7085–7096. doi:10.1063/1.457326. https://pubs.aip.org/aip/jcp/article-abstract/91/11/7085/95919/The-enthalpy-of-sublimation-and-thermodynamic ↩

  24. Chickos, James S.; Acree, William E. (2002). "Enthalpies of Sublimation of Organic and Organometallic Compounds. 1910–2001". Journal of Physical and Chemical Reference Data. 31 (2): 537–698. doi:10.1063/1.1475333. ISSN 0047-2689. http://aip.scitation.org/doi/10.1063/1.1475333 ↩

  25. Chickos, James S.; Acree, William E. (2002). "Enthalpies of Sublimation of Organic and Organometallic Compounds. 1910–2001". Journal of Physical and Chemical Reference Data. 31 (2): 537–698. doi:10.1063/1.1475333. ISSN 0047-2689. http://aip.scitation.org/doi/10.1063/1.1475333 ↩

  26. Chickos, James S.; Acree, William E. (2002). "Enthalpies of Sublimation of Organic and Organometallic Compounds. 1910–2001". Journal of Physical and Chemical Reference Data. 31 (2): 537–698. doi:10.1063/1.1475333. ISSN 0047-2689. http://aip.scitation.org/doi/10.1063/1.1475333 ↩