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Manganin
Copper-based alloy

Manganin is a trademarked name for an alloy of typically 84.2% copper, 12.1% manganese, and 3.7% nickel. It was first developed by Edward Weston in 1892, improving upon his Constantan (1887).

Manganin foil and wire is used in the manufacture of resistors, particularly ammeter shunts, because of its virtually zero temperature coefficient of resistance value and long term stability. Several Manganin resistors served as the legal standard for the ohm in the United States from 1901 to 1990. Manganin wire is also used as an electrical conductor in cryogenic systems, minimizing heat transfer between points which need electrical connections.

Manganin is also used in gauges for studies of high-pressure shock waves (such as those generated from the detonation of explosives) because it has low strain sensitivity but high hydrostatic pressure sensitivity.

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History

In 1887 Edward Weston discovered that metals can have a negative temperature coefficient of resistance, inventing what he called his "Alloy No. 2." It was produced in Germany where it was renamed "Constantan".4 In 1888 he patented5 "an alloy containing from 65 to 70 parts of copper, 25 to 30 parts of ferro-manganese, and 2.5 to 10 parts of nickel" which had a nearly constant resistivity.

Manganin wire as we know it was developed by Weston's assistant John Forrest Kelly.6 In May 1893, Weston received a patent for the material and its use for resistors. While Manganin represented a significant advance in technology -- the material was a conductive metal with constant resistance over a wide range of working temperatures, Weston did not receive wide recognition at the time.7

Properties

Cu86/Mn12/Ni2

Electrical Properties

  • Temperature coefficient: 1.5×10−5 K−1

Mechanical Properties

  • Modulus of elasticity: 124–159 GPa
  • Maximum use temperature in air: 300 °C
Cu84/Mn12/Ni48
Temperature [°C]coefficient of resistivity
 12+.000006
 25 .000000
100−.000042
250−.000052
475 .000000
500+.00011 
Resistance of Wires at 20 °C9
AWGohms per cmohms per ft
10.000836 0.0255
12.00133  0.0405
14.00211  0.0644
16.00336  0.102 
18.00535  0.163 
20.00850  0.259 
22.0135   0.412 
24.0215   0.655 
26.0342   1.04  
27.0431   1.31  
28.0543   1.66  
30.0864   2.63  
32.137    4.19  
34.218    6.66  
36.347   10.6   
40.878   26.8   

See also

References

  1. "Goodfellow Technical Information Manganin® - Resistance Alloy". www.goodfellow.com. Retrieved 2016-09-11. http://www.goodfellow.com/catalogue/GFCat2H.php?ewd_token=09GRBJvlw6lL5lDbZC1qWnos3v9ad5&n=kCvbg9HE4EQs6Xg56ttKPuupoT1SdP&ewd_urlNo=GFCat2L3&Head=CU06

  2. "Stability of Double-Walled Manganin Resistors" (PDF). Archived (PDF) from the original on 2024-09-30. Retrieved 2007-04-30. https://nvlpubs.nist.gov/nistpubs/sp958-lide/063-065.pdf

  3. "Special Use Sensors - Manganin Pressure Sensor" (PDF). web.sensor-ic.com. Vishay. Retrieved 15 April 2023.[permanent dead link‍] http://web.sensor-ic.com:8000/ZLXIAZAI/VISHAY/thumb_2011032859967085.pdf

  4. National Electrical Manufacturers Association (1946). A chronological history of electrical development from 600 B.C. New York, N.Y., National Electrical Manufacturers Association. https://archive.org/details/chronologicalhis00natirich

  5. U.S. patent 381304A https://patents.google.com/patent/US381304A

  6. Fessenden, Reginald A. (1893-07-21). "Electrical Notes". Science. ns-22 (546): 35–36. doi:10.1126/science.ns-22.546.35. ISSN 0036-8075. https://books.google.com/books?id=wdlCTzYLf2kC&pg=RA1-PA36

  7. Woodbury, David O. (1949). A Measure for Greatness; A Short Biography of Edward Weston. New York, Toronto, London: McGraw-Hill. https://archive.org/details/measureforgreatn001419mbp

  8. CRC Handbook 27th ed. Feb 1943. p. 1875.

  9. CRC Handbook 27th ed. Feb 1943. p. 2485.